氧化还原敏感微量元素 Re、Mo 和 U 主要依靠扩散作用通过沉积物—水界面,在不同氧化还原条件下的沉积物中自生富集,Re在轻度还原的次氧化沉积环境中富集,Mo在还原性更强的硫化环境中富集,而 U 具有较宽的富集沉积深度区间。Re、Mo和 U 独特的地球化学行为使其可用于指示海洋环境的氧化还原状态,其在沉积物中的自生富集程度与沉积时所处的氧化还原条件具有良好的相关性:Re、Mo 和 U 在氧化沉积环境(Re/Al<1.3×10-7,Mo/Al<0.4×10-4)和季节性缺氧区覆盖的沉积环境中富集程度较小,在常年性缺氧区覆盖的沉积环境(U/Al>5×10-4,Mo/Al>5×10-4)和硫化沉积环境(Mo/Al>5×10-4)中富集程度较大。除依据其地球化学行为特征和相对富集程度进行定性分析之外,还可以结合元素富集系数(TMEF<1 表示亏损,TMEF>1 表示富集,TMEF相似文献
Acta Geotechnica - A number of discrete element analyses of undrained triaxial shear tests on crushable assemblies are performed using 3-dimensional particle flow code (PFC3D). The undrained shear... 相似文献
Gravity retaining wall with geogrids has showed excellent seismic performance from Wenchuan great earthquake. However, seismic damage mechanism of this kind of wall is not sufficiently clear. In view of this, a large shaking table test of the gravity retaining wall with geogrids to reinforce the subgrade slope was carried out, and based on the Hilbert-Huang transform and the marginal spectrum theory, the energy identification method of the slope dynamic failure mode was studied. The results show that the geogrids can effectively reduce displacement and rotation of the retaining wall, and it can effectively absorb the energy of the ground movement when combined with the surrounding soil. In addition, it also reveals the failure development of the gravity retaining wall with geogrids to reinforce the subgrade slope. The damage started in the deep zone near the geogrids, and then gradually extended to the surface of the subgrade slope and other zones, finally formed a continuous failure surface along the geogrids. The analysis results of the failure mode identified by the Hilbert marginal spectrum are in good consistency with the experimental results, which prove that the Hilbert marginal spectrum can be applied to obtain the seismic damage mechanism of slope.
Mechanical responses induced by temperature and air pressure significantly affect the stability and durability of underground compressed air energy storage (CAES) in a lined rock cavern. An analytical solution for evaluating such responses is, thus, proposed in this paper. The lined cavern of interest consists of three layers, namely, a sealing layer, a concrete lining and the host rock. Governing equations for cavern temperature and air pressure, which involve heat transfer between the air and surrounding layers, are established first. Then, Laplace transform and superposition principle are applied to obtain the temperature around the lined cavern and the air pressure during the operational period. Afterwards, a thermo-elastic axisymmetrical model is used to analytically determine the stress and displacement variations induced by temperature and air pressure. The developments of temperature, displacement and stress during a typical operational cycle are discussed on the basis of the proposed approach. The approach is subsequently verified with a coupled compressed air and thermo-mechanical numerical simulation and by a previous study on temperature. Finally, the influence of temperature on total stress and displacement and the impact of the heat transfer coefficient are discussed. This paper shows that the temperature sharply fluctuates only on the sealing layer and the concrete lining. The resulting tensile hoop stresses on the sealing layer and concrete lining are considerably large in comparison with the initial air pressure. Moreover, temperature has a non-negligible effect on the lined cavern for underground compressed air storage. Meanwhile, temperature has a greater effect on hoop and longitudinal stress than on radial stress and displacement. In addition, the heat transfer coefficient affects the cavern stress to a higher degree than the displacement. 相似文献
Specimens of coarse-grained Äspö diorite were axially compressed to observe stress-induced spalling. The specimens had a novel design characterized by two manufactured large radius notches on opposite sides. The tangential stress occurring in the notches aimed to represent the tangential loading around a circular opening. Fracture stages were monitored by acoustic emission measurements. Rock chips were formed similar to those found in situ, which indicates a similar fracture process. Slabs were cut out from the specimens and impregnated using a fluorescent material to visualize the cracks. The cracks were subsequently examined by the naked eye and by means of microscopy images, from which fracture paths could be identified and related to different minerals and their crystallographic orientations. The microscopy analyses showed how the stress field and the microstructure interact. Parallel cracks were formed 2–4 mm below the surface, sub-parallel to the direction of the maximum principal stress. The crack initiation, the roles of minerals such as feldspar, biotite and quartz and their grain boundaries and crystallographic directions are thoroughly studied and discussed in this paper. Scale effects, which relate to the stress gradient and microstructure, are discussed. 相似文献