Biot介质中P波与井孔的耦合

依据全频域的Ｂｉｏｔ理论，推导了在Ｂｉｏｔ的流体饱和孔隙介质中，平面Ｐ波垂直井轴入时与井孔相互作用所产生的井内声压场的解析表达式．通过数值计算，对井内声压场出现的共振响应进行了分析．重点研究在不同频率段渗透率对井内声压的影响及偏离井轴记录时声压的变化．结果表明，在井内测量地震波声压，全频域都有明显影响；测量大于５００ＨＺ的地震信号，检波器偏离井轴放置以及方位不同的影响不能忽略；渗透率变化对井内声压的影响程度最大不超过弹性固体情况（零渗透率）下相应声压的１／５．     

A Late Ordovician high-energy temperate-water carbonate ramp,southern Quebec,Canada: implications for Late Ordovician oceanography*

The Trenton Group (Late Ordovician), the youngest carbonate unit in the Taconic foreland basin of southern Quebec, is a tripartite unit with a distinctive coarse-grained middle part, the Deschambault Formation. Lithofacies of the Deschambault Formation are dominated by coarse-grained bioclastic/intraclastic limestones; finer-grained lithofacies are ubiquitous but subordinate. The complete spectrum of lithofacies indicates sedimentation ranging from above fairweather- to below storm-wave base. Skeletal components are indicative of the modern temperate-water bryomol association. Non-skeletal elements are represented by peloids and intraclasts. Accretion rates from areas of continuous sedimentation were low (<14 cm/10³ years). From sedimentological and faunal evidence, it is proposed that the Late Ordovician Deschambault ramp was bathed by temperate waters. The model compares favourably with modern cool-water shelves rimming the southern edge of the Australian continent. Palaeomagnetic data locate southern Quebec in a low latitudinal setting during the Late Ordovician. Upper Ordovician facies distribution in eastern Canada and progressive disappearance of some faunal provinces through Late Ordovician time are used to conclude that the initiation of the Late Ordovician glaciation that covered most of Gondwana was instrumental in easing northward movement of cold oceanic currents. This resulted in the rapid contraction of the southern hemisphere warm-water tropical belt from a 30° latitudinal-wide zone in the early Caradoc to a 15° zone in the late Caradoc.     

Partial melting of metagreywacke: a calculated mineral equilibria study

Greywacke occurs in most regionally metamorphosed orogenic terranes, with depositional ages from Archean to recent. It is commonly the dominant siliciclastic rock type, many times more abundant than pelite. Using calculated pseudosections in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O system, the partial melting of metagreywacke is investigated using several natural protolith compositions that reflect the main observed compositional variations. At conditions appropriate for regional metamorphism at mid‐crustal depths (6–8 kbar), high‐T subsolidus assemblages are dominated by quartz, plagioclase and biotite with minor garnet, orthoamphibole, sillimanite, muscovite and/or K‐feldspar (±Fe–Ti oxides). Modelled solidus temperatures are dependent on bulk composition and vary from 640 to 690 °C. Assuming minimal melting at the H₂O‐saturated solidus, initial prograde anatexis at temperatures up to ～800 °C is characterized by very low melt productivity. Significant melt production in commonly occurring (intermediate) metagreywacke compositions is controlled by the breakdown of biotite and production of orthopyroxene (±K‐feldspar) across multivariant fields until biotite is exhausted at 850–900 °C. Assuming some melt is retained in the source, then at temperatures beyond that of biotite stability, melt production occurs via the consumption of plagioclase, quartz and any remaining K‐feldspar as the melt becomes progressively more Ca‐rich and H₂O‐undersaturated. Melt productivity with increasing temperature across the melting interval in metagreywacke is generally gradational when compared to metapelite, which is characterized by more step‐like melt production. Comparison of the calculated phase relations with experimental data shows good consistency once the latter are considered in terms of the variance of the equilibria involved. Calculations on the presumed protolith compositions of residual granulite facies metagreywacke from the Archean Ashuanipi subprovince (Quebec) show good agreement with observed phase relations. The degree of melt production and subsequent melt loss is consistent with the previously inferred petrogenesis based on geochemical mass balance. The results show that, for temperatures above 850 °C, metagreywacke is sufficiently fertile to produce large volumes of melt, the separation from source and ascent of which may result in large‐scale crustal differentiation if metagreywacke is abundant.     

A sequence of partial melting reactions at Mt Stafford, central Australia

Metasedimentary gneisses show a rapid change in grade in a 10  km wide low- P /high- T  regional aureole at Mt Stafford in the Arunta Block, central Australia. Migmatite occurs in all but the lowermost of five metamorphic zones, which grade from greenschist (Zone 1) through amphibolite (Zones 2–3) to granulite facies (Zones 4–5). The sequence of partial melting reactions inferred for metapelitic rocks is dependant upon protolith, temperature and fluid conditions. The metapelite solidus in Zone 2 reflects vapour-present melting at P ≈3  kbar and T  ≈640  °C, melting having initially been controlled by the congruent breakdown of the assemblage Crd–Kfs–Bt–Qtz. At slightly higher temperature, andalusite in leucosome formed via the reaction Kfs+Qtz+Bt+H₂O→And+melt; And+melt having been stabilized by the presence of boron. Sillimanite coaxially replaces andalusite in the high-grade portion of Zone 2. In Zone 3, large aluminosilicate aggregates in leucosome are armoured by Spl–Crd±Grt symplectites. Garnet partially pseudomorphs biotite, cordierite or spinel in high-grade portions of Zone 3. Zone 4 Grt–Crd–Opx-bearing metapsammite assemblages and garnet-bearing leucosome reflect T  ≈800  °C and P =2.2±0.9  kbar. In the model KFMASH system the principal vapour-absent melting step reflected significant modal changes related to the breakdown of the As–Bt tie-line and the establishment of the Spl–Crd tie-line; the bulk rock geochemistry of migmatite samples straddle the Spl–Crd tie-line. The aluminous bulk-rock composition of the common bedded migmatite restricted its potential to witness garnet-forming and orthopyroxene-forming reactions, minor textural and modal changes in and above Zone 3 reflecting biotite destablization in biotite-poor assemblages.     

Prograde Metamorphic Assemblage Evolution during Partial Melting of Metasedimentary Rocks at Low Pressures: Migmatites from Mt Stafford, Central Australia

The Mt Stafford area in central Australia preserves a low-pressuregreenschist- to granulite-facies regional aureole. The metasedimentarysequence has been divided into five zones from greenschist (Zone1) to granulite facies (Zone 4) and a zone of hybrid diatexiteformed from the introduction of granitic magma into the high-grademigmatites (Zone 5). Melt production was dominated by a seriesof multivariant biotite breakdown reactions, not the univariantreactions suggested by previous studies. Although the threemain metasedimentary rock types produced similar amounts ofmelt at the highest grades, their melt production historiesdiffered markedly as a function of temperature. Aluminous metapelitesproduced more melt at lower temperatures (Zones 2 and 3), whereasmetapsammite and cordierite granofels experienced an additionalmajor melt-producing step at higher temperatures (upper Zone3 and Zone 4). This melting step involved the breakdown of biotiteto produce garnet, K-feldspar and melt, and in some rocks theproduction of orthopyroxene. Melt production in Zone 4 exceeded25 mol %, resulting in the formation of in situ diatexites.Complex relationships involving aluminosilicate porphyroblastsresulted in the breakdown of biotite and aluminosilicate beingdrawn out over a wide temperature range, from subsolidus conditionsto temperatures close to 750°C. Initially, much of the meltingdeveloped around the aluminosilicate porphyroblasts during thebreakdown of coexisting biotite, aluminosilicate and quartz.However, much of the rock was chemically isolated from the porphyroblastsand could not react to produce melt. As temperatures rose, thepresence of the large isolated aluminosilicate porphyroblastscontrolled the spatial development of quartz-absent, spinel-presentcompositional domains, the formation of spinel being governedby the silica-undersaturated breakdown of coexisting biotiteand aluminosilicate. KEY WORDS: NCKFMASHTO; metapelite; granulite facies; petrogenetic grid; partial melting; THERMOCALC     

Genesis of Mafic Microgranular Enclaves in the Shaocunwu Granodiorite,Southern China,and their Implications: Evidence from Zircon and Whole-rock Geochemistry

Magmatic microgranular enclaves (MMEs) are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic belt.Field geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular apatite.Zircon U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic magmatism.Whole-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar ~(87)Sr/~(86)Sr,and ~(147)Nd/~(144)Nd isotope ratios,and their zircon ~(177)Hf/~(176)Hf isotopic ratios are similar.Geochemical studies indicate that both the host granodiorite and MMEs formed by mixing of coeval magma.Zircon Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-Cu (Mo) mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-Cu (Mo) fertile melts.     

一个新的矿物面扫描分析方法开发和地质学应用

LA-ICP-MS面扫描分析近些年来发展的新兴技术,相对于其他面扫描仪器,其具有样品制样流程简单、仪器购置和分析成本低、分析时间短、检测限低、多元素表面分析(5μm)、近乎无损等分析优势,在地球科学和生物学领域有着大量的应用。本文系统介绍了作者应用Photon Machines激光剥蚀系统与安捷伦ICP-MS新开发矿物元素面扫描分析方法。该方法基于近些年来开发的双室样品仓技术和Matlab软件,通过自主开发的LaIcpMsSoftware(LIMS)进行数据处理来完成的。本次研究开发的激光面扫描分析技术可以在短时间内(2小时)分析3mm×3mm区域,并同时给出多组元素(包括稀土元素等)在二维平面的分布特征。论文详细描述了LIMS工作原理和特点,相对于国外同类型软件,LIMS具有操作简单,并具有多种数据显示模式和剖面切割展示,元素比值面分布分析等优势,便于后期数据分析与解译。同时,还展示了对斜长石、白钨矿和石榴子石进行面扫描分析的初步结果。研究表明,通过LA-ICP-MS面扫描,可以获得比点分析更为准确的元素分布特征,并能够更为直观的展示不同元素在矿物分布特征和相关关系,更好的开展矿物地球化学研究。     

Contrasting behaviour of rare earth and major elements during partial melting in granulite facies migmatites, Wuluma Hills, Arunta Block, central Australia

Low‐P granulite facies metapelitic migmatites in the Wuluma Hills, Strangways Metamorphic Complex, Arunta Block, preserve evidence of polyphase deformation and migmatite formation which is of the same age of the c. 1730 Ma Wuluma granite. Mineral equilibria modelling of garnet‐orthoproxene‐cordierite‐bearing assemblages using thermocalc is consistent with peak S3 conditions of 6.0–6.5 kbar and 850–900 °C. The growth of orthopyroxene and garnet was primarily controlled by biotite breakdown during partial melting reactions. Whereas orthopyroxene in the cordierite‐biotite mesosome shows enrichment of heavy‐REE (HREE) relative to medium‐REE (MREE), orthopyroxene in adjacent garnet‐bearing leucosome shows depletion of HREE relative to MREE. There is no appreciable difference in major element contents of minerals common to both the mesosome and leucosome. The REE variations can be satisfactorily explained by decoupling of major element and REE partitioning, in the context of appropriate phase‐equilibria modelling of a prograde path at ～6 kbar. Sparse garnet nucleii formed at ～760 °C, along with concentrated leucosome development and preferentially partitioned HREE. Further heating to ～800 °C at constant or subtly increasing pressure conditions additionally stabilized orthopyroxene and decreased the garnet mode. Orthopyroxene in the leucosome inherited an REE pattern consequent to the partial consumption of garnet, it being distinct from the REE pattern in mesosome orthoproxene that was mostly controlled by biotite breakdown. Such within‐sample variability in the enrichment of heavy REE indicates that caution needs to be exercised in the application of common elemental partitioning coefficients in spatially complex metamorphic rocks.     

Using calculated chemical potential relationships to account for coronas around kyanite: an example from the Bohemian Massif

Corona textures around kyanite, involving for example zoned plagioclase separating kyanite from the matrix, reflect the instability of kyanite with the matrix on changing P–T conditions, commonly related to decompression. The chemical potential gradients set up between the kyanite and the matrix as a consequence of slow Al diffusion drive corona development, with the zoning of the plagioclase reflecting the gradients. Calculated mineral equilibria are used to account for corona textures involving plagioclase ± garnet around kyanite, and replacement of kyanite by plagioclase + spinel symplectite, in quartz + plagioclase + K‐feldspar + garnet + kyanite granulite facies gneiss from the Blanský les massif in the Bohemian massif, Czech Republic. In the garnet‐bearing coronas, a commonly discontinuous garnet layer lies between the kyanite and the continuous plagioclase layer in the corona, with both the garnet and the plagioclase appearing mainly to replace matrix rather than kyanite. The garnet layer commonly extends around kyanite from original matrix garnet adjacent to the kyanite. Where garnet is missing in the corona, the kyanite itself may be replaced by a spinel–plagioclase corona. In a local equilibrium model, the mineral and mineral compositional spatial relationships are shown to correspond to paths in μ(Na₂O)–μ(CaO)–μ(K₂O)–μ(FeO)–μ(MgO)–μ(SiO₂) in the model chemical system, Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂ (NCKFMAS). The discontinuous nature of the garnet layer in coronas is accounted for by the effect of the adjacent original garnet on the chemical potential relationships. The replacement of kyanite by spinel + plagioclase appears to be metastable with respect to replacement by corundum + plagioclase, possibly reflecting the difficulty of nucleating corundum.