DOC budgets of drained peat catchments: implications for DOC production in peat soils

The blocking of drainage ditches in peat has been proposed as a possible mitigation strategy for the widely observed increases in dissolved organic carbon (DOC) concentrations from northern peatlands. This study tested the hypothesis that drain‐blocking could lead to lower DOC concentrations by measuring the DOC export from a series of small peat‐covered catchments over a period of 2 years. Six catchments were chosen: two were pristine that had never been drained; three where drains had been blocked (one in 1995, and two in 2003); and a control peat drain catchment where the drain was left unblocked throughout the study. In the case where drains were blocked as part of thus study, the drains were observed for 2 months before blocking and 2 years after blocking. The results show that: (i) high concentrations of DOC can come from water ponded in the drain; (ii) the DOC export (flux of DOC per area of catchment) from the six study catchments shows a high degree of positive correlation with both catchment size and water yield; (iii) distinctly lower DOC export with water yield was observed for the catchments containing higher‐order channels (>27 500 m²) as opposed to single drain catchments (>7500 m²); (iv) drain‐blocking resulted in a statistically significant decrease in DOC export (average was 39%) but the effect upon DOC concentration explained only 1% of the variance in the data. The results suggest that drain blocking works by decreasing the flow from the drain, not by changing the production of DOC in the peat. The change in export with catchment size implies a considerable removal of DOC from large catchments. Copyright © 2009 John Wiley & Sons, Ltd.     

基于Erdas2013的Pleiades卫星影像区域网平差设计与实现

介绍了Pleiades卫星影像数据及基于Erdas 2013的Pleiades卫星影像应用的可行性和区域网平差技术,为该卫星影像应用于相关测绘工程提供了技术依据。     

塔里木地块库车坳陷早白垩世古地磁结果及磁倾角偏低的成因探讨

运用主成分分离及线性区段等方法 ,使早白垩世样品明显分离出二组磁组分 .叠加剩磁为喜山期重磁化 ,特征剩磁明显偏离现代地磁场方向 ,经倾斜校正后 ,有很好的一致性并通过了倒转检验 ,给出塔里木地块库车坳陷早白垩世巴西盖组古地磁新数据 .综合已有的古地磁结果 ,获得了塔里木地块早白垩世平均剩磁方向及平均古地磁极 ,阐明了塔里木地块早白垩世磁倾角明显偏低这一现象 .分析导致磁倾角偏低的诸多因素 ,认为压实作用可能是导致磁倾角偏低的重要因素之一 .     

兰州城区稳定能量及其与空气污染的关系

从能量学的观点出发，提出了描述地面至特定高度大气层结构稳定度的参数－稳定能量，并给出了具体计算方法。根据1988－1992年兰州气象站逐日08：00（北京时，下同）的探空资料，计算了300－1000m每隔50m共15层的稳定能量。利用同期兰州市环境监测站自动监测系统监测的兰州城区3种主要空气污染物二氧化硫、一氧化碳和氮氧化物（SO2、CO、NOX）的日平均浓度资料，计算了地面气象要素、低空气象参数、低空风和稳定能量等气象因子与SO2、CO、NOX之间的相关。结果表明：（1）用稳定能量来描述低层大气的稳定性更为合理一些；（2）在诸多气象因子中，稳定能量与SO2、CO、NOX浓度之间的相关性最显著；（3）稳定能量的年变化规律与空气污染浓度的年变化规律基本一致；（4）逐月看，各层稳定能量与SO2浓度之间均为正相关，除7月份以外，大多数层次均通过了α＝0．01显著性水平的相关性检验。     

Monitored Natural Attenuation to Manage PFAS Impacts to Groundwater: Scientific Basis

Sites impacted by per- and polyfluoroalkyl substances (PFAS) pose significant challenges to investigation and remediation, including very low cleanup objectives, limited information on natural PFAS degradation processes in the subsurface, and the apparent mobility and persistence of PFAS. Consequently, monitored natural attenuation (MNA) may be considered less applicable to PFAS compared to biodegradable classes of chemicals such as petroleum hydrocarbons and chlorinated solvents that can completely biodegrade to innocuous end products. However, MNA has proven effective for certain non-degrading metals, metalloids, and radionuclides (e.g., chromium, arsenic, and uranium). To assess the applicability of MNA to PFAS, this paper reviews the fate and transport properties of PFAS in conjunction with the various physiochemical factors that control the subsurface movement of chemicals. This analysis demonstrates that two important retention processes: (1) chemical retention in the form of PFAS precursors, and (2) geochemical retention in the form of sorption and matrix diffusion to mitigate the movement and potential impacts of PFAS in groundwater that may form the scientific basis for applying MNA to PFAS contamination. This paper describes the scientific and regulatory basis for using MNA to manage PFAS-impacted groundwater.     

The United Kingdom Infrared Telescope Deep Impact observations: Light curve, ejecta expansion rates and water spectral features

We present results from the United Kingdom Infrared Telescope observations of the impact of Deep Impact with Comet 9P/Tempel 1, on July 4, 2005 UT. These observations were carried out in conjunction with the worldwide observing campaign co-ordinated by K.J. Meech [Meech, K.J., and 208 colleagues, 2005. Science 310, 265-269]. The UKIRT team was the first to observe and announce the successful impact. At 05:50:52 (±2.5 s) UT the visible camera that is used to guide the telescope on the comet showed the start of a rapid rise in intensity, such that the visible brightness of Tempel 1 approximately doubled in 70 s. After that time there was a steady increase in the visible flux from the comet until it reached a maximum around 35 min post-impact, at which point it was more than ten times its original intensity. From an average of the time to maximum brightness and the time to noticeable intensity decline, we deduce that the material ejected by the impact expanded with a range of velocities between ∼125 and ∼390 m/s. We also observed water emission lines in the spectral region from 2.8945 to 2.8985 μm. We noted several water lines, which are known to be pumped by sunlight. But there was a lower intensity spectral component, which we propose may result from solar heating of icy grains freshly exposed by the impact.     

The Morávka meteorite fall: 3. Meteoroid initial size,history, structure,and composition

Abstract— The properties and history of the parent meteoroid of the Morávka H5–6 ordinary chondrites have been studied by a combination of various methods. The pre‐atmospheric mass of the meteoroid was computed from fireball radiation, infrasound, seismic signal, and the content of noble gases in the meteorites. All methods gave consistent results. The best estimate of the pre‐atmospheric mass is 1500 ± 500 kg. The fireball integral bolometric luminous efficiency was 9%, and the acoustic efficiency was 0.14%. The meteoroid cosmic ray exposure age was determined to be (6.7 ± 1.0) × 10⁶ yr. The meteorite shows a clear deficit of helium, both ³He and ⁴He. This deficit can be explained by solar heating. Numerical backward integration of the meteoroid orbit (determined in a previous paper from video records of the fireball) shows that the perihelion distance was probably lower than 0.5 AU and possibly as low as 0.1 AU 5 Ma ago. The collision which excavated Morávka probably occurred while the parent body was on a near‐Earth orbit, as opposed to being confined entirely to the main asteroid belt. An overview of meteorite macroscopic properties, petrology, mineralogy, and chemical composition is given. The meteorites show all mineralogical features of H chondrites. The shock level is S2. Minor deviations from other H chondrites in abundances of trace elements La, Ce, Cs, and Rb were found. The ablation crust is enriched with siderophile elements.     

High‐resolution proglacial lake records of pre‐Little Ice Age glacier advance,northeast Greenland

Understanding Arctic glacier sensitivity is key to predicting future response to air temperature rise. Previous studies have used proglacial lake sediment records to reconstruct Holocene glacier advance–retreat patterns in South and West Greenland, but high‐resolution glacier records from High Arctic Greenland are scarce, despite the sensitivity of this region to future climate change. Detailed geochemical analysis of proglacial lake sediments close to Zackenberg, northeast Greenland, provides the first high‐resolution record of Late Holocene High Arctic glacier behaviour. Three phases of glacier advance have occurred in the last 2000 years. The first two phases (c. 1320–800 cal. a BP) occurred prior to the Little Ice Age (LIA), and correspond to the Dark Ages Cold Period and the Medieval Climate Anomaly. The third phase (c. 700 cal. a BP), representing a smaller scale glacier oscillation, is associated with the onset of the LIA. Our results are consistent with recent evidence of pre‐LIA glacier advance in other parts of the Arctic, including South and West Greenland, Svalbard, and Canada. The sub‐millennial glacier fluctuations identified in the Madsen Lake succession are not preserved in the moraine record. Importantly, coupled XRF and XRD analysis has effectively identified a phase of ice advance that is not visible by sedimentology alone. This highlights the value of high‐resolution geochemical analysis of lake sediments to establish rapid glacier advance–retreat patterns in regions where chronological and morphostratigraphical control is limited.     

Field Test of Enhanced Remedial Amendment Delivery Using a Shear‐Thinning Fluid

Heterogeneity of hydraulic properties in aquifers may lead to contaminants residing in lower‐permeability zones where it is difficult to deliver remediation amendments using conventional injection processes. The focus of this study is to examine use of a shear‐thinning fluid (STF) to improve the uniformity of remedial amendment distribution within a heterogeneous aquifer. Previous studies have demonstrated the significant potential of STFs for improving remedial amendment delivery in heterogeneous aquifers, but quantitative evaluation of these improvements from field applications is lacking. A field‐scale test was conducted that compares data from successive injection of a tracer in water followed by injection of a tracer in an STF to evaluate the impact of the STF on tracer distribution uniformity in the presence of permeability contrasts within the targeted injection zone. Data from tracer breakthrough at multiple depth‐discrete monitoring intervals and electrical resistivity tomography (ERT) showed that inclusion of STF in the injection solution improved the distribution of the injected fluid within the targeted treatment zone. One improvement was a reduction in the movement of injected fluids through high‐permeability pathways, as evidenced by slower breakthrough of tracer at monitoring locations where breakthrough in baseline tracer‐only injection data was faster. In addition, STF‐amended injection solutions arrived faster and to a greater extent in monitoring locations within low‐permeability zones. ERT data showed that the STF injection covered a higher percentage of a two‐dimensional cross section within the injection interval between the injection well and a monitoring well about 3 m away.