The major‐ and trace‐element whole‐rock fingerprints of Egyptian basalts and the provenance of Egyptian artefacts

Discrimination diagrams have been developed that source Egyptian basaltic artefacts using whole‐rock major element geochemistry. These include K₂O versus SiO₂, TiO₂ and P₂O₅ against MgO/Fe₂O₃^t (total Fe as Fe₂O₃), and a discriminant analysis diagram using SiO₂, Fe₂O₃^t, CaO, and MnO. A complementary set of diagrams uses easily obtained trace element data (Nb/Y versus Zr/Nb; Zr [ppm] versus Rb/Sr; TiO₂ [wt % volatile free] versus V; and Cr [ppm] versus Zr/Y) to determine the bedrock sources. These diagrams have been applied to seven First Dynasty basalt vessels (Abydos), two Fourth Dynasty basalt paving stones (Khufu's funerary temple, Giza), and two Fifth Dynasty paving stones (Sahure's complex, Abu Sir). They show that the bedrock source for all the artefacts was the Haddadin flow in northern Egypt. Multidimensional scaling and cluster analysis applied to the whole‐rock data (major elements and trace elements together) and previously published mineral fingerprinting studies confirm these results. Comparing mineral versus whole‐rock fingerprinting techniques, a major advantage of the former is the small sample size required (0.001 g compared to ≥ 0.1 g). Analytical costs are similar for both methods assuming that a comparison (bedrock) database can be assembled from the literature. For most archaeological problems, a whole‐rock bedrock database is more likely to exist than a mineral database, and whole‐rock analyses on artefacts will generally be easier to obtain than mineral analyses. Whole‐rock fingerprinting may be more sensitive than mineral‐based fingerprinting. Thus, if sample quantity is not an issue, whole‐rock analysis may have a slight cost, convenience, and technical advantage over mineral‐based methods. Our results also emphasize that the Egyptians cherished their Haddadin basalt flow and used it extensively and exclusively for manufacturing basalt vessels and paving stones for at least 600 years (∼3150 B.C. to 2500 B.C., approximate ages of the vessels and Abu Sir paving stones, respectively). © 2001 John Wiley & Sons, Inc.     

Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.     

Geochemical processes in the saltwater–freshwater transition zone: comparing results of a sand tank experiment with field data

Geochemical processes, occurring in a stable transition zone between saltwater and freshwater, were simulated in a 2D, multi-layer flow chamber experiment. Mixing, calcite dissolution, and oxidative degradation of organic matter were identified as the main controlling factors. The results of the chamber experiment were compared to field data and verified by thermodynamic modeling. Similarity in most ion distributions suggests the general applicability of the experimental method. Differences in the redox conditions between field and experiment were reflected by the oxidants involved in the mineralization of organic carbon; while field data show evidence of sulfate reduction, the presence of oxygen in the laboratory experiment resulted in the reoxidation of sulfides.     

Two magmatic series with island arc affinities within the vourinos ophiolite

Within the Vourinos ophiolite evidence of two magmatic series has been preserved in cognate cumulates and in effusive and hypabyssal rocks, which constitute the earlier Krapa sequence and the younger Asprokambo sequence. The Asprokambo dyke basic magmas which are poor in incompatible elements and relatively Ni and Cr rich, bear some resemblance to very low Ti basalts (transitional to boninites) found in subduction related arcs or interarc basins. Krapa series magmas from sills, massive and pillow lavas are best equated with low-K tholeiites of island arc suites. Compositions of Al- and Ti- poor Cpx in lavas from both series are comparable to those in island arc basalts, the Asprokambo Cpx being richer in Ca and Cr than those from Krapa.The large volume of cumulates from the Krapa sequence displays the following crystallization order: Ol±Sp, Cpx, Pl±Opx, Mt. Periodic influx of fresh magma batches into the magma chamber occurred mainly during the formation of the lower cumulates (wehrlite, Ol-clinopyroxenite and melagabbro). The upper cumulates, gabbronorite and leucogabbronorite with minor Mt-bearing gabbronorite, crystallized in the upper levels of a magma chamber which became progressively smaller with time. In the Asprokambo sequence, Ol+Sp, Opx, Cpx, PI and Amph are the successively crystallizing phases. The ortho to heteradcumulates consist of websterite, Pl-websterite, gabbronorite, amphibole bearing leuconorite, diorite and granophyre. In cumulates, especially in the lower Krapa sequence, significant subsolidus reaction was probably induced by the persistence of high geothermal gradients linked to continuous magmatism. Petrological features indicate that the evolution of the Krapa series is more compatible with an intermediate fractional/equilibrium crystallization history in an initially open system, whereas nearly perfect fractional crystallization in closed system may have occurred in the small Asprokambo magma chambers. Chemical variations in the lavas of both series can be explained in terms of crystallization of the observed cumulates. Significantly, the Asprokambo intrusives have igneous Mg-hornblende and vanadium bearing, chromian, aluminous titaniferous magnetite, crystallization of which is responsible for the calcalkaline evolutionary trend of these rocks. Major and trace element modelling necessitates a two stage model for the petrogenesis of the Vourinos parental melts, involving high-degree remelting of previously depleted mantle sources favoured by the influx of subduction derived hydrous fluids. The primary magmas parental to the Krapa and Asprokambo series could have been derived respectively by 20 and 30% equilibrium partial fusion of variably depleted lherzolitic sources, leaving residua having a harzburgitic to dunitic composition.     

Reduction of inorganic compounds in autoclaves by using suspended cellulose

Autoclaves are closed vessels in which liquids can be heated above their ‘normal' boiling points. As a consequence the pressure will rise. This equipment has permitted a variety of processes like the syntheses of organics and the leaching of metal ores. Pressure technologies can be used for accelerating reactions, for specific syntheses or they offer an environmental or economical alternative for existing processes. Wet pressure oxidation of sewage sludge, an organic waste product, has become a proven technology. If less oxygen is added than stoichiometrically required for a complete oxidation, cellulose will break down by a different reaction mechanism, releasing electrons. Under these circumstances reduction of inorganic compounds is possible.     

Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.     

Assessment of cement’s dust impact on the soil using principal component analysis and GIS

To evaluate the impact of the cement’s dust emitted by the eastern Moroccan cement factory (Oujda Holcim) and deposited on the soil of the Ain Lahjar commune, 58 samples of soil were collected around the factory on a radius of 3 km approximately. The physicochemical analyses of the upper 3 cm of the soil surface samples correspond to the pH, electrical conductivity, the chlorides and the oxides of Ca, Al, Fe, K, Mn, S and Si which were analyzed by the fluorescence of X-rays. The preliminary results demonstrate that this dust are especially basic and contain a high free lime (43% CaO). The principal component analysis (applied on the 58 samples of soil) allows deducting that the free lime and the sulfur oxide are the tracer elements of this form of pollution. Furthermore, the spatial projection of the factor scores of the principal component analysis using the geographical information system permits to determine the spatial distribution of more polluted areas of soils as well as to estimate their surface (63.3% of the survey zone).     

Late Pleistocene and Early Holocene lake‐level fluctuations in the Lahontan Basin,Nevada: Implications for the distribution of archaeological sites

The Great Basin of the western U.S. contains a rich record of Late Pleistocene and Holocene lake‐level fluctuations as well as an extensive record of human occupation during the same time frame. We compare spatial‐temporal relationships between these records in the Lahontan basin to consider whether lake‐level fluctuations across the Pleistocene‐Holocene transition controlled distribution of archaeological sites. We use the reasonably well‐dated archaeological record from caves and rockshelters as well as results from new pedestrian surveys to investigate this problem. Although lake levels probably reached maximum elevations of about 1230–1235 m in the different subbasins of Lahontan during the Younger Dryas (YD) period, the duration that the lakes occupied the highest levels was brief. Paleoindian and Early Archaic archaeological sites are concentrated on somewhat lower and slightly younger shorelines (_1220–1225 m) that also date from the Younger Dryas period. This study suggests that Paleoindians often concentrated their activities adjacent to large lakes and wetland resources soon after they first entered the Great Basin. © 2008 Wiley Periodicals, Inc.