Theodosius Tschernyschew

Ohne Zusammenfassung     

Main Stages of Evolution of Pacific Ferromanganese Stromatolites and Oncolites

As exemplified by cobalt–bearing Fe–Mn crusts (ferromanganese stromatolite) of the Magellan Seamounts (Clarion–Clipperton Province), the main stages of the structural evolution of bacterial communities have been recognized. It has been demonstrated that the change of the stages is caused by the effect of major tectonic, volcanic, and other geological events.     

Reply to comments by K.A. Goettel and J.S. Lewis

Uranium has been measured by homogenized fission track analysis in 34 samples of 22 achondrites. Potassium has been determined in aliquots of eleven of these. The results, combined with previous Al data, are not compatible with achondrite formation from chondritic material by previously suggested fractional melting or metal-sulfide segregation processes.     

The axial momentum balance of Earth and its fluid envelope

The emergence of greatly improved data sets over the past decade has heightened awareness of the close relationship between changes in the axial component of the angular momentum of the atmosphere and that of the solid Earth, the latter being reflected in small, though detectable, changes in the planet's rate of rotation. Changes in the large-scale wind field, and hence in atmospheric angular momentum, on intraseasonal through interannual time scales can be associated with a number of identifiable meteorological phenomena, whose further study has been given new impetus by the discovery of their signals in Earth's rotation. Future advances in the subject are apt to occur in connection with new data sets that will help address questions remaining about rapid changes in Earth rotation and the torques responsible for the momentum changes. Also in the coming decade, both new data and modeling approaches should help clarify the role of the oceanic portion of Earth's fluid envelope in the planetary momentum balance.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.