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71.
72.
73.
高、低煤阶煤层气藏地质特征及控气作用差异性研究 总被引:4,自引:0,他引:4
高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。 相似文献
74.
Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China 总被引:2,自引:0,他引:2
Cheng Zhang Jianguo Pei Yunqiu Xie Jianhua Cao Lanling Wang 《Environmental Geology》2008,55(8):1621-1626
The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were
resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the
impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional
rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which
is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land,
fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion
process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less
the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly
affected by soil CO2 in tilled land and shrub. 相似文献
75.
Natural radioactivity in sediment of Wei River,China 总被引:1,自引:0,他引:1
The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with
the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China.
The activity concentrations of 226Ra, 232Th and 40K in sediment samples ranged from 10.4 to 39.9 Bq kg−1, 15.3 to 54.8 Bq kg−1 and 514.8 to 1,175.5 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities
of Chinese soil and Shaanxi soil. Radium equivalent activity (Raeq), external hazard index (H
ex) and representative level index (I
γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the
construction of dwellings. All the sediment samples have Raeq lower than the limit of 370 Bq kg−1, H
ex less than unity and I
γr close to 1 Bq kg−1. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h−1 and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological
risk and sediment can be safely used in construction. 相似文献
76.
Application of MODFLOW and geographic information system to groundwater flow simulation in North China Plain, China 总被引:2,自引:0,他引:2
Shiqin Wang Jingli Shao Xianfang Song Yongbo Zhang Zhibin Huo Xiaoyuan Zhou 《Environmental Geology》2008,55(7):1449-1462
MODFLOW is a groundwater modeling program. It can be compiled and remedied according to the practical applications. Because
of its structure and fixed data format, MODFLOW can be integrated with Geographic Information Systems (GIS) technology for
water resource management. The North China Plain (NCP), which is the politic, economic and cultural center of China, is facing
with water resources shortage and water pollution. Groundwater is the main water resource for industrial, agricultural and
domestic usage. It is necessary to evaluate the groundwater resources of the NCP as an entire aquifer system. With the development
of computer and internet information technology it is also necessary to integrate the groundwater model with the GIS technology.
Because the geological and hydrogeological data in the NCP was mainly in MAPGIS format, the powerful function of GIS of disposing
of and analyzing spatial data and computer languages such as Visual C and Visual Basic were used to define the relationship
between the original data and model data. After analyzing the geological and hydrogeological conditions of the NCP, the groundwater
flow numerical simulation modeling was constructed with MODFLOW. On the basis of GIS, a dynamic evaluation system for groundwater
resources under the internet circumstance was completed. During the process of constructing the groundwater model, a water
budget was analyzed, which showed a negative budget in the NCP. The simulation period was from 1 January 2002 to 31 December
2003. During this period, the total recharge of the groundwater system was 49,374 × 106 m3 and the total discharge was 56,530 × 106 m3 the budget deficit was −7,156 × 106 m3. In this integrated system, the original data including graphs and attribution data could be stored in the database. When
the process of evaluating and predicting groundwater flow was started, these data were transformed into files that the core
program of MODFLOW could read. The calculated water level and drawdown could be displayed and reviewed online. 相似文献
77.
Yuan-Bao Wu Shan Gao Hong-Fei Zhang Sai-Hong Yang Wen-Fang Jiao Yong-Sheng Liu Hong-Lin Yuan 《Contributions to Mineralogy and Petrology》2008,155(1):123-133
The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP
eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic
evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an
eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons
are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies.
These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf
isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ LuN ≥ 14) and 176Lu/177Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental
subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and 176Lu/177Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age
are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U
ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon
cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that
their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf
model ages (T
DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
78.
Hydrogen sulfide (H2S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO4 in the presence of variable H2S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H2S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H2S concentrations. To investigate whether the reaction of H2S(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO4 and variable H2S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO4 reduction was not measurable in the absence of paraffin even with high H2S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H2S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H2S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H2S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H2S pressure. Thus, we propose that the LSC produced from H2S reaction with HC are most likely the reactive intermediates for H2S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content. 相似文献
79.
加强技术创新服务地质调查——庆祝探矿工艺研究所成立30周年 总被引:1,自引:1,他引:0
为加强地质探矿技术力量,改变地质装备落后现状,经国务院批准,1978年8月8日成立了探矿工艺研究所。30年来,经过新老两代工艺所人的艰苦奋斗、刻苦钻研、勇于创新,在科研攻关、成果转化、基地建设和管理等方面都取得了可喜的成绩,为国家的地质科学事业做出了贡献,目前已成为一个“以勘查技术为基础,以承担地质调查任务和科研项目、提供勘查与监测技术方法和技术服务为手段,以服务国家经济建设、社会发展和地质工作为目标,以探矿工艺技术和地质灾害监测防治技术研发为主业”的地质调查科研机构。回顾了工艺所艰苦创业、改革进取的发展历程,对科技体制改革、专业结构调整、人事分配制度改革、地质调查和科研工作进行了总结,展示了丰硕的科研成果和强劲的科技实力;指出了工艺所在“十一五”期间地质调查和科研工作的重点领域和优先发展方向。 相似文献
80.