Classification of natural mineral and spring bottled waters of Portugal using Principal Component Analysis

Considering its area, Portugal is one of the world's richest countries in mineral and spring waters. There are 33 different types of bottled water, 18 of which are classified as natural mineral water and the remaining as spring water. The majority of these waters are of low mineralisation in comparison to most European bottled waters.     

Assessing climate change impacts on water balance in the Mount Makiling forest, Philippines

A statistical downscaling known for producing station-scale climate information from GCM output was preferred to evaluate the impacts of climate change within the Mount Makiling forest watershed, Philippines. The lumped hydrologic BROOK90 model was utilized for the water balance assessment of climate change impacts based on two scenarios (A1B and A2) from CGCM3 experiment. The annual precipitation change was estimated to be 0.1–9.3% increase for A1B scenario, and ?3.3 to 3.3% decrease/increase for the A2 scenario. Difference in the mean temperature between the present and the 2080s were predicted to be 0.6–2.2°C and 0.6–3.0°C under A1B and A2 scenarios, respectively. The water balance showed that 42% of precipitation is converted into evaporation, 48% into streamflow, and 10% into deep seepage loss. The impacts of climate change on water balance reflected dramatic fluctuations in hydrologic events leading to high evaporation losses, and decrease in streamflow, while groundwater flow appeared unaffected. A study on the changes in monthly water balance provided insights into the hydrologic changes within the forest watershed system which can be used in mitigating the effects of climate change.     

Probabilistic simulations of the impact of increasing leaf-level atmospheric carbon dioxide on the global land surface

Using a climate model with a sophisticated land surface scheme, simulations were conducted to explore the impact of increases in leaf-level carbon dioxide (CO₂) on evaporation, temperature and other land surface quantities. Fifty-one realizations were run, for each of four Januarys and four Julys for CO₂ concentrations at leaf-level of 280, 375, 500, 650, 840 and 1,000 ppmv. Atmospheric CO₂ concentration was held constant at 375 ppmv in all experiments. Statistically significant decreases in evaporation and increases in temperature occur in specific regions as leaf-level CO₂ is increased from 280 to 375 ppmv. These same areas expand geographically, and the magnitude of the changes increase as leaf-level CO₂ is increased further suggesting that changes are caused by the increase in leaf-level CO₂ and are not internal model variability. As leaf-level CO₂ is increased further, larger areas of the continental surface are affected by increasing amounts and a statistically significant change in precipitation is seen. The increase in leaf-level CO₂ from 280 ppmv to 375 ppmv causes statistically significant changes in the evaporation over 12% of continental surfaces in July. This increases to 25% at 500 ppmv, 35% at 650 ppmv, 41% at 840 ppmv and 47% at 1,000 ppmv. This affects temperature and rainfall by similar amounts, generally in coincident regions. An analysis of these results over key regions shows that the probability density functions of the latent heat flux and temperature are affected non-uniformly. There is a shift in the latent heat flux probability density function to lower values, mainly through the reduction in the upper tail of the distribution. The temperature probability density function shifts to higher values, mainly through an increase in the upper tail of the distribution indicating that the impact is focussed on extremes. Given that there are a suite of well evaluated land surface models that include the biogeochemical effects of increasing CO₂ we suggest that the inclusion of such a model should be a recommended component of climate models used in future assessment reports by the Intergovernmental Panel on Climate Change.     

Comparison of Linear Regression Models for Quantitative Geochemical Analysis: An Example Using X-Ray Fluorescence Spectrometry

This paper presents statistical aspects related to the calibration process and a comparison of different regression approaches of relevance to almost all analytical techniques. The models for ordinary least-squares (OLS), weighted least-squares (WLS), and maximum likelihood fitting (MLF) were evaluated and, as a case study, X-ray fluorescence (XRF) calibration curves for major elements in geochemical reference materials were used. The results showed that WLS and MLF models were statistically more consistent in comparison with the usually applied OLS approach. The use of uncertainty on independent and dependent variables during the calibration process and the calculation of final uncertainty on individual results using error propagation equations are the novel aspects of our work.     

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.     

Structural Alignment Methods with Applications to Geospatial Ontologies

We consider the problem of enabling interoperability and information sharing among geospatial applications that use ontologies to describe their concepts and the relationships among them. We present two fully automatic alignment methods that use the graph structures of a pair of ontologies to establish their alignment, that is, the semantic correspondences between their concepts. We have tested our methods on geospatial ontologies pertaining to wetlands and four other pairs that belong to a repository that has been used in the Ontology Alignment Evaluation Initiative (OAEI). Using these ontologies, we have compared the effectiveness (precision and recall) of our methods against the Similarity Flooding Algorithm that was proposed by others and show that for each of the tested ontologies one of our methods is at least as effective as their method. We have tuned the performance of our methods by introducing a greedy approach that reduces the number of concepts that get compared. This approach reduces runtime by approximately 30% with a minor compromise to the effectiveness of the results. To further validate our approach, we participated in the OAEI competition to align a pair of ontologies, each with a few thousand concepts.     

Long term variation in rainfall erosivity in Uruguay: a preliminary Fournier approach

In order to explore the consequences of precipitation increase on soil erosion in Uruguay, the monthly Fournier Index (FI) and the annual Modified Fournier Index (MFI) were developed as a preliminary approach, covering consecutive decadal periods from 1931 to 2000. Rainfall data were used from 13 stations distributed all over the country. MFI shows a decrease in the 1940s, an increase during the 1950s, then a little decrease during the 1960s and 1970s and an increase in the 1980s, remaining near these last values during the 1990s. FI behavior in July and October in the last two decades shows a decrease in the Northeast region of the country—the region with highest annual precipitation—and a slight increase over the Southeast—the region with the lowest annual precipitation and the only region with a winter rainfall maximum. For the core months of winter and early spring there is a decline in erosivity in the Northeast, but an increase in the Southeast. January shows erosivity decreasing in the South during the last two decades. In April there is a peak in precipitation variability all across the country. FI shows an early increase during the 1940s in the Northwest, and generally very low values during the 1970s, with the return of high values in the 1990s, especially in the Northern corner. Results pose a challenge in order to improve research on the erosion problem, since the main source of freshwater nationwide remains surface river flow, which is prone to higher turbidity problems in areas of high soil erosion.     

Experimental study of friction dissipators for seismic protection of building structures

This paper presents the results from unidirectional shaking table tests of two reduced scale steel models of a building frame, with one and two floors, respectively. These frames incorporate friction dissipators at every floor. The inputs are sine-dwells and artificial and registered earthquakes. This study is part of a larger research project aiming to assess the seismic efficiency of friction dissipators by means of an integrated numerical and experimental approach. Inside this framework, the main objectives of these experiments are to: (i) collect a wide range of results to calibrate a numerical model derived within the project, (ii) clarify some of the most controversial issues about friction dissipators (including behavior for inputs containing pulses, capacity to reduce resonance peaks, introduction of high frequencies in the response, and self-generated eccentricities), (iii) better understand their dynamic behavior, (iv) provide insight on the feasibility and reliability of using simple friction dissipators for seismic protection of building structures and (v) characterize the hysteretic behavior of these devices. Most of these objectives are satisfactorily reached and relevant conclusions are stated.     

NH4-bearing micas in poly-metamorphic Alpuj��rride micaschists and gneisses from the central zone of the Betic Cordillera (Spain): tectono-metamorphic and crystal-chemical constraints

The content and distribution of NH₄-bearing micas in micaschists and paragneisses of the Alpujárride complex (Betic Cordillera, Spain) are interpreted on the basis of textures, metamorphic history and crystal-chemical constraints. NH₄ is present in important amounts in early micas, recording their older diagenetic-to-metamorphic history. NH₄ was inherited by micas formed in successive metamorphic events. At similar metamorphic grade, annite is enriched in NH₄ relative to muscovite with a fractionation of 4:1. Maximum NH₄ contents were estimated in golden annite from medium-grade schists and in retrogressive annite-chlorite mixed-layers (~1.0?wt.%). A Ti-NH₄ avoidance gives rise to associated chemical changes, such as the enrichment in Mg and in ^VIAl. These data suggest that NH₄ can be a decisive factor in chemical equilibrium and element partitioning between coexisting phases, thus affecting to the commonly used thermobarometers. Estimation of the P-T conditions from texturally different muscovite-annite pairs reveals the superposition of several stages of mica growth, under different geothermal gradients.