Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

On-the-fly server-based aerial imagery management system

Aerial images are valuable products when dealing with both geospatial and geotemporal analysis. Nowadays, they are widely used for many different purposes and by an extensive public, including private companies, official administrations and individual users. Although in the past few years there has been an increasing interest in showing all kinds of geographical information on the World Wide Web, access to aerial imagery and its dissemination are still difficult and lack flexibility. This paper introduces an aerial imagery management system based on client–server principles, operated so as to allow users quick and efficient queries, processing and management of huge sets of photogrammetric imagery stored on raster servers. It is a novel product that is ready to provide image-based cartographic data available in public and private digital warehouses, facilitating all the required visualisations and queries, as well as geometric and radiometric processing on the fly. This paper shows the design, system architecture and various functionalities of the system in a real-life scenario.     

Geomagnetic and Ionospheric Responses to the Interplanetary Shock Wave of March 17, 2015

The propagation of perturbation caused by the interplanetary shock wave of March 17, 2015 from the solar wind through the magnetosheath, magnetosphere, and ionosphere down to the Earth’s surface is analyzed. The onboard satellite measurements, global magnetometer network data, and records by the receivers of the global positioning system (GPS) providing the information about the total electron content (TEC) of the ionosphere are used for the analysis. By the example of this event, various aspects of the influence of the interplanetary shock wave on the near-Earth environment and ground-based engineering systems are considered. It is shown which effects of this influence are well described by the existing theoretical models and which ones need additional research. The formation of the fine structure of the magnetic impulse of the storm sudden commencement (SC)—the preliminary impulse (PI) and main impulse (MI)—is considered. The MI and compression of the magnetospheric magnetic field is observed by the GOES and RBSP satellites and on the geomagnetically conjugate stations; however, the PI was only noted on the Earth. The PI was detected in the afternoon sector practically simultaneously (within 1 min) with the shock wave impact on the magnetopause. The wave’s response to the SC includes the strongly decaying resonant oscillations of the magnetic shells and the magnetoacoustic cavity mode. This study supports the possibility of detecting the ionospheric response to the SC by the GPS method. The TEC response to the MI was detected in the auroral latitudes although not on every radio path. The TEC modulation can be associated with the precipitation of superthermal electrons into the lower ionosphere which is undetectable by riometers. The burst in the intensity of the geomagnetically induced currents caused by an interplanetary shock wave turns out to be higher than the currents during the storm’s commencement, although the SC’s amplitude is noticeably lower than the amplitude of the magnetic bay related to the substorm.     

Assessing food web dynamics and relative importance of organic matter sources for fish species in two Portuguese estuaries: a stable isotope approach

Stable carbon and nitrogen isotopes (δ13C, δ1?N) were used to analyse food web dynamics of two of the main estuaries of the Portuguese coast: Tejo and Mira. The ultimate sources of organic matter supporting production of some of the most abundant and commercially important fish species were determined; and seasonal, inter- and intra- estuarine differences in the trophic relations among producers and consumers were identified. Stable isotope analysis was performed in different producers, primary consumers (main prey items for fish) and fish species (Solea solea, Solea senegalensis, Pomatoschistus microps, Dicentrarchus labrax, Liza ramada, Diplodus vulgaris and Atherina presbyter) of two areas in each estuary, in July and October 2009. Model calculations showed that the main prey for the fish species in the Tejo estuary used mostly salt marsh-derived organic matter as nutritional sources, with no marked differences between the sampled months. Trophic levels of fish species from the same estuary differed at multiple scales: inter-species, seasonally and spatially (both between and within estuaries). Significant differences in isotopic composition of fish species were more pronounced spatially (between the two sampled areas in the estuary) than seasonally (between sampled months). Trophic relationships in both estuaries demonstrated that organic matter is transferred to higher trophic positions mainly through benthic pathways. This shows the flexibility of these species to share resources and to exploit temporary peaks in prey populations. The present results showed that extensive disturbance in intertidal habitats from both estuaries may potentially change the balance of organic matter in the base of these complex food webs.     

Stochastic Simulation Model for the Spatial Characterization of Lung Cancer Mortality Risk and Study of Environmental Factors

This paper presents a study in which the lung cancer risk in males was characterized based on a simulation model of mortality rates. Block sequential simulation of mortality rates, measured in counties of different sizes, was implemented and applied to a normal grid of continental Portugal with high spatial resolution. The uncertainty in the mortality rate measurements, directly related to differences in the population size of each county, was integrated in a block direct sequential simulation through Poisson kriging of local means and variances. Three age groups were examined: 50–59, 60–69, and 70–79 years. After the continuous geographic patterns of lung cancer risk were obtained, factors potentially associated with the main areas of risk were analyzed for southern Portugal. Thus, a defined class of land use and dry weather events, related to airborne particulate matter, were found to be associated with high-risk areas, resulting in high local spatial correlation patterns in all three age groups.     

Limestone Provenance in Roman Lime‐Volcanic Ash Mortars from the Villa dei Quintili,Rome

Roman mortars were collected from the Villa dei Quintili in Rome, an archaeological site consisting of numerous edifices from nine construction phases dating from the 2nd century A.D. to modern times. A multianalytical approach was used on 34 mortar samples to infer the evolution of production techniques over time and to identify the source area of calcareous raw materials used in the preparation of the lime. Optical microscopy, scanning electron microscopy coupled with an energy‐dispersive system, and laser ablation inductively coupled plasma mass spectrometry were used to study the samples. The major and trace element data were compared with the compositions of two types of limestone samples (Calcare Massiccio and Calcare Maiolica) collected from the Cornicolani Mountains. The results suggest that the technological practices and the calcareous raw materials used for lime production remained unchanged over the time period considered (2nd century A.D. to 3rd century A.D.). The compositions of lime‐related particles in the mortars match those of Calcare Maiolica, which suggests its use as raw material for lime production. On the whole, the results are in agreement with data from existing literature regarding both the use by Roman builders of specific raw materials for the mortars’ production and the relative supply area.     

Butyltin compounds,sterility and imposex assessment in Nassarius reticulatus (Linnaeus, 1758), prior to the 2008 European ban on TBT antifouling paints,within Basque ports and along coastal areas

Levels of imposex (superimposition of male characters, upon females) and the presence of sterile females are assessed in the gastropod Nassarius reticulatus (L.), at 35 locations in the Basque Country. At 18 of these localities, organotin bioaccumulation (tributyltin (TBT); dibutyltin; monobutyltin) was evaluated, using isotope dilution GC–ICP–MS. Higher imposex levels and TBT body burden were found in confined harbours, with large vessel traffic or the presence of an offshore fleet. The highest values were found for the port of Pasaia, near to a shipyard (a relative penis size index of up to 92%, and TBT body burden up to 405 ng g^?1 – given on a dry weight basis as Sn). Imposex effects were evaluated also in parasitized females, at some of the sampling sites. The percentage of presence of c-type Vas Deferens sequence stages (i.e., with vas deferens beginning at the oviduct opening) was higher in parasitized females. In turn, there was an absence of highly convoluted oviduct in parasitized females.