Stratigraphy, chemistry, and eruptive dynamics of the 12.4 ka plinian eruption of Apoyeque volcano, Managua, Nicaragua

Apoyeque volcano, located 9 km northwest of Managua city, erupted explosively at 12.4 ka. The Plinian eruption deposited a widespread pumice fall deposit known as the Upper Apoyeque Tephra (UAq). The UAq is massive, reversely graded, and consists of white juvenile pumice (~78 vol.%), a variety of cognate lithics and accidental altered lithics. The whole-rock pumice composition is rhyodacitic (SiO₂?=?66.9–68.5 wt.%) with a mineral paragenesis of plagioclase, orthopyroxene, clinopyroxene, amphibole, titanomagnetite, and ilmenite in a rhyolitic glass groundmass (SiO₂?=?74.4?±?0.6 wt.%). The deposit’s dispersal axis is to the south, with the deposit covering a minimum area of 877 km² within the 50 cm isopach and has a total volume of 3 km³ (dense rock equivalent, 1.15 km³). The eruption column reached a maximum height of ca.28 km. The eruption ejected a total mass of 3?×?10¹² kg at an average rate of 2?×?10⁸ kg/s, and based on available models, we infer duration of almost 4 h. Petrographic and geochemical characteristics suggest that the eruption was triggered by magma mixing.     

Chlorophyll a Biomass of Netplankton in Surface Waters in the Pacific Sector of the Southern Ocean in Austral Summer

Chlorophyll a of total and particles retained on 30 μm mesh plankton net were both determined in surface waters along two cruise tracks ranging from the Subtropical water to the marginal ice zone in the Pacific sector of the Southern Ocean in austral summer. Total surface chlorophyll a in the study area was mostly less than 1 μg chl a 1⁻¹, and showed distributions with no obvious trend associated with different waters masses of the Antarctic and the Subantarctic, although total chlorophyll a concentrations changed greatly within each water mass. Particularly low concentrations of chlorophyll a were detected in the marginal ice zone. Chlorophyll a contained in 30 μm netplankton made up 5∼60% of total chlorophyll a: large near the marginal ice zone and becoming small with travel towards the north. High percentage shares of netplankton chlorophyll a were confirmed even in low total chlorophyll a concentrations in summer in the Southern Ocean. A positive relation was observed between the percentage of 30 μm netplankton and the “average total chlorophyll a”, although there was great scatter. This revised version was published online in August 2006 with corrections to the Cover Date.     

Late Cenozoic magnetostratigraphy (11 – 0 Ma) of the Dongshanding and Wangjiashan sections in the Longzhong Basin,western China

A paleomagnetic study of the 510-m-thick Wangjiashan section of Late Miocene and Pliocene terrestrial sediments reveals a fairly complete reversal record with ages from 11 to 1.8 Ma. The magnetostratigraphy of the Dongshanding section, located nearby, reveals a partially overlapping reversal record with ages from 2.2 to 0 Ma, and facilitates correlation of the Wangjiashan section with the global polarity time scale. A new stratigraphic division of the Wangjiashan section replaces the name Linxia formation by five new formation names, based on lithologic variation and mammalian fossil finds. The new formations and their magnetostratigraphically determined ages are: Dongshan Formation (c. 1.75–2.6 Ma), Jishi Fm. (c. 2.6–3.6 Ma), Hewangjia Fm. (4.5–6.0 Ma), Liushu Fm. (6.0–7.6 Ma), and Dongxiang Fm. (7.6–c. 12 Ma). The Neogene stratigraphy and fossil mammals suggest that the nearby part of the Tibetan Plateau experienced a persistent denudation during the Late Miocene and Early Pliocene, but that it was uplifted more rapidly at about 3.6 Ma.     

Effect of solar radiation and the subsequent dark periods on two newly isolated and characterized Antarctic marine bacteria

Two strains of psychrotolerant Antarctic marine bacteria were isolated and characterized using biochemical and molecular techniques. Sequencing of 16S rRNA gene showed that UVvi strain belongs to the genus Arthrobacter whereas UVps strain is related to the Flexibacter-Cytophaga-Bacteroides (FCB) group. Response of the strains to solar radiation was studied during the summer of 1999 in Potter Cove, near Jubany station (South Shetland Island, Antarctica). The effect of photosynthetically available radiation (PAR, 400-700 nm), ultraviolet-A (UV-A, 320-400 nm) and ultraviolet-B radiation (UV-B, 280-320 nm) on cell viability was studied using mixed cultures in quartz bottles covered with interferential filters and exposed to solar radiation. In all experiments, four treatments were used: dark (with light screened out), PAR (with UV radiation screened out), PAR+UV-A (UV-B screened out) and PAR+UV-A+UV-B. Under the assayed conditions, PAR+UV-A and PAR+UV-A+UV-B radiation showed similar negative effects on the viability of the studied strains. However, at the end of the exposure time, mortality values in PAR+UV-A+UV-B treatments were higher than those observed under PAR+UV-A treatments. In both PAR+UV-A and PAR+UV-A+UV-B treatments we observed high levels of hydrogen peroxide compared with the dark control. The Arthrobacter UVvi strain showed significant recovery in dark conditions after exposure to the PAR+UV-A but not after the PAR+UV-A+UV-B treatment. This strain proved to be more resistant to UV radiation than the FCB group-related UVps strain. The results showed that UV radiation has a deleterious effect on these Antarctic marine bacteria and also revealed that the analysed components of the Antarctic bacterioplankton may have different responses when they are exposed to the same irradiance conditions.     

Effect of isolation temperature on the characteristics of extracellular proteases produced by Antarctic bacteria

Protease-producing psychrotolerant bacteria were isolated from Antarctic biotopes on casein agar plates using different incubation temperatures. Most of the isolates were non-spore-forming Gram-negative motile rods with catalase activity, 30% were pigmented and none of them were glucose fermenters. All the strains were grown in liquid cultures at 20°C and protease secretion was tested using the azocasein method. Despite their capacity for production of a clear zone of hydrolysis in agar plates, some strains did not produce detectable levels of proteolytic activity in liquid cultures. The lowest apparent optimum temperature for protease activity found in culture supernatants was 40°C. Almost all the strains showed activation energy values about 10-20 kJ-mol⁻¹ lower than that observed for a mesophilic Subtilisin. Most of the proteases showed optimal activity at neutral or alkaline pH values and developed a multiple-band profile on gelatine-SDS-PAGE. It was observed that the lower the strain isolation temperature was, the more stongly cold-adapted–in terms of optimal temperature and activation energy–were the proteases produced by them. This dependence of the characteristics of the proteases on the isolation temperature is an important factor to take into account in the design of screening programmes directed towards the isolation of psychrotolerant bacteria able to produce proteases strongly or weakly adapted to work in the cold. The Antarctic area explored proved to be a promising source of proteolytic bacteria with potential use in industrial processes to be carried out at low or moderate temperatures.     

The Decay of Supersonic and Super-Alfvénic Turbulence in Star-Forming Clouds

Supersonic and super-Alfvénic turbulent motions generate an intricate pattern of shock waves through which the turbulence decays. We here illustrate the spatial structure during shock formation and decay. This revised version was published online in July 2006 with corrections to the Cover Date.     

Comparative study of the kinetics of the thermal decomposition of synthetic and natural siderite samples

The mechanism of the thermal decomposition of two siderites (a pure synthetic and a natural Mg-containing sample) has been determined from comparison of the results obtained from linear heating rate (TG) and constant rate thermal analysis (CRTA) experiments in high vacuum. The thermal decomposition of the synthetic siderite takes place approximately 200 K below the decomposition temperature of the natural sample. The mechanism and the product of the thermal decomposition are different for the siderite samples. In fact, an A₂ kinetic model describes the thermal decomposition of the synthetic siderite, whereas the thermal decomposition of the natural sample obeys an F₁ kinetic law. Decomposition products of the synthetic siderite are iron and magnetite, those of the natural siderite are wüstite and minor magnetite. Received: 22 July 1999 / Accepted: 12 February 2000     

Wavelet-multivariate relevance vector machine hybrid model for forecasting daily evapotranspiration

Evapotranspiration (ET) is one of the main components of the hydrological cycle. It is a complex process driven mainly by weather parameters, and as such, is characterized by high non-linearity and non-stationarity. This paper introduces a methodology combining wavelet multiresolution analysis with a machine learning algorithm, the multivariate relevance vector machine (MVRVM), in order to predict 16 days of future daily reference evapotranspiration (ETo). This methodology lays the ground for forecasting the spatial distribution of ET using Landsat satellite imagery, hence the choice of 16 days, which corresponds with the Landsat overpass cycle. An accurate prediction of daily ETo is needed to improve the management of irrigation schedules as well as the operations of water supply facilities like canals and reservoirs. In this paper, various wavelet decompositions were performed and combined with MVRVM to develop hybrid models to predict ETo over a 16-days period. These models were compared to a MVRVM model, and models accuracy and robustness were evaluated. The addition of 10 days of forecasted air temperature as additional inputs to the forecasting models was also investigated. The results of the wavelet-MVRVM hybrid modeling methodology showed that a reliable forecast of ETo up to 16 days ahead is possible.