Pre‐drill Groundwater Geochemistry in the Karoo Basin,South Africa

Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin.     

The Influences of NAO and the Hudson Bay sea-ice on the climate of eastern Canada

Sea-ice cover over the Hudson Bay (HB) exhibits large variability in the freeze-up season normally starting in November. Its influence on the climate over eastern Canada has been studied with the Canadian Regional Climate Model (CRCM) in three steps. First, a 30-year continuous simulation from 1970 to 1999 was performed as a control run to evaluate the simulated climate variability over eastern Canada, in particularly variability associated with the North Atlantic oscillation (NAO). Then, 50 additional 1 month experiments were performed with modified sea-surface conditions prescribed over the HB. These integrations allowed us to quantify the contribution of HB sea-ice anomalies versus large scale NAO atmospheric variability (as defined by prescribed lateral boundary conditions) in inducing climate variability over eastern Canada. Results show that the NAO is the dominant factor controlling climate variability over eastern Canada. The contribution of HB sea-ice anomalies is significant only in the immediate coastal region. Under the influence of different phases of NAO, HB sea-ice anomalies do co-vary with temperature and precipitation anomalies downstream of the HB over eastern Canada. The ultimate cause of this co-variability is NAO variability which forces variability in both HB sea-ice cover as well as temperature/precipitation over eastern Canada.     

Cyclicity in the late Precambrian Elatina Formation,South Australia: Solar or tidal signature?

New observations from two late Precambrian (~800-650 Ma) sedimentary rhythmites in South Australia (Reynella Siltstone and Chambers Bluff Tillite) reveal cycles structurally similar to the ~12-laminae cycles of the ~650-Ma Elatina Formation but which comprise from 15 to 26 or more laminae. The new data are difficult to accomodate in depositional models for the Elatina Formation whereby its laminae are regarded as annual and the cyclicity ascribed to solar variability (Williams and Sonett, 1985) or to the combined influences of the sunspot cycle and the lunar nodal tide (Zahnle and Walker, 1987). If, however, the long-term Elatina Cycle and not the individual lamina is taken as a yearly climatic signal, the Elatina and other rhythmites studied may be interpreted as the deposits of marine ebb-tidal deltas that record variability in the velocity and range of paleo-ebb tides. The basic laminae-cycles would represent lunar fortnightly cycles of diurnal and/or semidiurnal laminae, commonly truncated through non-deposition at neap tides. Despite numerous empirical similarities between the Elatina and sunspot series, the ebb-tidal model for deposition is preferred because it accounts plausibly for observations from all three rhythmites studied.     

Pollen representation,source area,and basin size: Toward a unified theory of pollen analysis

The concepts of pollen source area and of production and dispersal biases in pollen representation are quantified by means of a simple theoretical model. Source areas and relative pollen representation are shown to depend on basin size according to functions that describe the amount of pollen remaining airborne at increasing distances from single pollen sources. The form of these functions is determined by physical processes. Standard formulas for elevated sources do not apply, but the integrated form of Sutton's equation for particle dispersal from a ground-level source gives useful approximations applicable to pollen transport over a forest canopy. Simulations using this equation yielded source areas that increased realistically with basin size, showed substantial differences between source areas for pollen grains with different deposition velocities, and predicted that lighter pollen grains should become better represented with increasing basin size. All of these predictions are qualitatively consistent with present knowledge of the characteristics of pollen assemblages in different depositional environments. The model further allows parameters that can be estimated by statistical calibration methods to be predicted from underlying physical quantities. This extension suggests procedures for testing the theory with quantitative data on surface pollen and forest composition. Preliminary results showed reasonable agreement between estimated and predicted values of dispersal indices for the most abundant taxa in pollen spectra from the northern midwestern United States.     

Dynamic model of flotation cell banks — circuit analysis

While all mineral industry flotation circuits are stable, they are sensitive to low-frequency perturbations in the feedrate. In both countercurrent and cocurrent circuits, the lead cell is more sensitive to feed variations. The frequency response predicts the amount of extra cell capacity needed to handle the maximum feed due to a sinusoidal forcing function. Feedback loops are more significant than sump delays. The countercurrent $\text{4 × 4}$ circuit floating quartz, with a 200-sec retention time, requires 75 minutes for the concentration of quartz in the input to the first cell to reach 95% of its steady-state value. Countercurrent circuits were found superior to cocurrent circuits in all respects.