Hydrocarbons generated by hydropyrolysis of suspended marine particulate organic matter: Relationship to the oceanography of the Black Sea and the Rhodes Gyre

The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C₁₈, hypothesised to arise predominantly from unsaturated C₁₈ fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.     

Glaciation and deglaciation of the SW Lake District,England: implications of cosmogenic 36Cl exposure dating

Exposure dating using cosmogenic ³⁶Cl demonstrates that the summit plateau of Scafell Pike (978 m) in the SW Lake District escaped erosion by glacier ice during the last glacial maximum (LGM; c. 26–21 kyr) and probably throughout the Devensian Glacial Stage (MIS 5d-2). Exposure ages obtained for ice-moulded bedrock on an adjacent col at 750–765 m confirm over-riding and erosion of bedrock by warm-based glacier ice during the LGM. The contrast between the two sites is interpreted in terms of preservation of tors, frost-shattered outcrops and blockfields on terrain above 840–870 m under cold-based ice. An exposure age of 17.3 ± 1.1 kyr for the col at 750–765 m suggests that substantial downwastage of the last ice sheet had occurred by c. 17 kyr, consistent with deglacial exposure ages obtained for other high-level sites in the British Isles. An exposure age of 12.5 ± 0.8 kyr obtained for a glacially transported rockfall boulder within the limits of later corrie glaciation confirms that the final episode of local glaciation in the Lake District occurred during the Loch Lomond Stade (c. 12.9–11.7 kyr). This research also demonstrated the difficulties of obtaining reliable exposure ages from rhyolite and andesite bedrock that has proved resistant to glacial abrasion.     

A 1D microphysical cloud model for Earth,and Earth-like exoplanets: Liquid water and water ice clouds in the convective troposphere

One significant difference between the atmospheres of stars and exoplanets is the presence of condensed particles (clouds or hazes) in the atmosphere of the latter. In current 1D models clouds and hazes are treated in an approximate way by raising the surface albedo, or adopting measured Earth cloud properties. The former method introduces errors to the modeled spectra of the exoplanet, as clouds shield the lower atmosphere and thus modify the spectral features. The latter method works only for an exact Earth-analog, but it is challenging to extend to other planets.The main goal of this paper is to develop a self-consistent microphysical cloud model for 1D atmospheric codes, which can reproduce some observed properties of Earth, such as the average albedo, surface temperature, and global energy budget. The cloud model is designed to be computationally efficient, simple to implement, and applicable for a wide range of atmospheric parameters for planets in the habitable zone.We use a 1D, cloud-free, radiative–convective, and photochemical equilibrium code originally developed by Kasting, Pavlov, Segura, and collaborators as basis for our cloudy atmosphere model. The cloud model is based on models used by the meteorology community for Earth’s clouds. The free parameters of the model are the relative humidity and number density of condensation nuclei, and the precipitation efficiency. In a 1D model, the cloud coverage cannot be self-consistently determined, thus we treat it as a free parameter.We apply this model to Earth (aerosol number density 100 cm^?3, relative humidity 77%, liquid cloud fraction 40%, and ice cloud fraction 25%) and find that a precipitation efficiency of 0.8 is needed to reproduce the albedo, average surface temperature and global energy budget of Earth. We perform simulations to determine how the albedo and the climate of a planet is influenced by the free parameters of the cloud model. We find that the planetary climate is most sensitive to changes in the liquid water cloud fraction and precipitation efficiency.The advantage of our cloud model is that the cloud height and the droplet sizes are self-consistently calculated, both of which influence the climate and albedo of exoplanets.     

An array of lens-coupled antennas for cosmic microwave background measurements in the 30 Ghz band

An array of bow-tie slot antennas coupled through an extended hemispherical lens is proposed to operate in the 30?GHz frequency band. The design includes a combination of three microstrip Wilkinson power dividers (WPD) and transitions to coplanar wave guides (CPW) to form the feeding antenna network. This configuration is suitable for the integration with heterodyne imaging detectors commonly used in radioastronomy. Measurements and simulation results exhibit a frequency range of operation from 20 to 40?GHz with a bandwidth of 24% achieved for ?10?dB return loss at the central frequency. The measured radiation patterns show a maximum peak gain of around 13?dB with HPBW of 10° for the E-plane, and whose first side lobes are lower than 13?dB below the main lobe in both angular shift sides. The presented results will be considered as preliminary feasibility studies in the 30?GHz QUIJOTE-CMB Instrument, which is designed to study the anisotropies of the Cosmic Microwave Background (CMB).     

Reef-island topography and the vulnerability of atolls to sea-level rise

Low-lying reef islands on the rim of atolls are perceived as particularly vulnerable to the impacts of sea-level rise. Three effects are inferred: erosion of the shoreline, inundation of low-lying areas, and saline intrusion into the freshwater lens. Regional reconstruction of sea-level trends, supplementing the short observational instrumental record, indicates that monthly mean sea level is rising in the eastern Indian and western Pacific Oceans. This paper reviews the morphology and substrate characteristics of reef islands on Indo-Pacific atolls, and summarises their topography. On most atolls across this region, there is an oceanward ridge built by waves to a height of around 3 m above MSL; in a few cases these are topped by wind-blown dunes. The prominence of these ridges, together with radiocarbon dating and multi-temporal studies of shoreline position, indicate net accretion rather than long-term erosion on most of these oceanward shores. Less prominent lagoonward ridges occur, but their morphology and continuity are atoll-specific, being a function of the processes operating in each lagoon. Low-lying central areas are a feature of many islands, often locally excavated for production of taro. These lower-lying areas are already subject to inundation, which seems certain to increase as the sea rises. Tropical storms play an important role in the geomorphology of reef islands in those regions where they are experienced. Topographical differences, as well as features such as emergence of the reef flat and the stability of the substrate, mean that islands differ in terms of their susceptibility to sea-level rise. Further assessment of variations in shoreline vulnerability based on topography and substrate could form the basis for enhancing the natural resilience of these islands.     

Dark matter accretion wakes of high-redshift black holes

Anisotropic emission of gravitational waves during the merger of black holes induces a recoil velocity on the centre of mass of the binary and the final merger product can then be ejected from its host galaxy. We consider ejected black holes which stay on bound orbits around their host haloes. A recoiled black hole which moves on an almost radial orbit outside the virial radius of its central galaxy, in the cold dark matter background, reaches its apapsis in a finite time. Due to small dark matter velocity dispersion at high redshifts and also the small black hole velocity near the apapsis passage a high-density wake forms around these black hole. Gamma-ray emission can result from the enhancement of dark matter annihilation in these wakes. The diffuse high-energy gamma-ray background from the ensemble of such black holes in the Hubble volume is also evaluated.     

Stormwater control impacts on runoff volume and peak flow: A meta-analysis of watershed modelling studies

Decades of research has concluded that the percent of impervious surface cover in a watershed is strongly linked to negative impacts on urban stream health. Recently, there has been a push by municipalities to offset these effects by installing structural stormwater control measures (SCMs), which are landscape features designed to retain and reduce runoff to mitigate the effects of urbanisation on event hydrology. The goal of this study is to build generalisable relationships between the level of SCM implementation in urban watersheds and resulting changes to hydrology. A literature review of 185 peer-reviewed studies of watershed-scale SCM implementation across the globe was used to identify 52 modelling studies suitable for a meta-analysis to build statistical relationships between SCM implementation and hydrologic change. Hydrologic change is quantified as the percent reduction in storm event runoff volume and peak flow between a watershed with SCMs relative to a (near) identical control watershed without SCMs. Results show that for each additional 1% of SCM-mitigated impervious area in a watershed, there is an additional 0.43% reduction in runoff and a 0.60% reduction in peak flow. Values of SCM implementation required to produce a change in water quantity metrics were identified at varying levels of probability. For example, there is a 90% probability (high confidence) of at least a 1% reduction in peak flow with mitigation of 33% of impervious surfaces. However, as the reduction target increases or mitigated impervious surface decreases, the probability of reaching the reduction target also decreases. These relationships can be used by managers to plan SCM implementation at the watershed scale.     

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.     

On the linear elastic responses of the 2D bonded discrete element model

The bonded discrete element model (DEM) is a numerical tool that is becoming widely used when studying fracturing, fragmentation, and failure of solids in various disciplines. However, its abilities to solve elastic problems are usually overlooked. In this work, the main features of the 2D bonded DEM which influence Poisson's ratio and Young's modulus, and accuracy when solving elastic boundary value problems, are investigated. Outputs of numerical simulations using the 2D bonded DEM, the finite element method, a hyper elasticity analysis, and the distinct lattice spring model (DLSM) are compared in the investigation. It is shown that a shear interaction (local) factor and a geometric (global) factor are two essential elements for the 2D bonded DEM to reproduce a full range of Poisson's ratios. It is also found that the 2D bonded DEM might be unable to reproduce the correct displacements for elastic boundary value problems when the represented Poisson's ratio is close to 0.5 or the long-range interaction is considered. In addition, an analytical relationship between the shear stiffness ratio and the Poisson's ratio, derived from a hyper elasticity analysis and applicable to discontinuum-based models, provides good agreement with outputs from the 2D bonded DEM and DLSM. Finally, it is shown that the selection of elastic parameters used the 2D bonded DEM has a significant effect on fracturing and fragment patterns of solids.