GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

High resolution absorption cross-section measurements of ozone at 195 K in the wavelength region 240–350 nm

Cross-sections of the Hartley-Huggins bands of 03 at the temperature 195 K have been obtained from photoabsorption measurements at column densities in the range 2 × 10¹⁷?1 × 10²¹ cm^?2 throughout the wavelength region 240–350 nm with a 6.65 m photoelectric scanning spectrometer equipped with a 2400 lines mm^?1 grating and operated at an instrumental width (FWHM) of 0.003 nm. The assumptions made in putting the measured relative cross-sections on an absolute basis are discussed. Fine structure in the cross-section observed in the Huggins bands is illustrated in the region 323–327 nm where shallow features of width 0.01–0.02 nm occur superposed on a stronger apparent continuum exhibiting broader wavy structure.     

Monitoring changes of ice streams using time series of satellite-altimetry-based digital terrain models

The Antarctic Ice Sheet plays a major role in the global system, and the large ice streams discharging into the circumpolar sea represent its gateways to the world’s oceans. Satellite radar altimeter data provide an opportunity for mapping surface elevation at kilometerresolution with meteraccuracy. Geostaristical methods have been developed for the analysis of these data. Applications to Seasat data and data from the Geosat Exact Repeat Mission indicate that the grounding line of Lambert Glacier/Amery Ice Shelf, the largest ice stream in East Antarctica, has advanced 10–12 km between 1978 and 1987–89. The objectives of this paper are to explore possibilities and limitations of satellite-altimetry-based mapping to capture changes for shorter time windows and for smaller areas, and to investigate some methodological aspects of the data analysis. We establish that one season of radar altimeter data is sufficient for constructing a map. This allows study of interannual variation and is the key for a limeseries analysis approach to study changes in ice streams. Maps of the lower Lambert Glacier and the entire Amery Ice Shelf are presented for austral winters 1978, 1987, 1988, and 1989. As a first step toward understanding the dynamics of the ice-stream/iceshelf system, elevation changes are calculated for grounded ice, the grounding zone, and floating ice. In the absence of (sufficient) surface gravity control for the Lambert Glacier/Amery Ice Shelf area, altimetry-based maps may facilitate improvement of geoid models as they provide constraints on the terrain correction in the inverse gravimetric problem.     

Mobile Learning in a Human Geography Field Course

This article reports on reusable mobile digital learning resources designed to assist human geography undergraduate students in exploring the geographies of life in Dublin. Developing active learning that goes beyond data collection to encourage observation and thinking in the field is important. Achieving this in the context of large class sizes presents several challenges. Combining in situ learning with spatially accurate historical and contemporary multimedia, a set of location-aware digital mobile tools, or mediascapes, was developed. How scaffolding can be achieved in such a context, focusing on the development of students’ observational, enquiry, and thinking skills in the field was explored.     

Morphological variation of Stephanodiscus niagarae Ehrenb. (Bacillariophyta) in a Lake Ontario sediment core

Stephanodiscus niagarae populations in a core from Lake Ontario show systematic variation in radial puncta number and mean valve diameter. Puncta number is stable in specimens from samples deposited between 1720 and 1844. Puncta number gradually increases in samples deposited between 1860 and 1947, then increases rapidly to high numbers in samples deposited after 1964. Mean valve diameter is relatively high in specimens from samples deposited between 1720 and 1959. Diameter of specimens deposited during this period fluctuates around a mean of 63.2 m. Mean diameter of specimens deposited from 1959 to 1980 is only 42.5 m. We conclude that the trend in puncta number reflects the time course of eutrophication in Lake Ontario. We interpret the precipitous decline in mean diameter as an indication that conditions in the lake after the late 1950's did not permit sexual reproduction in this species.     

Piltdown Man's ‘Treasure Map’

The ‘Maresfield Map’ is a map that purports to show features pertinent to the old iron industry in the Sussex Weald of southern England in 1724. It first appeared in a journal published by the Sussex Archaeological Society in early 1913, at roughly the same time as the formal publication by the Geological Society of London of papers introducing the discovery of the ‘remains’ of what became known as ‘Piltdown Man’ to the world. Piltdown Man was eventually revealed as fraudulent in 1953, followed by the Maresfield Map in 1974. Experiments in replication now show that the Maresfield Map is a sort of ‘treasure map’ (in a negative sense), which points fairly accurately to the supposed find‐spot of Piltdown Man, along with a coded accusation against Charles Dawson. The map's compiler is thought to have been L.F. Salzmann, the editor of the journal in which the map appeared. As such, the map represents the only such denunciation to have been published in the open literature in Dawson's lifetime, albeit a cryptic one. Mr Salzmann's possible motives are explored.