Aeromagnetic surveying using a simulated unmanned aircraft system

Carleton University and Sander Geophysics are developing an unmanned aircraft system (UAS) for aeromagnetic surveying. As an early indication of the expected performance of the unmanned aircraft system, a simulated unmanned aircraft system (sUAS) was built. The simulated unmanned aircraft system is a T‐shaped structure configured as a horizontal gradiometer with two cesium magnetometers spaced 4.67 m apart, which is the same sensor geometry as planned for the unmanned aircraft system. The simulated unmanned aircraft system is flown suspended beneath a helicopter. An 8.5 km² area in the Central Metasedimentary Belt of the Grenville Province, near Plevna, Ontario, Canada, was surveyed with the simulated unmanned aircraft system suspended 50 m above ground. The survey site was chosen on the basis of its complex geological structure. The total magnetic intensity (TMI) data recorded were compared to that obtained during a conventional fixed‐wing survey and a ground survey. Transverse magneto‐gradiometric data were also recorded by the simulated unmanned aircraft system. The simulated unmanned aircraft system total magnetic intensity data have a higher resolution than the conventional fixed‐wing data and were found to have a similar resolution to that of the ground survey data. The advantages of surveying with the simulated unmanned aircraft system were: (1) the acquisition of a detailed data set free of gaps in coverage at a low altitude above the terrain and (2) substantial saving of time and effort. In the survey site, the 4.67 m simulated unmanned aircraft system gradiometer measured the transverse magnetic gradient reliably up to an altitude of 150 m above ground.     

Observations of water vapor ions at the lunar surface

The Apollo 14 Suprathermal Ion Detector Experiment observed a series of bursts of 48.6 eV water vapor ions at the lunar surface during a 14-h period on March 7, 1971. The maximum flux observed was 10⁸ ions cm^–2 s^–1 sr^–1. These ions were also observed at Apollo 12, 183 km to the west. Evaluation of specific artificial sources including the Apollo missions and the Russian Lunokhod leads to the conclusion that the water vapor did not come from a man-made source. Natural sources exogenous to the Moon such as comets and the solar wind are also found to be inadequate to explain the observed fluxes. Consequently, these water vapor ions appear to be of lunar origin.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Transfrontier macroseismic observations of the Ml = 5.4 earthquake of February 22, 2003 at Rambervillers,France

The 2003 Ml = 5.4 Rambervillers earthquake, north-east of France, is the largest seismic event recorded north of the Alps since the 1992 Ms = 5.3, I₀ = VII, Roermond earthquake, Netherlands. With a maximum macroseismic intensity of VI-VII EMS-98, the 2003 event was broadly felt to a distance of 300 km from the epicentre. It provides a unique opportunity to test and compare the different procedures used in France, Germany and Switzerland when evaluating macroseismic intensities. The main purpose of this paper is to present a common transfrontier macroseismic map based on the EMS-98 intensity scale. Maximum horizontal accelerations recorded in the area are compared to the intensity values, and we propose to use a differential technique to re-estimate the magnitude of the 1682 Remiremont, I₀ = VIII, earthquake, which occurred 40 km south of Rambervillers.     

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates

The martian orbital and landed surface missions, OMEGA on Mar Express and the two Mars Explorations Rovers, respectively, have yielded evidence pointing to the presence of magnesium sulfates on the martian surface. In situ identification of the hydration states of magnesium sulfates, as well as the hydration states of other Ca- and Fe- sulfates, will be crucial in future landed missions on Mars in order to advance our knowledge of the hydrologic history of Mars as well as the potential for hosting life on Mars. Raman spectroscopy is a technique well-suited for landed missions on the martian surface. In this paper, we report a systematic study of the Raman spectra of the hydrates of magnesium sulfate. Characteristic and distinct Raman spectral patterns were observed for each of the 11 distinct hydrates of magnesium sulfates, crystalline and non-crystalline. The unique Raman spectral features along with the general tendency of the shift of the position of the sulfate ν₁ band towards higher wavenumbers with a decrease in the degree of hydration allow in situ identification of these hydrated magnesium sulfates from the raw Raman spectra of mixtures. Using these Raman spectral features, we have started the study of the stability field of hydrated magnesium sulfates and the pathways of their transformations at various temperature and relative humidity conditions. In particular we report on the Raman spectrum of an amorphous hydrate of magnesium sulfate (MgSO₄·2H₂O) that may have specific relevance for the martian surface.     

Timing of diagenetic haematite growth in red pelagic limestones from Gubbio (Italy)

Magnetite, haematite, and to a minor extent maghaemite are recognised in the Cretaceous and Paleocene red pelagic limestones at Gubbio. The magnetite is detrital (or biological), whereas the haematite grew during diagenesis from a goethitic precursor. Thermal and AF demagnetization of samples collected from close to reversal boundaries indicate that the various magnetization components do not record the polarity reversal at exactly the same stratigraphic level. In the few tens of centimetersbelow a recorded geomagnetic reversal, defined by the magnetite magnetization, some of the haematite grains are magnetized in the post-reversal field. The blocking temperature spectra of this haematite fraction (with post-reversal magnetization) are found to shift toward higher temperatures as the reversal boundary is approached. The blocking temperature spectra reflect the grain size spectra of the haematite, which we interpret as arising by the continual nucleation of grains down to a certain burial depth where the conditions are no longer conducive to further haematite growth. The depth below reversal boundaries to which haematite with post-reversal magnetization can occur, is estimated to be about 60 cm (after compaction), and is equivalent to a time of about 10⁵ years for these particular sediments. A detailed study of the magnetization components at reversal boundaries indicates that the first diagenetic growth of haematite through the single-domain critical volume occurs prior to the mechanical fixation of the detrital (or biological) magnetite. Subsequently the diagenetic haematite grains do not rotate in response to the ambient geomagnetic field polarity as easily as the magnetite, because of their occurrence as pigmentary coatings on larger non-magnetic grains.     

Temporal changes in the contribution of methane-oxidizing bacteria to the biomass of chironomid larvae determined using stable carbon isotopes and ancient DNA

Freshwater lakes are important sources of methane (CH₄) emissions, by organic matter degradation under anaerobic conditions (methanogenesis). Previous studies suggest that lakes contribute up to 16 % of natural emissions. About 60 % of the CH₄ produced is used as an energy source by methane-oxidizing bacteria (MOB—methanotrophs), which could support higher trophic levels, especially Chironomidae (Diptera). Because biogenic methane has a very low stable carbon isotope value, evidence of methane-derived organic-matter assimilation can be tracked by stable carbon isotope analysis in consumers such as chironomids. In some cases, however, chironomid δ¹³C values are not low enough to unambiguously demonstrate methanotroph assimilation and an alternative line of evidence is required. Analysis of ancient DNA (aDNA) from the methanotroph community preserved in lake sediment provides reliable information about past methane oxidation in freshwater lakes. A combination of these two approaches was used to study a sediment core from the deepest zone of Lake Narlay (Jura, France), which covers the last 1,500 years of sediment accumulation. Results show a significant change ca. AD 1600, with an increase in the proportion of MOB in the total bacteria community, and a decrease in chironomid head-capsule δ¹³C. These trends suggest assimilation of MOB by chironomid larvae, and account for up to 36 % of the chironomid biomass. The data also provide information about the feeding behavior of chironomids, with evidence for preferential assimilation of methanotroph type I and the NC10 phylum. The combination of aDNA analysis and carbon stable isotopes strengthens the reliability of inferences about carbon sources incorporated into chironomid biomass.     

Assessment of the climate preparedness of 30 urban areas in the UK

Cities are increasingly aware of the need to mitigate greenhouse gas emissions and adapt to changes in weather patterns leading to the production of urban climate change plans. The few existing systematic studies of these plans have focused on either adaptation or mitigation issues, and are typically based on surveys completed by city officials rather than analysis of documented evidence. To gain insight into the status of adaptation and mitigation action across the UK, climate change documents from 30 urban areas (representing ~28 % of the UK’s population) were analysed. An Urban Climate Change Preparedness Score, which could be applied to other urban areas outside the UK, has been devised for comparative analysis. This analysis characterizes progress against (i) Assessment, (ii) Planning, (iii) Action, and (iv) Monitoring, for both adaptation and mitigation. The Preparedness Score allows a quantitative comparison of climate change strategies across the urban areas analysed. This methodology can be transferred to other countries and makes an international comparison of urban areas and their climate change adaptation and mitigation plans possible. We found that all areas acknowledge climate change being a threat and that adaptation and mitigation planning and action is required. However, two urban areas did not have official adaptation or mitigation plans. Typically, mitigation activities across all cities were more advanced than adaptation plans. Emissions reduction targets ranged from 10 %–80 % with differing baselines, timeframes and scopes, for defining and meeting these targets. Similar variability was observed across adaptation plans. Several reasons for these differences are considered, but particularly notable is that a combination of incentives and regulation seem to stimulate more comprehensive strategies and action in many urban areas.     

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.