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Claus Kohfahl Paul L. Brown Claire M. Linklater Kai Mazur Parviz Irannejad Asaf Pekdeger 《Applied Geochemistry》2008,23(12):3783-3798
The objective of this study was to investigate the impact of flow, transport and geochemical parameters in the unsaturated and saturated zones on the release of SO4 from overburden lignite spoil piles into the adjacent lake. A vertical one-dimensional model was set up using the reactive transport simulator SULFIDOX in order to account for the unsaturated zone. The SULFIDOX model was calibrated for effective diffusion using measured O2 in the gas phase and SO4 concentrations in the liquid phase from the unsaturated zone of the heap. The results show high sensitivity to O2 supply and initially present gypsum, but the inclusion of secondary mineral precipitation in equilibrium is of minor importance for the results. To account for the transport of released SO4 from the saturated zone into the surface water, scenarios were performed by using SULFIDOX results as input concentration for a two-dimensional vertical model set up with PROCESSING MODFLOW and MT3D. These scenarios indicate a rising discharge of SO4 into the adjacent lake due to continued pyrite weathering for 80 a. Results are highly sensitive to dispersivity, whereas the spatial variability of pyrite distribution did not show any influence on the results. The consideration of initially present gypsum shows a major effect on the modelled SO4 release. 相似文献
356.
Alaura C. Singleton Gordon R. Osinski Claire Samson Scott Holladay 《Planetary and Space Science》2010,58(4):472-481
Polygonal terrain is found in a variety of polar environments on Earth and Mars. As a result, many areas of northern Canada may represent ideal terrestrial analogues for specific regions of Mars - in particular the northern plains. In the Canadian Arctic, polygon troughs are commonly underlain by wedges of massive ice, with rare examples of other wedge types. If the same is true for Mars, this raises interesting implications for the processes that concentrate H2O at the Martian poles. This study uses an electromagnetic induction sensor to investigate the electromagnetic characteristics of terrestrial polar ice-wedge polygons. Surveys were conducted in two regions of the Canadian Arctic using a DUALEM-1S dual-geometry electromagnetic induction sensor, which measures electrical conductivity in the first 1.5-2 m of the subsurface. At locations where strong geomorphological evidence of ice was found, polygon troughs corresponded to local conductive anomalies. Trenching confirmed the presence of ice wedges at one site and allowed ground-truthing and calibration of the geophysical data. Previously unknown bodies of massive ice were also identified through the use of this geophysical technique. This study shows that an electromagnetic induction sounder is a useful instrument for detecting and mapping out the presence of subsurface ice in the Canadian Arctic. Taking together with its small size, portability and ruggedness, we suggest that this would also be a useful instrument for any future missions to Mars’ polar regions. 相似文献
357.
Youhei?YamashitaEmail author Anouska?Panton Claire?Mahaffey Rudolf?Jaffé 《Ocean Dynamics》2011,61(5):569-579
The spatial and diurnal tidal variability of dissolved organic carbon (DOC) concentrations and the composition of dissolved
organic matter (DOM), as evaluated by high-temperature catalytic oxidation and excitation–emission matrix combined with parallel
factor analysis (EEM–PARAFAC), respectively, were determined in Liverpool Bay. EEM–PARAFAC modeling resulted in six fluorescent
components characterized as terrestrial humic-like (two), microbial humic-like (two), and protein-like (two). The spatial
distributions of DOC and the four humic-like components were negatively correlated with salinity in the high-salinity waters
observed in this study (30.41–33.75), suggesting that terrestrial DOM was conservatively distributed. The spatial patterns
of protein-like components were largely different from those of DOC, humic-like components, and chlorophyll a, suggesting that these distributions were the combined result of production and degradation in the bay in addition to river
inputs. These findings suggest that the DOM dynamics in Liverpool Bay are strongly controlled by river-dominated allochthonous
DOM inputs with some less significant contributions of autochthonous DOM within the bay. In addition, the temporal variations
of DOM associated with the diurnal tidal cycles were determined at one inshore (31.34–32.24 salinity) and one offshore (33.64–33.75
salinity) station in the bay. Negative linear relationships between salinity and DOM characteristics, i.e., DOC, humic-like,
and protein-like components, were observed at the inshore station. In contrast, no relationship was observed at the offshore
station, suggesting that the export of DOM through rivers and possibly tidal flats have a noticeable influence on DOM concentration
and composition up to a relatively elevated salinity of around 33 in Liverpool Bay. 相似文献
358.
Juteau Thierry Manac'h Gilles Moreau Olivier Lécuyer Christophe Ramboz Claire 《Marine Geophysical Researches》2000,21(3-4):351-385
Marine Geophysical Research - The present study is focused on the so-called High Temprature Reaction Zone of the Oman ophiolite, a thin zone located between the roots of the sheeted dyke complex... 相似文献
359.
This paper presents the implementation of conservation measures, especially bottom trawl free areas, for the protection of cold-water coral off the Norwegian coast. The protection measures became effective less than 9 months after the managers were informed and the public became aware of damaged coral on nationwide television. Behind this quick reaction were a number of agents such as the oil industry, fishers, biologists, NGOs as well as policy-makers. The implementation of the protected areas was remarkably free of contention. This work attempts to outline the reasons for this, and determine whether there are lessons to be learned with regard to conservation measures elsewhere. 相似文献
360.
Expansion of impervious surface cover results in “flashy” hydrologic response, elevated flood risk, and degraded water quality in urban watersheds. Stormwater management ponds (SWMPs) are often engineered into stream networks to mitigate these issues. A clearer understanding of how water is stored and released from SWMPs and SWMP-treated catchments is required to better represent these engineered systems in hydrological and water quality models of urban and urbanizing watersheds. Stable water isotopes were used to compare water age in SWMPs and SWMP-treated catchments in an urbanizing watershed. We sampled water biweekly from two SWMPs and five stream sites with varying land cover and stormwater control in their catchments. Two inverse transit time proxies (damping ratio and young water fraction) were computed along with the mean transit time (MTT) by sine–wave fitting for each SWMP and stream site using the δ18O and δ2H data. Water entering the SWMPs was consistently older (224 and 177 days) than water in or exiting the ponds (ranging from 46 to 91 days and 39 to 67 days, respectively). This finding is likely due to a combination of groundwater infiltration into broken sewer pipes that transport water into the ponds and a bias toward baseflow sampling. At the catchment scale, detention provided by SWMPs was not found to be more significant than the interactive effects of impervious cover, surficial geology, land use proportions, and catchment size in determining MTT. Overall, surficial geology explained the most variation in MTT among the seven sites. This study illustrates the potential for isotope-based approaches of water age to provide information on individual SWMP functioning and the influence of SWMPs on catchment-scale water movement. 相似文献