Analysis of high-voltage,high-resolution images of lattice defects in experimentally-deformed dolomite

Deformation-induced stacking defects in dolomite have been characterised following examination at the cation sublattice level using high-resolution electron microscopy at 500kV. Slip on c (≡{0001}) is observed to produce stacking faults, often de-localised laterally, which are terminated by partial dislocations with Burgers vectors of the form 1/3 [1 \(\overline 1 \) 00]: a model for the faulted dolomite lattice has been constructed which agrees with the image appearance. Slip on f (≡{10 \(\overline 1 \) 2}) produces long planar faults which are established as not being stacking faults, in the normal sense, since there appear to be no offsets of the cation sublattice across the faults, nor any general indication of any terminating partial dislocations: it is proposed that the contrast arises from rotational disorder in CO₃ groups which has resulted from the prior passage of partial dislocations during deformation.     

Inputs of dissolved and particulate 226Ra to lakes and implications for 210Pb dating recent sediments

Gamma spectroscopy was used to measure radioisotope (²¹⁰Pb, ²²⁶Ra, ¹³⁷Cs) activities in sediment cores from 20 lakes and a wetland in Florida, USA. Nine profiles display relatively low (<5 dpm g^–1) and constant ²²⁶Ra activities, whereas 12 show high (>5 dpm g^–1) and variable ²²⁶Ra activities. In the latter group, most display up-core increases in activity. Upper sediments from two lakes (Round and Rowell) possess very high (>20 dpm g^–1) ²²⁶Ra activities that exceed total ²¹⁰Pb activities, clearly illustrating disequlibrium between ²²⁶Ra and supported ²¹⁰Pb. Supported ²¹⁰Pb activity is generally thought to come from in situ, ²²⁶Ra-containing detrital mineral particles, and is typically assumed to be in secular equilibrium with ²²⁶Ra activity. Since 1966, Round Lake has been augmented hydrologically with ²²⁶Ra-rich (6.2 dpm L^–1) groundwater pumped from the local deep aquifer. Adsorption of dissolved ²²⁶Ra to recent Round Lake sediments probably accounts for the high measured ²²⁶Ra activities and the pronounced disequilibrium between ²²⁶Ra and supported ²¹⁰Pb in topmost deposits. We suspect that many Florida waterbodies receive some ²²⁶Ra-rich runoff and seepage from groundwater pumped for irrigation, residential use, industrial applications, and mining. This may account for up-core increases in ²²⁶Ra activity measured in sediment cores from some Florida lakes. Significant groundwater pumping began within the last century, and there has been insufficient time for supported ²¹⁰Pb to come into equilibrium with adsorbed ²²⁶Ra in uppermost deposits. Input of ²²⁶Ra-rich groundwater to lakes may occur in any geographic region where local bedrock contains ²³⁸U and its daughters. When dissolved ²²⁶Ra adsorbs to recent sediments, it complicates accurate estimation of supported ²¹⁰Pb activity, and confounds calculation of unsupported ²¹⁰Pb activity that is used in dating models.     

Longues séries d'insolation homogénéisées en France

Prior to have long-term sunshine-duration series, data rescue effort has to be engaged. Eighteen series have been homogenized over the period 1931–2000. These series complete the set of diagnoses on climate change at a regional scale, confirm part of the diagnosis established for the temperatures, and offer new tracks for the mechanisms of climate change. To cite this article: J.-M. Moisselin, C. Canellas, C. R. Geoscience 337 (2005).     

Phytoplankton reference communities for Chesapeake Bay and its tidal tributaries

Phytoplankton reference communities for Chesapeake Bay were quantified from least-impaired water quality conditions using commonly measured parameters and indicators derived from measured parameters. A binning approach was developed to classify water quality. Least-impaired conditions had relatively high water column transparency and low concentrations of dissolved inorganic nitrogen and orthophosphate. Reference communities in all seasons and salinity zones are characterized by consistently low values of chlorophylla and pheophytin coupled with relative stable proportions of the phytoplankton taxonomic groups and low biomasses of key bloom-forming species. Chlorophyll cell content was lower and less variable and average cell size and seasonal picophytoplankton biomass tended to be greater in the mesohaline and polyhaline reference communities as compared to the impaired communities. Biomass concentrations of the nano-micro phytoplankton size fractions (2–200 μm) in 12 of the 16 season-specific and salinity-specific reference communities were the same or higher than those in impaired habitat conditions, suggesting that nutrient reductions will not decrease the quantity of edible phytoplankton food available to large consumers. High (bloom) and low (bust) biomass events within the impaired phytoplankton communities showed strikingly different chlorophyll cell content and turnover rates. Freshwater flow had little effect on phytoplankton responses to water quality condition in most of the estuary. Improved water column transparency, or clarity, through the reduction of suspended sediments will be particularly important in attaining the reference communities. Significant nitrogen load reductions are also required.     

Late Pleistocene variations in Antarctic sea ice II: effect of interhemispheric deep-ocean heat exchange

Variations in production rates of warm North Atlantic Deep Water (NADW) have been proposed as a mechanism for linking climate fluctuations in the northern and southern hemispheres during the Pleistocene. We have tested this hypothesis by examining the sensitivity of a thermodynamic/dynamic model for Antarctic sea ice to changes in vertical ocean heat flux and comparing the simulations with modified CLIMAP sea-ice maps for 18 000 B.P. Results suggest that changes in NADW production rates, and the consequent changes in the vertical ocean heat flux in the Antarctic, can only account for about 20%–30% of the overall variance in Antarctic sea-ice extent. This conclusion has been validated against an independent geological data set involving a time series of sea-surface temperatures from the subantarctic. The latter comparison suggests that, although the overall influence of NADW is relatively minor, the linkage may be much more significant at the 41 000-year obliquity period. Despite some limitations in the models and geological data, we conclude that NADW variations may have played only a modest role in causing late Pleistocene climate change in the high latitudes of the southern hemisphere. Our conclusion is consistent with calculations by Manabe and Broccoli (1985) suggesting that atmospheric CO₂ changes may be more important for linking the two hemispheres.     

Acquisition and processing of data for isotope-ratio-monitoring mass spectrometry

Methods are described for continuous monitoring of signals required for precise analyses of 13C, 18O, and 15N in gas streams containing varying quantities of CO2 and N2. The quantitative resolution (i.e. maximum performance in the absence of random errors) of these methods is adequate for determination of isotope ratios with an uncertainty of one part in 10(5); the precision actually obtained is often better than one part in 10(4). This report describes data-processing operations including definition of beginning and ending points of chromatographic peaks and quantitation of background levels, allowance for effects of chromatographic separation of isotopically substituted species, integration of signals related to specific masses, correction for effects of mass discrimination, recognition of drifts in mass spectrometer performance, and calculation of isotopic delta values. Characteristics of a system allowing off-line revision of parameters used in data reduction are described and an algorithm for identification of background levels in complex chromatograms is outlined. Effects of imperfect chromatographic resolution are demonstrated and discussed and an approach to deconvolution of signals from coeluting substances described.     

Epiclastic deposits and ‘horseshoe-shaped’ calderas in Tahiti (Society Islands) and Ua Huka (Marquesas Archipelago), French Polynesia

Occurrences of debris avalanche deposits newly identified in Tahiti (Society Islands) and Ua Huka (Marquesas Archipelago) are described and interpreted here. In both islands, the breccias are located within horseshoe-shaped residual calderas. In Tahiti, the epiclastic formations, up to 500 m thick, lie on the floor of the central depression and in the valley of the northwards running Papenoo River. In Ua Huka, the breccias crop out within a depression limited by a semicircular crest in four bays along the southern coast. Their thickness is ca. 100 m. A few clasts collected in the Tahitian breccias and some rocks forming their substratum have been dated (K–Ar datings) and analysed (major and trace elements, Sr–Nd isotopes) for this study. Using these data, we show that the debris avalanche(s) occurred in Tahiti Nui at the end of the growth of the shield volcano (between 570 000 and 390 000 years ago), maybe in consequence of the emplacement of the plutonic body which occupies the central part of the caldera. In Ua Huka, the collapse took place nearly 3 Ma ago, between the construction of the shield volcano and that of the inner one. The southwards orientation of the caldera, like that of the neighbouring island Nuku Hiva, might reflect a preferential direction of weakness in the substratum of the central Marquesas.