Palaeoenvironmental interpretation of Late Pleistocene-Holocene morphosedimentary record in the Valsalada saline wetlands (Central Ebro Basin, NE Spain)

This work presents a palaeoenvironmental interpretation of the Upper Pleistocene-Holocene sedimentary sequence recorded in the Valsalada saline wetland system (Monegros, Central Ebro Basin). This morphosedimentary system developed on karstified, gypsiferous bedrock and was mainly fed by local saline groundwater. Based on geomorphological, sedimentological, palynological and radiocarbon data, three depositional units have been differentiated: 1) a lacustrine unit, which accumulated under cold/cool and humid environmental conditions at 41-40 kyr cal BP, 2) a fluvial unit that was deposited under arid climatic conditions with cold episodic periods from 14 to 3.5 kyr cal BP, and 3) an alluvial slope unit associated with arid climate with human influence during the Late Roman Period (1.5 kyr cal BP). The morphosedimentary evolution of the Valsalada system is strongly influenced by the geomorphic setting (small catchment with karstic depressions and low gradient slopes on gypsum), the hydrological availability (runoff and groundwater discharges) related to climate variability during the Late Pleistocene-Holocene, and the human activities developed in the area during historical times. The response of the Valsalada system displays a low sensitivity to short-term climatic changes but responds to major long-term climatic conditions, improving the regional paleoenvironmental picture of the Late Quaternary in NE Spain.     

Solar influence and hydrological variability during the Holocene from a speleothem annual record (Molinos Cave,NE Spain)

We present a multi‐proxy approach to reconstructing Holocene climate conditions in northeastern Spain based on an excellent correlation among the lamina thickness, colour parameters and isotope (δ¹⁸O and δ¹³C) variations recorded in a speleothem. An age model constructed from five U/Th dates and annual lamina counting suggests that the uppermost 14.7 cm of the MO‐7 stalagmite grew between 7.2 and 2.5 ka before present but experienced a growth hiatus from 4.9 to 4.3 ka. Three spectral analysis methods were applied to 11 time series. The results reveal common solar periodicities on decennial (Gleissberg cycle) and centennial (De Vries‐Suess cycle) scales. The onset of Holocene carbonate precipitation in the MO‐7 stalagmite appears to be associated with a cold, wet period, whereas the hiatus and the end of growth are related to warm, dry periods. This environmental trend fits well within the regional Holocene climate.     

Geochemical compositional changes at the Pliocene–Pleistocene transition in fluviodeltaic deposits in the Tegelen-Reuver area (southeastern Netherlands)

2 O contents, which can be attributed to the Alpine source supplying fresh, sodic plagioclase-rich material instead of the local, strongly weathered sediments. Increasing K₂O/Al₂O₃ can be attributed to a similar decrease in degree of weathering. However, this trend is disturbed by the loss of K from clay minerals during weathering in organic-rich layers. Local high TiO₂ anomalies, caused by preferential sorting and concentration, are found in most Pliocene sections, but they are absent in the Upper Pliocene and Lower Pleistocene Alpine-derived deposits. This change is probably due to a change in the energy of the fluvial system. Finally, (pyrite-) S contents drop (siderite-) Fe contents rise. Micromorphological observations indicate that the Pliocene pyrite was formed when freshwater deposits were flooded with seawater during short-term events. The decrease in S, and the increase in siderite-Fe, can be attributed to decreasing marine influence, as a result of the marine regression at the Pliocene–Pleistocene transition. Received: 28 August 1999 / Accepted: 2 November 1999     

Geochemistry of the acid Kawah Putih lake, Patuha Volcano, West Java, Indonesia

Kawah Putih is a summit crater of Patuha volcano, West Java, Indonesia, which contains a shallow, 300 m-wide lake with strongly mineralized acid–sulfate–chloride water. The lake water has a temperature of 26–34°C, pH=<0.5–1.3, S^tot=2500–4600 ppm and Cl=5300–12 600 ppm, and floating sulfur globules with sulfide inclusions are common. Sulfur oxyanion concentrations are unusually high, with S₄O₆²⁻+S₅O₆²⁻+S₆O₆²⁻=2400 – 4200 ppm. Subaerial fumaroles (<93°C) on the lake shore have low molar SO₂/H₂S ratios (<2), which is a favorable condition to produce the observed distribution of sulfur oxyanion species. Sulfur isotope data of dissolved sulfate and native sulfur show a significant ³⁴S fractionation (ΔSO₄–S_e of 20‰), probably the result of SO₂ disproportionation in or below the lake. The lake waters show strong enrichments in ¹⁸O and D relative to local meteoric waters, a result of the combined effects of mixing between isotopically heavy fluids of deep origin and meteoric water, and evaporation-induced fractionation at the lake surface. The stable-isotope systematics combined with energy-balance considerations support very rapid fluid cycling through the lake system. Lake levels and element concentrations show strong seasonal fluctuations, indicative of a short water residence time in the lake as well.Thermodynamic modeling of the lake fluids indicates that the lake water is saturated with silica phases, barite, pyrite and various Pb, Sb, Cu, As, Bi-bearing sulfides when sulfur saturation is assumed. Precipitating phases predicted by the model calculations are consistent with the bulk chemistry of the sulfur-rich bottom sediments and their identified mineral phases. Much of the lake water chemistry can be explained by congruent rock dissolution in combination with preferential enrichments from entering fumarolic gases or brines and element removal by precipitating mineral phases, as indicated by a comparison of the fluids, volcanic rocks and lake bed sediment.Flank springs on the mountain at different elevations vary in composition, and are consistent with local rock dissolution as a dominant factor and pH-dependent element mobility. Discharges of warm sulfate- and chloride-rich water at the highest elevation and a near-neutral spring at lower level may contain a small contribution of crater-lake water. The acid fluid-induced processes at Patuha have led to the accumulation of elements that are commonly associated with volcano-hosted epithermal ore deposits. The dispersal of heavy metals and other potentially toxic elements from the volcano via the local drainage system is a matter of serious environmental concern.     

Esterification of vertebrate-like steroids in the eastern oyster (Crassostrea virginica)

The esterification of two model vertebrate steroid hormones - estradiol (E2) and dehidroepiandrosterone (DHEA) - was studied in the oyster Crassostrea virginica. The activity of acyl-CoA:steroid acyltransferase was characterized in microsomal fractions isolated from oyster digestive glands. The apparent Km and Vmax values changed with the fatty acid acyl-CoA used (C20:4, C18:2, C18:1, C16:1, C18:0 or C16:0), and were in the range of 9-17 microM, and 35-74 pmol/min/mg protein for E2, and in the range of 45-120 microM, and 30-182 pmol/min/mg protein for DHEA. Kinetic parameters were also assessed in gonadal tissue. The enzyme saturated at similar concentrations, although conjugation rates were lower than in digestive gland. Preliminary data shows that tributyltin (TBT) in the low microM range (1-50) strongly inhibits E2 and DHEA esterification, the esterification of E2 being more sensitive to inhibition than that of DHEA. Overall, results indicate that apolar conjugation occurs in oysters, in both digestive gland and gonads, at a very similar rate to mammals, suggesting that this is a well conserved conjugation pathway during evolution. Esterification, together with other mechanisms, can modulate endogenous steroid levels in C. virginica, and might be a target for endocrine disrupters, such as TBT.     

Searching for Binary Systems Among Nearby Dwarfs Based on Pulkovo Observations and SDSS Data

Our goal is to find previously unknown binary systems among low-mass dwarfs in the solar neighborhood and to test the search technique. The basic ideas are to reveal the images of stars with significant ellipticities and/or asymmetries compared to the background stars on CCD frames and to subsequently determine the spatial parameters of the binary system and the magnitude difference between its components. For its realization we have developed a method based on an image shapelet decomposition. All of the comparatively faint stars with large proper motions (V >13 ^m , μ > 300 mas yr^?1) for which the “duplicate source” flag in the Gaia DR1 catalogue is equal to one have been included in the list of objects for our study. As a result, we have selected 702 stars. To verify our results, we have performed additional observations of 65 stars from this list with the Pulkovo 1-m “Saturn” telescope (2016–2017). We have revealed a total of 138 binary candidates (nine of them from the “Saturn” telescope and SDSS data). Six program stars are known binaries. The images of the primaries of the comparatively wide pairs WDS 14519+5147, WDS 11371+6022, and WDS 15404+2500 are shown to be resolved into components; therefore, we can talk about the detection of triple systems. The angular separation ρ, position angle, and component magnitude difference Δm have been estimated for almost all of the revealed binary systems. For most stars 1.5′′ < ρ < 2.5′′, while Δm <1.5^m.     

Deflecting an Asteroid with a Low-Thrust Tangential Engine to the Orbit

Astronomy Reports - In order to solve the problem of deflecting a dangerous asteroid from a collision orbit with the Earth, using a low-thrust engine directed tangentially to the trajectory is...     

Origin and evolution of playas and blowouts in the semiarid zone of Tierra de Pinares (Duero Basin, Spain)

A large number of blowouts and playas occur in the marginal sectors of the aeolian deposits located in the southern sector of the Duero Depression (Tierra de Pinares) in Spain. The blowouts are relict landforms that were developed on sand sheets by deflation during dry periods with lower vegetation cover and a deeper water table. The studied blowouts form complexes of NW–SE and NNW–SSE elongated hollows with accompanying dunes up to 4 km long in the leeward margins. Some hollows host lakes or swampy areas related to a shallow water table. The dunes formed by NE–ENE winds show steep windward slopes and gentle leeward slopes. The studied playas, with prevalent NNW–SSE orientations, result from the aeolian excavation of terrace deposits and the underlying marly bedrock. It is probable that the formation of these depressions in an initial stage was related to deflation processes affected preferentially NNW–SSE sandy channels perpendicular to the dominant wind direction. The precipitation of salts in the playas generates aggregates of clay particles (peloids) that are easily removed by the wind. Once the bottom reached the substratum, the deepening of the depressions progressed by the deflation of particles produced by weathering of the argillaceous bedrock.     

Hydrothermal metasomatic alteration of carbonate bottom sediments in the Ashadze-1 field (13° N Mid-Atlantic Ridge)

We have performed the first detailed study of hydrothermal alteration of the Holocene-upper Pleistocene sediments in the recent Ashadze-1 hydrothermal field sampled during the 26th cruise of R/V Professor Logachev in 2005. It has been established that alterations in mineralogy and geochemistry are caused by the dissolution of calcite shells in bottom sediments and their metasomatic replacement with sulfides and other hydrothermal minerals. A zone of sediments enriched in magnesian hydrothermal minerals has been revealed in the sediments of the MAR for the first time. It is suggested that metasomatism is related to diffuse percolation of hydrothermal fluids through sediments.