1950年以来青藏高原兹格塘错碳酸盐稳定碳同位素变化及其原因

兹格塘错是青藏高原中部一个典型的半混合型咸水湖泊。本文在~(210)Pb和~(137)Cs定年的基础上,研究了兹格塘错重力岩芯(ZGTC A-1)小于38.5μm细颗粒组分碳酸盐稳定碳同位素1950年以来的变化及其影响因素。对冬夏季湖水水化学特征的分析表明,夏季湖水溶解CO_2呈逸出状态,冬季湖水钙离子浓度是夏季湖水的10倍,据此可以得出兹格塘错碳酸盐矿物主要在夏季沉淀。通过与那曲气象站气象记录对比发现,1950年以来A-1岩芯碳酸盐碳同位素变化与年均温度有很好的相关性,表现出年均温度高时碳同位素偏重,而年均温度低时碳同位素偏轻的特征。兹格塘错1950年以来自生碳酸盐碳同位素的变化是由湖区及水体碳循环(如碳酸盐沉淀,有机质的沉淀与分解,有机碳和无机碳的转化等)的变化引起的,但各种因素的相互作用非常复杂。碳酸盐含量也与温度有关,温度越高,碳酸盐含量越高,同时降水量与碳酸盐含量也存在明显的相关关系。1950年以来有机质含量与温度呈反相关,可能与湖泊生产力的下降有关。     

秘鲁阿雷基帕省阿蒂科地区水系沉积物地球化学特征及找矿远景预测

依据1∶10万水系沉积物测量资料,分析研究了秘鲁南部阿蒂科地区水系沉积物地球化学特征。通过对元素分布、元素相关性、单元素异常、异常元素组合等特征的分析,结合成矿地质条件,圈定了阿祖卡、塞罗皮耶霍、帕姆帕和卡拉帕尔卡4处找矿远景区,为该区下一步的找矿工作指明了方向。     

现代爆破理论及其新进展

爆破理论的研究历史，经历了三个不同的发展阶段，各阶段均有其代表性理论。文章介绍和分析了各爆破理论的要点及其优缺点以及最新进展情况，对工程爆破实践起着重要的指导意义     

Relationship between surface pollen assemblages and vegetation in Luonan Basin,Eastern Qinling Mountains,Central China

The catchment of South Luohe River in Central China is an important region for investigating modern pollen-environment relationship, because it is located in the transitional zone between south and north China, an environment which is sensitive to climate changes. In this study, 40 surface samples under ten vegetation types were collected to reveal the relationship between pollen assemblages and vegetation. The results show that the surface pollen assemblages reflect the vegetation quite well. In forest topsoils, the average of arboreal pollen content is greater than 40%, and the Selaginella sinensis spore is high. As to sparse forest grassland and shrub community, the average arboreal pollen is 13.2% and 16.6% respectively, and the shrub pollen is relatively higher than that of grassland samples. The grassland and farmland are characterized by low percentage of tree and shrub pollen (<10% and <1%), and high percentage of herbs (>80%). Pinus, Quercus and some other arboreal pollen can indicate the regional vegetation because of their dispersal ability. Quercus pollen is under-representative and so is Pinus. Artemisia pollen is significantly over-represented, has poor correlation with the plant coverage, and may reflect human disturbance. Gramineae can indicate plant quite well, but with low representation. High content of Chenopodiaceae probably suggests human impact. Predominant Selaginella sinensis can be used as an indicator of forest environment. Cluster analysis and principal components analysis of pollen assemblages can distinguish forest and non-forest vegetation well. The former method is better at separating pine and mixed forests, while the latter is more stable and could better differentiate farmland and other non-forest area. The first axis of PCA mainly reflects the humidity.     

Caledonian Low-Temperature Granulite-Facies Metamorphism in the West Kunlun Orogenic Belt—SHRIMP Chronological Evidence from Zircon

The West Kunlun orogenic belt is located at the conjunction of the paleo-Asian tectonic system and the Tethys tectonic system. Petrological and mineralogical studies of the Early Cambrian metamorphic surface crust in this region have shown that in case the metamorphism reached low-temperature granulate facies, the typical mineral assemblage is biotite-garnet-silimanite-K feldspar-plagioclase-quartz. The peak metamorphic temperatures are within the range of 720–740°C and the pressure is 0.6 GPa ±. Three types of metamorphic zircon have been detected in the metamorphic rocks: the complex inclusion-bearing type ; the early relic zircon inclusion-bearing type; and the inclusion-free type. SHRIMP age determination of these three types of metamorphic zircon have revealed that these zircons were formed principally during 400–460 Ma, indicating that pre-Cambrian metamorphic surface crust rocks underwent low-temperature granulite facies metamorphism during the Caledonian. In combination with the geological characteristics of this region, it is considered that when the oceanic basin was closed, there occurred intense intracontinental subduction (type A), bringing part of the Early Cambrian metamorphic basement in this region downwards to the lower crust. Meanwhile, there were accompanied with tectonic deformation at deep levels and medium- to high-grade metamorphism. This study provided important chronological and mineralogical evidence for the exploration of the evolutionary mechanism and process of the West Kunlun Early Paleozoic. Part of the results from the research project “ Research on the West Kunlun pre-Cambrian tectonic events” under the program “ Research on the important geological problems of China’ s pre-Cambrian” (No. 200113900070) sponsored by the China National Geological Surveying Bureau.     

Two Periods of Skarn Mineralization in the Baizhangyan W–Mo Deposit,Southern Anhui Province,Southeast China: Evidence from Zircon U–Pb and Molybdenite Re–Os and Sulfur Isotope Data

The recently discovered Baizhangyan skarn‐porphyry type W–Mo deposit in southern Anhui Province in SE China occurs near the Middle–Lower Yangtze Valley polymetallic metallogenic belt. The deposit is closely temporally‐spatially associated with the Mesozoic Qingyang granitic complex composed of g ranodiorite, monzonitic g ranite, and alkaline g ranite. Orebodies of the deposit occur as horizons, veins, and lenses within the limestones of Sinian Lantian Formation contacting with buried fine‐grained granite, and diorite dykes. There are two types of W mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization. Among skarn mineralization, mineral assemblages and cross‐cutting relationships within both skarn ores and intrusions reveal two distinct periods of mineralization, i.e. the first W–Au period related to the intrusion of diorite dykes, and the subsequent W–Mo period related to the intrusion of the fine‐grained granite. In this paper, we report new zircon U–Pb and molybdenite Re–Os ages with the aim of constraining the relationships among the monzonitic granite, fine‐grained granite, diorite dykes, and W mineralization. Zircons of the monzonitic granite, the fine‐grained granite, and diorite dykes yield weighted mean U–Pb ages of 129.0 ± 1.2 Ma, 135.34 ± 0.92 Ma and 145.3 ± 1.7 Ma, respectively. Ten molybdenite Re–Os age determinations yield an isochron age of 136.9 ± 4.5 Ma and a weighted mean age of 135.0 ± 1.2 Ma. The molybdenites have δ³⁴S values of 3.6‰–6.6‰ and their Re contents ranging from 7.23 ppm to 15.23 ppm. A second group of two molybdenite samples yield ages of 143.8 ± 2.1 and 146.3 ± 2.0 Ma, containing Re concentrations of 50.5–50.9 ppm, and with δ³⁴S values of 1.6‰–4.8‰. The molybdenites from these two distinct groups of samples contain moderate concentrations of Re (7.23–50.48 ppm), suggesting that metals within the deposit have a mixed crust–mantle provenance. Field observation and new age and isotope data obtained in this study indicate that the first diorite dyke‐related skarn W–Au mineralization took place in the Early Cretaceous peaking at 143.0–146.3 Ma, and was associated with a mixed crust–mantle system. The second fine‐grained granite‐related skarn W–Mo mineralization took place a little later at 135.0–136.9 Ma, and was crust‐dominated. The fine‐grained granite was not formed by fractionation of the Qingyang monzonitic granite. This finding suggests that the first period of skarn W–Au mineralization in the Baizhangyan deposit resulted from interaction between basaltic magmas derived from the upper lithospheric mantle and crustal material at 143.0–146.3 and the subsequent period of W–Mo mineralization derived from the crust at 135.0–136.9 Ma.     

碳担载钼基催化剂的性质研究

利用差热分析（ＤＴＡ） 和程序升温还原（ＴＰＲ） 技术研究了活性炭担载钼基催化剂在制备和预处理过程中的性质变化。ＤＴＡ结果表明,催化剂在焙烧过程中产生了新相,这种新相与活性组分和载体间的相互作用有关,助剂Ｋ和Ｎｉ 的引入对这种相互作用有明显的影响。Ｋ／Ｃ样品的ＴＰＲ结果表明,Ｋ 本身不被还原,但它可以改变催化剂中其它物种的还原行为。Ｃ 担载Ｍｏ 基催化剂的ＴＰＲ谱一般由四个正峰和一个负峰组成,正峰归属为不同Ｍｏ 物种和载体本身（ 包括其中的某些杂质）的还原,负峰则归属于氧化的Ｃ载体表面脱附出的ＣＯ,Ｍｏ 担载到活性炭上后变得更加难还原了。Ｋ 的引入大大促进了低温下可还原Ｍｏ 物种（ 主要是八面体Ｍｏ） 的形成,而抑制了那些仅在高温下才能被还原的Ｍｏ 物种（ 主要是四面体Ｍｏ） 的产生。这可能是影响催化剂在ＣＯ加氢反应中的选择性的一个重要因素。     

南洛河流域洛南盆地表土孢粉与植被的关系(英文)

The catchment of South Luohe River in Central China is an important region for investigating modern pollen-environment relationship, because it is located in the transitional zone between south and north China, an environment which is sensitive to climate changes. In this study, 40 surface samples under ten vegetation types were collected to reveal the relationship between pollen assemblages and vegetation. The results show that the surface pollen assemblages reflect the vegetation quite well. In forest topsoils, the average of arboreal pollen content is greater than 40%, and the Selaginella sinensis spore is high. As to sparse forest grassland and shrub community, the average arboreal pollen is 13.2% and 16.6% respectively, and the shrub pollen is relatively higher than that of grassland samples. The grassland and farmland are characterized by low percentage of tree and shrub pollen(<10% and <1%), and high percentage of herbs(>80%). Pinus, Quercus and some other arboreal pollen can indicate the regional vegetation because of their dispersal ability. Quercus pollen is under-representative and so is Pinus. Artemisia pollen is significantly over-represented, has poor correlation with the plant coverage, and may reflect human disturbance. Gramineae can indicate plant quite well, but with low representation. High content of Chenopodiaceae probably suggests human impact. Predominant Selaginella sinensis can be used as an indicator of forest environment. Cluster analysis and principal components analysis of pollen assemblages can distinguish forest and non-forest vegetation well. The former method is better at separating pine and mixed forests, while the latter is more stable and could better differentiate farmland and other non-forest area. The first axis of PCA mainly reflects the humidity.     

南洛河流域洛南盆地表土孢粉与植被的关系

选取南洛河上游洛南盆地10 种植被类型下40 处样点表土苔藓开展孢粉与植被关系的研究.结果表明,表土中孢粉组成能很好地反映植被类型.森林表土中乔木植物花粉含量平均值大于40%,且有较高含量的中华卷柏孢子;疏林草原、灌丛群落中乔木植物花粉平均含量分别为13.2%和16.6%,灌木植物花粉相对草丛群落含量较高;草丛群落和农田中乔木花粉平均含量均<10%,草本植物花粉>80%,灌木植物花粉<1%.洛南盆地表土孢粉总浓度平均为1.42×10⁵粒/g,与植被覆盖度关系较弱,而与植被类型有一定联系,能辅助植被类型的辨识.聚类分析和PCA分析都能较好区分森林和非森林植被,前者能较好地区分松林和混交林,后者能较好地区分农田和灌、草丛植被,且比聚类分析更加稳定.松属、栎属等乔木花粉具有较强的扩散能力,能指示区域植被,松属没有表现出很强的超代表性,栎属具有低代表性;蒿属花粉与植被覆盖度间的相关关系较差,具有明显的超代表性,其大量出现与人类的干扰有一定的联系,禾本科花粉具有很好的植被指示性和低代表性,藜科花粉的高含量主要指示了高强度的人类活动;中华卷柏孢子在地层中的大量出现具有指示森林或松林环境的意义.     

2012年6月24日宁蒗—盐源M_S5.7地震序列M_L≥3.5余震震源机制解

针对2012年6月24日宁蒗—盐源MS 5.7地震序列,基于云南地震台网及部分四川地震台网宽频带数据,采用CAP方法反演该序列主震及ML≥3.5余震的震源机制解。结果显示:主震主应力方位角为148°,俯角58°,节面Ⅰ走向:179°、倾角55°、滑动角-43°;节面Ⅱ走向:297°、倾角26°、滑动角-136°,矩心深度4 km,矩震级5.36,表现为正断层兼走滑型地震,判定节面Ⅱ为其发震断层面,永宁断裂为其发震构造。