Correlation between local structure and molar ratio of Au (III) complexes in aqueous solution: An XAS investigation

The local and geometrical structure around gold (III) e.g., Au³⁺ ions in aqueous solution with different OH⁻/Cl⁻ molar ratios, has been investigated by X-ray absorption spectroscopy (XAS). X-ray absorption near-edge structure (XANES) spectra of [AuCl_n(OH)_4−n]⁻ solutions have been calculated and the multiple-scattering spectral features have been attributed to Cl d-states, axial water molecules and the replacement of Cl⁻ ligands by OH⁻ ligands. A square–planar geometry for [AuCl_n(OH)_4−n]⁻ with two axial water molecules has been identified. Moreover, a spectral correlation between XANES features and the type of planar atoms has been identified. By extended X-ray absorption fine structure spectra (EXAFS), the planar Au bond distances in the solutions have also been determined, e.g., 2.28 Å for Au–Cl and 1.98 Å for Au–O, respectively. The same EXAFS analysis provides evidence that the peak at about 4.0 Å in solutions with the lowest OH⁻/Cl⁻ molar ratio arises from collinear Cl–Au–Cl multiple-scattering contributions. For the first time, a complete detailed reconstruction of the hydration structure of an Au ion at different pH values has been achieved.     

化学地球动力学中的铂族元素地球化学

对球粒陨石和地幔样品来讲,Ru,Rh,Pd,Os,Ir和Pt等贵金属元素的含量比值在一定程度上是相同的,但是在地幔样品中它们的含量实际上比球粒陨石低大约2个数量级,因此提出了核幔分离之后地球增生过程的“后增薄层”假说。数百公里尺度地幔橄榄岩的PEG分布的不均一性除被认为由于增生阶段的不均一造成外,更可能是由于地幔形成之后的地幔过程、核－幔及壳－幔相互作用造成。部分熔融、岩浆结晶分异（特别是硫化物、金属相析离）、流体（包括岩浆）／岩石相互作用等造成了大型俯冲带、造山带中地幔橄榄岩、蛇绿岩和杂岩体的PGE分异,也是形成铬铁矿,大型贵金属矿床的主要机制。     

福建省古生代至中生代大地构造演化的格架

松溪—长汀断裂带和福州—永定断裂带是控制福建古生代及以后大地构造演化的两条北东东向的断裂带。地质地球化学资料表明,前者是加里东期的地体碰撞带,沿线分布了构造混杂岩、变质超基性岩体、具有角闪岩相和中压矿物的变质岩以及同碰撞型花岗岩体,以后又发育为A型俯冲带;后者是发育于加里东构造层之上的海西期张裂带,在形成海西期的福州—永定海峡的同时,产生了石炭纪海底双模式火山岩及层控铁矿,印支期的碰撞活动使海峡封闭并发育A型俯冲作用。由此,北东东向的松溪—长汀断裂带和福州—永定断裂带可以将福建划分为三个古生代的构造地层地体:闽北地体、闽中地体和闽东南地体。通过对福建省古生代地体构造分析、古地磁测量及古地理重建,展现在我们眼前是:华南(其中包括福建)在古生代中期从冈瓦纳大陆分离出来后,横渡特提斯海,在古生代末至中生代初到达劳亚大陆,与中朝板块碰撞引起了福建地体间强烈的造山运动。     

珠江口西部海域表层沉积物重金属元素多尺度空间变化特征

笔者应用因子克里格分析方法,研究了珠江口西部海域388个表层沉积物中7种重金属元素Cd, Ni,Cu,Zn,Pb,Cr和As的空间结构特征,识别并分离了重金属元素不同尺度的空间主成分及其分布特征,探讨了不同空间尺度重金属的物源及控制因素。结果显示,研究区7种重金属元素在空间上存在块金尺度、局部尺度(变程为60 km的球状结构)和区域尺度(变程为160 km的球状结构)3种尺度的空间变化。以迭代算法模拟了研究区重金属元素线性协同区域化模型。根据不同尺度上区域化因子的主成分得分分布特征可知:局部尺度上,F₁因子(Zn,Cr,Ni,Cu)和F₂因子(As)的高值区表现为"牛眼"状局部特征,并分布在陆地沿海的河口或者港湾区,指示了可能受人为污染成分影响的重金属区域。其中,雷州半岛东部沿海是最可能的重金属污染区,其空间分布主要受控于局部的地形、海流等因素。F₂因子不同于F₁的空间分布,主要在于As不同于Zn,Cr,Ni,Cu等的地球化学行为。区域尺度上,F₁(Zn,Cr,Ni)和F₂(As)因子主要反映了不同陆源母岩物质的影响。Zn,Cr,Ni等主要源于华南大陆陆源母岩物质,而As主要受到海南岛陆源母岩物质的控制。F₁和F₂因子得分高值区整体上表现为NNE向自陆地向较深海域延伸的"片状"分布特征,推测其主要受到海平面变化及NNE向区域性海洋环流的控制。     

额尔齐斯碰撞带东段结构与形成时代

阿尔泰地体与萨吾尔岛弧之间的额尔齐斯碰撞带其结构与形成时代是中亚造山带构造演化研究的热点问题之一。本文报道了额尔齐斯碰撞带东段结构与形成时代的研究结果。新的结果显示:额尔齐斯碰撞带东段由4个走向NWNNW陡立的韧性变形带组成,剖面上呈扇状挤压变形的结构;这4个韧性变形带的应变类型为收缩应变与平面应变;片理带的变形从宏观到微观都表现出对称的结构,不同变形带不同地段可具变化的流动方向而表现出"奶油饼结构",其可能整体形成于共轴挤压机制;玉勒肯与老山口韧性变形带花岗闪长质糜棱岩、花岗闪长质超糜棱岩中变质重结晶锆石U-Pb定年结果显示韧性变形时间约为360Ma。这可能意味着早石炭世时卡拉先格尔地区已进入碰撞阶段,即萨吾尔岛弧与阿尔泰地体间在360Ma时已发生碰撞。     

High‐T and low‐P metamorphism in the Xilingol Complex of central Inner Mongolia,China: An indicator of extension in a previous orogeny

The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle.     

Study on Water Internal Recycle Process and Mechanism in Typical Mountain Areas of Inland Basins,Northwest China: Progress and Challenge

The water resource and its change of mountainous area are very important to the oasis economic system and ecosystem in the arid areas of northwest China. Accurately understanding the water transfer and circulation process among vegetation, soil, and atmosphere over different hydrological units in mountainous areas such as snow and ice, cold desert, forest and grassland is the basic scientific issue of water research in cold and arid regions, which is also the basis of water resource delicacy management and regulation. There are many research results on the hydrological function of different land covers in mountain areas, basin hydrological processes, however, there are only very limited studies on the water internal recycle at basin scale. The quantitative study on the mechanism of water internal recycle is still at the starting stage, which faces many challenges. The key project “Study on water internal recycle processes and mechanism in typical mountain areas of inland basins, Northwest China” funded by National Natural Science Foundation of China will select the Aksu River and Shule River Basin, which have better observation basis, as study area. The internal mechanism of moisture transfer and exchange process of different land cover and atmosphere, the internal mechanism of water cycle in the basin, and water transfer paths in atmosphere will be studied through enhancing runoff plot experiments on different land cover, analyzing the mechanism of water vapor transfer and exchange between different land covers in the watershed by isotope tracing on the water vapor flux of vegetation water, soil moisture and atmospheric moisture, improving the algorithms of remote sensing inversion and ground verification on land surface evapotranspiration on different land cover, and analyzing the water vapor flux from reanalysis data, and the coupling modeling of regional climate model and land surface process model. At last, the effect of different land cover in hydrological process of mountain area, and the impact of land cover on downstream oasis will be systematically analyzed.     

塔里木盆地西南地区早中寒武世岩相古地理

塔里木盆地西南地区早中寒武世岩相古地理存在一定争议,这制约了该区的勘探评价。综合利用露头、钻井和地震资料,开展沉积相、地震相分析,并结合区域构造背景,恢复了岩相古地理格局,提出了相应的沉积模式。中下寒武统发育陆棚相、开阔台地相、局限台地相、蒸发台地相和缓坡相。震旦纪末期麦盖提斜坡南部形成水下低隆起,向南在西南坳陷区残留部分被动陆缘,主要发育缓坡相、陆棚相;麦盖提斜坡区地势较高,地层较薄,主要发育局限台地和蒸发台地潮坪;巴楚隆起区水体局限,在干燥炎热气候下形成了厚度较大的蒸发台地膏盐湖沉积。巴楚隆起区和麦盖提斜坡区中下寒武统膏盐岩分布广泛,与下伏碳酸盐岩可构成良好的储盖组合,西南坳陷区残留部分被动陆缘,烃源岩发育条件较好,这表明塔西南具有较好的油气前景。     

Geochemical and Sr-Nd isotopic study of alkaline syenites in Liangtun-Kuangdonggou, Liaoning Province, China： Evidence for enriched mantle before 1.86 Ga and implications

The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes.