The stability of sapphirine + clinopyroxene: implications for phase relations in the CaO-MgO-Al2O3-SiO2 system under deep-crustal and upper mantle conditions

Reaction textures and chemographic relations in sapphirine-bearing basic granulites at Finero, Italy, suggest that sapphirine and aluminous diopside were formed in mutual equilibrium from an inferred early spinel-bearing assemblage. Finero appears to be the only known locality where this association has been found in situ, although it is also known from kimberlite and breccia pipe nodules elsewhere. The reactions deduced to have occurred in these rocks suggest the existence of stable invariant points involving the phases sapphirine-spinel-orthopyroxene-clinopyroxene-garnet-anorthite and sapphirine-two pyroxenes-garnetanorthite-kyanite (or sillimanite) in the CMAS end-member system. P-T estimates for the relevant rocks, and the available experimental data, suggest that these points lie at around 800°–900° C, 9–11 kbar. A semi-quantitative petrogenetic grid, incorporating these invariant points with previously determined univariant reactions, is proposed. It is inferred that sapphirine+diopside are stable relative to spinel-bearing assemblages below 900° C. The relatively low temperature explains why sapphirine has not to date been reported from experimental work on the CMAS system. It also suggests that sapphirine may be an important aluminous phase in Mg-rich metagabbros under conditions corresponding to the base of the continental crust, despite the observed rarity of such rocks at the surface.     

A model for the origin of the cell-doubling phase transitions in clinopyroxene and body-centred anorthite

Comparisons of the structures of the high-pressure and high-temperature phases of both anorthite and clinopyroxene show that they are quite distinct although they share a common space group and site symmetries for all atoms. The low-pressure, low-temperature phases in both systems are formed by zone-boundary transitions from the high-pressure or high-temperature structures, and have structures that are made up of the alternation of portions of the high-pressure and high-temperature structures. This behaviour is analyzed in terms of the order parameter behaviour of the high-symmetry structures, and it is shown that the stability of the low-symmetry phases arises naturally from inhomogeneity in this order parameter.     

Planar and line defects in the sapphirine polytypes

Transmission electron microscopy of various natural and synthetic sapphirines shows the existence of extensive polytypic variation in some samples. In addition to the previously described 1Tc and 2M polytypes, 3Tc, 4M and 5Tc structures are observed. The structural principles underlying the polytypism and the associated diffraction behaviour are reviewed, and the correlation between the nature of the observed stacking faults and their origin during crystal growth, in deformation or as a result of solid-state transformation is discussed. Pairs of c/2 partial dislocations observed in synthetic material provide a likely solid-state transformation mechanism, although the evidence suggests that most observed stacking variation arises during growth.A new type of non-conservative planar defect has been found in sapphirine from Finero, Italy, suggestive of unit-cell scale intergrowth with a surinamite- or pyroxene-like structure. A polysomatic model of the sapphirine and surinamite structures as stackings of pyroxene P and spinel S modules is proposed.     

Holocene vegetation, fire and climate history of the Sawtooth Range, central Idaho, USA

The paucity of low- and middle-elevation paleoecologic records in the Northern Rocky Mountains limits our ability to assess current environmental change in light of past conditions. A 10,500-yr-long vegetation, fire and climate history from Lower Decker Lake in the Sawtooth Range provides information from a new region. Initial forests dominated by pine and Douglas-fir were replaced by open Douglas-fir forest at 8420 cal yr BP, marking the onset of warmer conditions than present. Presence of closed Douglas-fir forest between 6000 and 2650 cal yr BP suggests heightened summer drought in the middle Holocene. Closed lodgepole pine forest developed at 2650 cal yr BP and fires became more frequent after 1450 cal yr BP. This shift from Douglas-fir to lodgepole pine forest was probably facilitated by a combination of cooler summers, cold winters, and more severe fires than before. Five drought episodes, including those at 8200 cal yr BP and during the Medieval Climate Anomaly, were registered by brief intervals of lodgepole pine decline, an increase in fire activity, and mistletoe infestation. The importance of a Holocene perspective when assessing the historical range of variability is illustrated by the striking difference between the modern forest and that which existed 3000 yr ago.     

A Small‐Diameter NMR Logging Tool for Groundwater Investigations

A small‐diameter nuclear magnetic resonance (NMR) logging tool has been developed and field tested at various sites in the United States and Australia. A novel design approach has produced relatively inexpensive, small‐diameter probes that can be run in open or PVC‐cased boreholes as small as 2 inches in diameter. The complete system, including surface electronics and various downhole probes, has been successfully tested in small‐diameter monitoring wells in a range of hydrogeological settings. A variant of the probe that can be deployed by a direct‐push machine has also been developed and tested in the field. The new NMR logging tool provides reliable, direct, and high‐resolution information that is of importance for groundwater studies. Specifically, the technology provides direct measurement of total water content (total porosity in the saturated zone or moisture content in the unsaturated zone), and estimates of relative pore‐size distribution (bound vs. mobile water content) and hydraulic conductivity. The NMR measurements show good agreement with ancillary data from lithologic logs, geophysical logs, and hydrogeologic measurements, and provide valuable information for groundwater investigations.     

Geochemistry of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex,South Sulawesi,Indonesia: Protolith origin and tectonic setting

We present the first data on bulk‐rock major and trace element compositions for a suite of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex, Indonesia, with the aim of better constraining the protolith origins and nature of the subducted crust. The eclogites can be classified into two groups: glaucophane‐rich eclogite and glaucophane‐free eclogite, whereas the blueschists are divided into albite–epidote glaucophanite and quartz–glaucophane schists. SiO₂ contents of the eclogites are 43.3–49.6 wt%, with Na₂O + K₂O contents 3.7–4.7 wt%. The blueschists show a wider range of compositions, with SiO₂ = 40.7–63.8 wt% and Na₂O + K₂O = 2.7–4.5 wt%. Trace element data suggest that the eclogite protoliths include both enriched and normal mid‐oceanic ridge basalt (E‐MORB and N‐MORB) and also gabbroic cumulates. The blueschists show more variation in protoliths, which include N‐MORB, Oceanic Island Basalt (OIB) and Island Arc Basalt (IAB). Plots of element concentrations against the immobile Zr show considerable mobility of large ion lithophiles but not of high field‐strength elements during high‐pressure metamorphism, and indicate that the high SiO₂ content of some blueschists is probably due to metasomatism by a LILE‐rich siliceous aqueous fluid. Strong correlations between K, Rb, Ba and Cs suggests that enrichment of these elements occurred by a single process. All the protoliths were subducted, metamorphosed to blueschist/eclogite‐facies and subsequently exhumed. It is noteworthy that the samples deduced to have come from thicker‐crust environments (OIB, IAB) were subducted to shallower depths (blueschist‐facies) than MORB‐derived samples, all except one of which reached eclogite‐facies conditions. The geochemical data of this study demonstrate the variety of ocean floor types that were subducted under the southeast margin of Sundaland in the late Jurassic period.     

The crystal structure of disordered (Zr,Ti)O2 solid solution including srilankite: evolution towards tetragonal ZrO2 with increasing Zr

Crystal structure data are presented for seven synthetic samples of disordered zirconium-titanate solid solution (Zr,Ti)O₂, ranging in composition from x _Ti=0.43 to 0.67, thus covering compounds such as ZrTiO₄, Zr₅Ti₇O₂₄, and ZrTi₂O₆ (srilankite). The compounds, synthesized at high temperatures and various pressures in their respective stability fields, are well crystallized and of homogeneous composition. The resulting structure data are less scattered compared to previous studies that were based on compounds synthesized metastably at low temperatures and room pressure. The compounds have the structure of scrutinyite (α-PbO₂) with space group Pbcn, Z=4, unit cell parameters a=4.8495(3) Å, b=5.4635(3) Å, c=5.0462(3) Å at x _Ti=0.425 to a=4.7112(2) Å, b=5.4944(1) Å, c=4.9962(1) Å at x _Ti=0.666. The first structure refinement of pure, synthetic srilankite is presented, which is in good agreement with that of the natural counterpart. Structural trends observed in disordered zirconium-titanate solid solution along the binary join ZrO₂–TiO₂ are relatively smooth and continuous, except for rapid lengthening of an unshared octahedral edge which is anomalously short in scrutinyite-structure TiO₂. The shortness of this edge may explain the observed instability of this structure with the relatively small Ti as the dominant cation. With increasing Zr content, the average cation position moves off-centre inside the octahedron, away from two shared edges, which permits the 12 closest cation–cation distances in the structure to become more equal. The shortening of the b dimension with increasing amount of the larger cation Zr decreases the distance between octahedral Zr and two additional oxygens in an adjacent chain of edge-sharing octahedra, implying that the Zr environment is evolving towards eightfold coordination. If the two additional oxygens are considered as part of the Zr coordination polyhedron, the bonding topology of tetragonal zirconia is obtained. The compositional evolution of the cell parameters, Zr atomic coordinates and Zr coordination environment is consistent with the idea that the structure is evolving towards that of tetragonal ZrO₂. Group-theoretical relationships between scrutinyite, tetragonal zirconia, baddeleyite and fluorite structures show that the sequence of structures fluorite > tetragonal zirconia > scrutinyite > baddeleyite are all related by potentially diffusionless phase transitions driven by wavelike displacements of the oxygen substructure. The scrutinyite and tetragonal structures can act outside their stability fields as “transition states” between the structures on either side.     

Satellite bulk tropospheric temperatures as a metric for climate sensitivity

We identify and remove the main natural perturbations (e.g. volcanic activity, ENSOs) from the global mean lower tropospheric temperatures (T _LT ) over January 1979 - June 2017 to estimate the underlying, potentially human-forced trend. The unaltered value is +0.155 K dec^?1 while the adjusted trend is +0.096 K dec^?1, related primarily to the removal of volcanic cooling in the early part of the record. This is essentially the same value we determined in 1994 (+0.09 K dec^?1, Christy and McNider, 1994) using only 15 years of data. If the warming rate of +0.096 K dec^?1 represents the net T _LT response to increasing greenhouse radiative forcings, this implies that the T _LT tropospheric transient climate response (ΔT _LT at the time CO₂ doubles) is +1.10 ± 0.26 K which is about half of the average of the IPCC AR5 climate models of 2.31 ± 0.20 K. Assuming that the net remaining unknown internal and external natural forcing over this period is near zero, the mismatch since 1979 between observations and CMIP-5 model values suggests that excessive sensitivity to enhanced radiative forcing in the models can be appreciable. The tropical region is mainly responsible for this discrepancy suggesting processes that are the likely sources of the extra sensitivity are (a) the parameterized hydrology of the deep atmosphere, (b) the parameterized heat-partitioning at the oceanatmosphere interface and/or (c) unknown natural variations.     

Percolation pond as a method of managed aquifer recharge in a coastal saline aquifer: A case study on the criteria for site selection and its impacts

Percolation ponds have become very popular methods of managed aquifer recharge due to their low cost, ease of construction and the participation and assistance of community. The objective of this study is to assess the feasibility of a percolation pond in a saline aquifer, north of Chennai, Tamil Nadu, India, to improve the storage and quality of groundwater. Electrical resistivity and ground penetrating radar methods were used to understand the subsurface conditions of the area. From these investigations, a suitable location was chosen and a percolation pond was constructed. The quality and quantity of groundwater of the nearby area has improved due to the recharge from the pond. This study indicated that a simple excavation without providing support for the slope and paving of the bunds helped to improve the groundwater quality. This method can be easily adoptable by farmers who can have a small pond within their farm to collect and store the rainwater. The cost of water recharged from this pond works out to be about 0.225 Re/l. Cleaning the pond by scrapping the accumulated sediments needs to be done once a year. Due to the small dimension and high saline groundwater, considerable improvement in quality at greater depths could not be achieved. However, ponds of larger size with recharge shafts can directly recharge the aquifer and help to improve the quality of water at greater depths.