Sustained turbidity currents and their interaction with debrite-related topography; Labuan Island, offshore NW Borneo, Malaysia

The Temburong Fm (Early Miocene), Labuan Island, offshore NW Borneo, was deposited in a lower-slope to proximal basin-floor setting, and provides an opportunity to study the deposits of sustained turbidity currents and their interaction with debrite-related topography. Two main gravity-flow facies are identified; (i) slump-derived debris-flow deposits (debrites) — characterised by ungraded silty mudstones in beds 1.5 to > 60 m thick which are rich in large (> 5 m) lithic clasts; and (ii) turbidity current deposits (turbidites) — characterised by medium-grained sandstone in beds up to 2 m thick, which contain structureless (T_a) intervals alternating with planar-parallel (T_b) and current-ripple (T_c) laminated intervals. Laterally discontinuous, cobble-mantled scours are also locally developed within turbidite beds. Based on these characteristics, these sandstones are interpreted to have been deposited by sustained turbidity currents. The cobble-mantled scours indicate either periods of intense turbidity current waxing or individual flow events. The sustained turbidity currents are interpreted to have been derived from retrogressive collapse of sand-rich mouth bars (breaching) or directly from river effluent (hyperpycnal flow). Analysis of the stratal architecture of the two facies indicates that routing of the turbidity currents was influenced by topographic relief developed at the top of the underlying debrite. In addition, turbidite beds are locally eroded at the base of an overlying debrite, possibly due to clast-related substrate ‘ploughing’ during the latter flow event. This study highlights the difficulty in constraining the origin of sustained turbidity currents in ancient sedimentary sequences. In addition, this study documents the importance large debrites may have in generating topography on submarine slopes and influencing routing of subsequent turbidity currents and the geometry of their associated deposits.     

Microbial reduction of ferrous arsenate: Biogeochemical implications for arsenic mobilization

In reduced aqueous environments, the presence of As in solution is a function of both biotic and abiotic mechanisms. Recent studies have demonstrated a significant release of As(III) through the microbial reduction of dissolved and mineral-bound As(V), which raises health concerns when the greater comparative mobility and toxicity of As(III) is considered. These release mechanisms do not operate in isolation but occur in concert with a number of removal processes, including secondary mineralization and sorption to other natural substrates. Thermodynamic and applied experimental studies have shown that ferrous arsenates, such as symplesite [Fe(II)₃(As(V)O₄)₂·8H₂O], may provide a significant sink for Fe(II) and As(V). In this study, the stability of a representative ferrous arsenate phase in the presence of the arsenate-reducing bacterium Shewanella sp. strain ANA-3 is examined. The reduction of ferrous arsenate by ANA-3 results in the release of aqueous As(III) and, subsequently, the progressive nucleation of a biogenic ferrous arsenite phase proximal to the microbial cells. The valence states of secondary solid-phase products were verified using X-ray absorption spectroscopy (XAS). Electron microscopy reveals that nucleation occurs on cellular exudates which may imply a role of extracellular reduction through c-type cytochromes as investigated in recent literature. These observations provide new insights into the reduction mechanisms of ANA-3 and the biogeochemical cycling of As(III) in natural systems.     

A simple expression for vertical convective fluxes in planetary atmospheres

We explore the vertical convective flux F_c in a radiative-convective grey atmosphere. An expression of the form F_c=F_sτ_o/(C+Dτ_o) appears useful, where F_s is the shortwave flux absorbed at the base of an atmosphere with longwave optical depth τ_o and C and D are constants. We find excellent agreement with an idealized grey radiative-convective model with no shortwave absorption for D=1 and C=1∼2 depending on the surface-atmosphere temperature contrast and on the imposed critical lapse rate. Where shortwave absorption is correlated with longwave opacity, as in the atmospheres of Earth and Titan, C=2, D=2 provides an excellent fit, validated against the present terrestrial situation and the results of a nongrey model of Titan's strongly antigreenhouse atmosphere under a wide range of conditions. The expression may be useful for studying the energetics of planetary climates through time where there is insufficient data to constrain more elaborate models.     

Impacts of past climate and sea level change on Everglades wetlands: placing a century of anthropogenic change into a late-Holocene context

We synthesize existing evidence on the ecological history of the Florida Everglades since its inception ??7?ka (calibrated kiloannum) and evaluate the relative impacts of sea level rise, climate variability, and human alteration of Everglades hydrology on wetland plant communities. Initial freshwater peat accumulation began between 6 and 7?ka on the platform underlying modern Florida Bay when sea level was ??6.2?m below its current position. By 5?ka, sawgrass and waterlily peats covered the area bounded by Lake Okeechobee to the north and the Florida Keys to the south. Slower rates of relative sea level rise ??3?ka stabilized the south Florida coastline and initiated transitions from freshwater to mangrove peats near the coast. Hydrologic changes in freshwater marshes also are indicated ??3?ka. During the last ??2?ka, the Everglades wetland was affected by a series of hydrologic fluctuations related to regional to global-scale fluctuations in climate and sea level. Pollen evidence indicates that regional-scale droughts lasting two to four centuries occurred ??1?ka and ??0.4?ka, altering wetland community composition and triggering development of characteristic Everglades habitats such as sawgrass ridges and tree islands. Intercalation of mangrove peats with estuarine muds ??1?ka indicates a temporary slowing or stillstand of sea level. Although sustained droughts and Holocene sea level rise played large roles in structuring the greater Everglades ecosystem, twentieth century reductions in freshwater flow, compartmentalization of the wetland, and accelerated rates of sea level rise had unprecedented impacts on oxidation and subsidence of organic soils, changes/loss of key Everglades habitats, and altered distribution of coastal vegetation.     

A survey of unbalanced flow diagnostics and their application

1.IntroductionImbalanceisdefinedintermsoftowhatextenttheflowdepartsfromabalancedstate.Despitetheapparentcomplexityofatmosphericmotions,thepressure(massfield)andvelocity(momentum)distributioncanberelatedbyrathersimpleapproximateforcebalances(sothatparcelaccelerationscanbeignored).Davisetal.(1996)pointedoutthattheunderlyingassumptionofbalanceddingnosticsisthatthenowevolvesinawayconsistentwiththerestrictionsimplicitwithinthediagnosticframework.ThesimplesttwobalancerelationsaregeostrOPhl'cbalance…     

Salt tectonics driven by differential sediment loading: stability analysis and finite-element experiments

At many continental margins, differential sediment loading on an underlying salt layer drives salt deformation and has a significant impact on the structural evolution of the basin. We use 2‐D finite‐element modelling to investigate systems in which a linear viscous salt layer underlies a frictional‐plastic overburden of laterally varying thickness. In these systems, differential pressure induces the flow of viscous salt, and the overburden experiences updip deviatoric tension and downdip compression. A thin‐sheet analytical stability criterion for the system is derived and is used to predict conditions under which the sedimentary overburden will be unstable and fail, and to estimate the initial velocities of the system. The analytical predictions are in acceptable agreement with initial velocity patterns of the numerical models. In addition to initial stability analyses, the numerical model is used to investigate the subsequent finite deformation. As the systems evolve, overburden extension and salt diapirism occur in the landward section and contractional structures develop in the seaward section. The system evolution depends on the relative widths of the salt basin and the length scale of the overburden thickness variation. In narrow salt basins, overburden deformation is localised and characterised by high strain rates, which cause the system to reach a gravitational equilibrium and salt movement to cease earlier than for wide salt basins. Sedimentation enhances salt evacuation by maintaining a differential pressure in the salt. Continued sedimentary filling of landward extensional basins suppresses landward salt diapirism. Sediment progradation leads to seaward propagation of the landward extensional structures and depocentres. At slow sediment progradation rates, the viscous flow can be faster than the sediment progradation, leading to efficient salt evacuation and salt weld formation beneath the landward section. Fast sediment progradation suppresses the viscous flow, leaving salt pillows beneath the prograding wedge.     

Seismic evidence for the Pleistocene depositional changes in Lake Hovsgol, Mongolia, and implications for the age model and the sediment grain size record of KDP-01 drill core

This paper seeks to arrive at a consistent interpretation of (1) the age model, (2) the grain size record, and (3) seismic reflection data from Lake Hovsgol (a.k.a Khubsugul or Hövsgöl), Mongolia, reported by Fedotov et al. (2007, earlier by Fedotov et al. 2002, 2004). In their most recent contribution, the grain size record of the KDP-01 drill core is interpreted as a climatic signal while little consideration is given to lake-level changes and hence to basin-wide changes in depositional setting evident from seismic profiles; also, a nearly linear age model is at odds with the seismic evidence for a major angular unconformity in the sediment strata. The lack of regional seismic stratigraphic analysis has thus led to an improbable interpretation of the Lake Hovsgol sediment grain size record and ultimately to an improbable scenario of Mongolian glaciation history. Using the available seismic profiles, here we show that the drill core penetrated several transgressive/regressive sedimentary sequences and a major angular unconformity. Therefore, the drilled sediment section cannot represent continuous sediment accumulation and the Brunhes age model across the unconformity cannot be nearly linear; the time interval representing a hiatus remains to be determined. The assumed nearly linear age/depth relationship in the upper 23 m above the angular unconformity is also an unlikely relationship, given the evidence of repeated changes in lake level, and hence in the depositional setting and sedimentation rates. We further propose a qualitative reference model for changes in the Lake Hovsgol depositional setting (presented as a step-by-step animation – see supplementary material) based on manually ‘backstripping and rebuilding’ the seismic pattern. We argue that this model provides a useful template of the likely sediment facies changes in the deep axial part of the Hovsgol basin: our crude model in fact captures the major depositional trends in the KDP-01 drill core section located some 10 km NW along the seismic line. We contend that changes in the depositional setting provide the first-order control on sediment grain size in the Hovsgol record. Our study provides important new constraints on the nature of sedimentary proxy records in Lake Hovsgol and on their interpretation as a record of Mongolian glaciation history.     

The role of organic haze in Titan's atmospheric chemistry: II. Effect of heterogeneous reaction to the hydrogen budget and chemical composition of the atmosphere

One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C₄H₂ and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH₄ due to an episodic CH₄ release into Titan's atmosphere.