14C dating and palaeoenvironment of the historic ‘little ice age’ glacier advance of Nigardsbreen Southwest Norway

Moss and grass remains associated with a well-developed in situ palaeosol buried beneath a moraine ridge in front of Nigardsbreen (Jostedalsbreen ice cap, southern Norway) have been ¹⁴C-dated. Pollen preserved with the plant remains suggests the existence of an agricultural landscape prior to the deposition of the moraine. The calibrated dates and the pollen spectra are in close accord with historically-documented evidence for the timing and palaeoenvironment of the ‘Little Ice Age’ advance of the glacier. Considerable potential is indicated for estimating the maximum ages of moraine ridges and for palaeoenvironmental reconstruction where such documentary evidence does not exist.     

Optical and near-infrared colours as a discriminant of the age and metallicity of stellar populations

We present a comprehensive analysis of the ability of current stellar population models to reproduce the optical ( ugriz ) and near-infrared ( JHK ) colours of a small sample of well-studied nearby elliptical and S0 galaxies. We find broad agreement between the ages and metallicities derived using different population models, although different models show different systematic deviations from the measured broad-band fluxes. Although it is possible to constrain simple stellar population models to a well-defined area in age–metallicity space, there is a clear degeneracy between these parameters even with such a full range of precise colours. The precision to which age and metallicity can be determined independently, using only broad-band photometry with realistic errors, is  Δ[Fe/H]≃ 0.18  and  Δlog Age ≃ 0.25  . To constrain the populations and therefore the star formation history further, it will be necessary to combine broad-band optical–IR photometry with either spectral line indices, or else photometry at wavelengths outside this range.     

Fate and transport of metals in H2S-rich waters at a treatment wetland

The aqueous geochemistry of Zn, Cu, Cd, Fe, Mn and As is discussed within the context of an anaerobic treatment wetland in Butte, Montana. The water being treated had a circum-neutral pH with high concentrations of trace metals and sulfate. Reducing conditions in the wetland substrate promoted bacterial sulfate reduction (BSR) and precipitation of dissolved metal as sulfide minerals. ZnS was the most common sulfide phase found, and consisted of framboidal clusters of individual spheres with diameters in the submicron range. Some of the ZnS particles passed through the subsurface flow, anaerobic cells in suspended form. The concentration of "dissolved" trace metals (passing through a 0.45 μm filter) was monitored as a function of H₂S concentration, and compared to predicted solubilities based on experimental studies of aqueous metal complexation with dissolved sulfide. Whereas the theoretical predictions produce "U-shaped" solubility curves as a function of H₂S, the field data show a flat dependence of metal concentration on H₂S. Observed metal concentrations for Zn, Cu and Cd were greater than the predicted values, particularly at low H₂S concentration, whereas Mn and As were undersaturated with their respective metal sulfides. Results from this study show that water treatment facilities employing BSR have the potential to mobilize arsenic out of mineral substrates at levels that may exceed regulatory criteria. Dissolved iron was close to equilibrium saturation with amorphous FeS at the higher range of sulfide concentrations observed (>0.1 mmol H₂S), but was more likely constrained by goethite at lower H₂S levels. Inconsistencies between our field results and theoretical predictions may be due to several problems, including: (i) a lack of understanding of the form, valence, and thermodynamic stability of poorly crystalline metal sulfide precipitates; (ii) the possible influence of metal sulfide colloids imparting an erroneously high "dissolved" metal concentration; (iii) inaccurate or incomplete thermodynamic data for aqueous metal complexes at the conditions of the treatment facility; and (iv) difficulties in accurately measuring low concentrations of dissolved sulfide in the field.     

Stable isotope ratios in Cape gannets around the southern coasts of Africa reveal penetration of biogeographic patterns in oceanic signatures

The southern coasts of Africa are influenced by two major oceanic currents, leading to biogeographic patterns in inshore and offshore species assemblages, and in the stable isotope signatures of suspended particulate matter and filter-feeding mussels. We used the stable isotope ratios of carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N) from the blood and feathers of adult and chick Cape gannets (Morus capensis) to investigate whether the geographic differences observed at the lower levels in the marine communities are deep penetrating effects that reach top predators. Additionally, we evaluated whether trophic segregation occurs between adult and reared chick gannets, and whether a shift to wintering habitat occurs in adults. The study was conducted during the 2006 breeding season on Bird Island in the Agulhas system, and on Malgas and Ichaboe Islands, in the south and north Benguela respectively. Our results showed significant differences in the isotope ratios of members of different colonies, but no intra-colony differences between tissues or age groups. These results indicate that there is neither age-related nor temporal segregation in the diet of members of the same colony. Feather isotopic values suggest that adults remain all year round in the same habitats, and do not undertake long migration after reproduction. Since all gannets tend to target similar prey, we attributed among-colony differences in isotope signatures mostly to the oceanic conditions experienced by the main prey of birds rather than substantial differences in diet composition. Overall, isotopic signatures segregate the two current systems, with depleted carbon values in the Agulhas and enriched nitrogen values in the upwelled waters of the Benguela. Within the Benguela birds from Ichaboe in the north had higher δ¹⁵N values than those from Malgas in the south, which we attributed to differences in the functioning of the upwelling cells in the vicinity of the two colonies. Finally, slight variation in the proportion of main prey and discards from fisheries may contribute to the variation in the stable-isotope signatures between colonies in the Benguela.     

Distribution and relations of 4- to 10-km-diameter craters to global geologic units of Mars

By correlating the 1:25,000,000 geologic map of Mars of Scott and Carr (1977) with 4- to 10-km-diameter crater density data from Mariner 9 images, the average crater density for 23 of the equatorial geologic-geomorphic units on Mars was computed. The correlation of these two data sets was accomplished by digitizing both the crater density data and geologic map at the same scale and by comparing them in a computer. This technique assigns the crater density value found in the corresponding location on the geologic data set to a discrete computer file assigned each of the 23 geologic units. By averaging the crater density values accumulated in each file, an “average” crater density for each geologic unit was obtained. Condit believes these average crater density values are accurate indicators of the relative age of the geologic units considered. The statistical validity of these average values is strongest for the geologic units of the largest areal extent. The relative ages as obtained from the average crater density values for the seven largest geologic units, from youngest to oldest, are: Tharsis volcanic material, 21 ± 4 craters/10⁶km²; smooth plains material, 57 ± 14 craters/10⁶km²; rolling plains material, 66 ± 16 craters/10⁶km²; plains materials, 80 ± 17 craters/10⁶km²; ridged plains material, 128 ± 25 craters/10⁶km²; hilly and cratered material, 137 ± 38 craters/10⁶km²; and cratered plateau material, 138 ± 27 craters/10⁶km².     

Eccentric geomagnetic dipole drift

A recalculation of the rate of westward drift of the eccentric geomagnetic dipole since 1900 has confirmed its correlation with irregularities in the excess length-of-day (LOD) as originally reported by Vestine. The major changes in the LOD curve since 1900 are shown to be well correlated with the westward drift rate from a number of magnetic models covering the interval. A new Magsat model of secular variation for 1980.0 shows no increase in the drift rate which dropped by a factor of three in the interval 1965–1970.     

A study on the reference frame consistency in recent Earth gravitational models

All gravity field functionals obtained from an Earth gravitational model (EGM) depend on the underlying terrestrial reference frame (TRF), with respect to which the EGM’s spherical harmonic coefficients refer to. In order to maintain a coherent framework for the comparison of current and future EGMs, it is thus important to investigate the consistency of their inherent TRFs, especially when their use is intended for high precision studies. Following the methodology described in an earlier paper by Kleusberg (1980), the similarity transformation parameters between the associated reference frames for several EGMs (including the most recent CHAMP/GRACE models at the time of writing this paper) are estimated in the present study. Specifically, the differences between the spherical harmonic coefficients for various pairs of EGMs are parameterized through a 3D-similarity spatial transformation model that relates their underlying TRFs. From the least-squares adjustment of such a parametric model, the origin, orientation and scale stability between the EGMs’ reference frames can be identified by estimating their corresponding translation, rotation and scale factor parameters. Various aspects of the estimation procedure and its results are highlighted in the paper, including data weighting schemes, the sensitivity of the results with respect to the selected harmonic spectral band, the correlation structure and precision level of the estimated transformation parameters, the effect of the estimated differences of the EGMs’ reference frames on their height anomaly signal, and the overall feasibility of Kleusberg’s formulae for the assessment of TRF inconsistencies among global geopotential models.     

The downward continuation of aerial gravimetric data without density hypothesis

Techniques for downward continuing gravity field data from aircraft altitude are well established if the earth's surface is either approximated by a plane or sphere, or is replaced by one of these surfaces using terrain corrections based on a density model. An alternative procedure is presented here where the continuation is analytical to a nontrivial surface, such as the actual topographic surface. Terrain elevations must be given, but density information is specifically not used.     

Airborne vector gravimetry using precise,position-aided inertial measurement units

Vector gravimetry using a precise inertial navigation system continually updated with external position data, for example using GPS, is studied with respect to two problems. The first concerns the attitude accuracy requirement for horizontal gravity component estimation. With covariance analyses in the space and frequency domains it is argued that with relatively stable uncompensated gyro drift, the short-wavelength gravity vector can be estimated without the aid of external attitude updates. The second problem concerns the state-space estimation of the gravity signal where considerable approximations must be assumed in the gravity model in order to take advantage of the ensemble error estimation afforded by the Kalman filter technique. Gauss-Markov models for the gravity field are specially designed to reflect the attenuation of the signal at a specific altitude and the omission of the long-wavelength components from the estimation. With medium accuracy INS/GPS systems, the horizontal components of gravity with wavelengths shorter than 250 km should be estimable to an accuracy of 4–6 mgal (µg); while high accuracy systems should yield an improvement to 1–2 mgal.