A chromate-contaminated site in southern Switzerland – Part 2: Reactive transport modeling to optimize remediation options

A 2D horizontal reactive transport model of a chromate-contaminated site near Rivera, Switzerland, was developed using the computer code CrunchFlow to evaluate site remediation strategies. Transport processes were defined according to the results of an existing hydrological model, and the definition of geochemical (reactive) processes is based on the results of a detailed mineralogical and geochemical site characterization leading to a comprehensive conceptual site model. Kinetics of naturally occurring Cr(VI) reduction by Fe(II) and natural solid organic matter is quantified by fitting measured Cr isotope ratios to a modeled 1D section along the best constrained flow line. The simulation of Cr isotope fractionation was also incorporated into the 2D model. Simulation of the measured present day Cr(VI) plume and δ⁵³Cr value distribution was used for the 2D model calibration and corresponds to a situation where only monitored natural attenuation (MNA) is occurring. Other 2D model runs simulate alternate excavation scenarios. The simulations show that with an excavation of the top 2–4 m the groundwater Cr(VI) plume can be minimized, and that a deeper excavation depth only diminishes the plume if all the contaminants can be removed. A combination of an excavation of the top 2–4 m and monitoring of the ongoing natural Cr(VI) reduction is suggested as the most ecological and economical remediation strategy, even though a remaining time period with ongoing subsoil Cr(VI) contamination in the order of 1 ka is predicted.     

A chromate-contaminated site in southern Switzerland – Part 1: Site characterization and the use of Cr isotopes to delineate fate and transport

The risk of groundwater contamination by chromate at a former chromite ore processing industrial site in Rivera (Switzerland) was assessed by determining subsoil Cr(VI) concentrations and tracking naturally occurring Cr(VI) reduction with Cr isotopes. Using a hot alkaline extraction procedure, a total Cr(VI) contamination of several 1000 kg was estimated. Jarosite, KFe₃((SO₄)_x(CrO₄)_1−x)₂(OH)₆, and chromatite (CaCrO₄) were identified as Cr(VI) bearing mineral phases using XRD, both limiting groundwater Cr(VI) concentrations. To track assumed Cr(VI) reduction at field scale δ⁵³Cr values of contaminated subsoil samples in addition to groundwater δ⁵³Cr data are used for the first time. The measurements showed a fractionation of groundwater δ⁵³Cr values towards positive values and subsoil δ⁵³Cr towards negative values confirming reduction of soluble Cr(VI) to insoluble Cr(III). Using a Rayleigh fractionation model, a current Cr(VI) reduction efficiency of approximately 31% along a 120 m long flow path was estimated at an average linear groundwater velocity of 3.3 m/d. Groundwater and subsoil δ⁵³Cr values were compared with a site specific Rayleigh fractionation model proposing that subsoil δ⁵³Cr values can possibly be used to track previous higher Cr(VI) reduction efficiency during the period of industrial activity. The findings strongly favor monitored natural attenuation to be part of the required site remediation measures.     

Cone morphologies associated with shallow marine eruptions: east Pico Island, Azores

Eruptions in shallow water typically produce cones of volcaniclastic material. In order to identify any systematic effects of water depth and other environmental parameters on cone morphology, we have measured the heights and widths of cones in multibeam echo-sounder data from a submarine ridge extending southeast from Pico Island, Azores. XRF analyses of dredged samples show that lavas here vary compositionally from alkali basalt to trachybasalt and trachyandesite. Cones in deeper water are generally steep-sided with upper flanks close to 30°, the dip of talus at the angle of repose. However, height/width ratios of cones vary more in shallow water (200?C400-m summit depth) with extreme values below 0.1; while some shallow-water cones are steep-sided as in deep water, others are much flatter. Three such cones lie on a bench at 300-m depth immediately east of Pico Island and have flank slopes of only 10?C20°. We speculate that exceptionally shallow cone slopes here were produced by forced spreading of the erupting columns on reaching the water?Cair density barrier.     

Allochthonous individuals in managed populations of the fire-bellied toad Bombina bombina: Genetic detection and conservation implications

The ongoing global amphibian decline calls for an increase of habitat and population management efforts. Pond restoration and construction is more and more accompanied by breeding and translocation programs. However, the appropriateness of translocations as a tool for conservation has been widely debated, as it can cause biodiversity loss through genetic homogenization and can disrupt local adaptation, eventually leading to outbreeding depression. In this study, we investigated the genetic structure of two translocated populations of the critically endangered fire-bellied toad Bombina bombina at its north western distribution edge using supposedly neutral genetic markers (variation in the mitochondrial control region and microsatellites) as well as a marker under selection (major histocompatibility complex (MHC) genes). While one of the newly established populations showed the typical genetic composition of surrounding populations, the other was extremely diverged without clear affinity to its putative source. In this population we detected a profound impact of allochthonous individuals: 100% of the analyzed individuals exhibited a highly divergent mitochondrial haplotype which was otherwise found in Austria. 83% of them were also assigned to Austria by the analysis of microsatellites. Interestingly, for the adaptive marker (MHC) local alleles were predominant in this population, while only very few alleles were shared with the Austrian population. Probably Mendelian inheritance has reshuffled genotypes such that adaptive local alleles are maintained (here, MHC), while presumably neutral allochthonous alleles dominate at other loci. The release of allochthonous individuals generally increased the genetic variability of the affected population without wiping out locally adaptive genotypes. Thus, outbreeding depression might be less apparent than sometimes thought and natural selection appears strong enough to maintain locally adaptive alleles, at least in functionally important immune system genes.     

The diurnal variation of polar mesospheric cloud frequency near 55°N observed by SHIMMER

We present the first measurement of polar mesospheric cloud (PMC) occurrence frequency over the diurnal cycle from a satellite. The observations are made during the 2007 northern hemisphere PMC season by the Spatial Heterodyne IMager for MEsospheric Radicals (SHIMMER), which views the limb near 309 nm typically between 34 and 98 km. The PMC diurnal variation is derived between 50 and 58°N, where local times at the tangent point precess by ～30 min/day allowing for observations between 0330 and 2130 local time during the PMC season. We find that the occurrence frequencies exhibit a strong semidiurnal behavior with peaks near 0600 and 1800 local time and a minimum between 0900 and 1600 during which they are on average an order of magnitude less. The semidiurnal dependence is strongly correlated with concurrent ground-based measurements of meridional winds and temperatures measured at the same latitude. Our results for PMC frequency over the diurnal cycle can be used to help reconcile observations from other satellites that only permit cloud measurements at discrete local times.     

High-altitude data assimilation system experiments for the northern summer mesosphere season of 2007

A global numerical weather prediction system is extended to the mesosphere and lower thermosphere (MLT) and used to assimilate high-altitude satellite measurements of temperature, water vapor and ozone from MLS and SABER during May–July 2007. Assimilated temperature and humidity from 100 to 0.001 hPa show minimal biases compared to satellite data and existing analysis fields. Saturation ratios derived diagnostically from these assimilated temperature and water vapor fields at PMC altitudes and latitudes compare well with seasonal variations in PMC frequency measured from the aeronomy of ice in the mesosphere (AIM) satellite. Synoptic maps of these diagnostic saturation ratios correlate geographically with three independent transient mesospheric cloud events observed at midlatitudes by SHIMMER on STPSat-1 and by ground observers during June 2007. Assimilated temperatures and winds reveal broadly realistic amplitudes of the quasi 5-day wave and migrating tides as a function of latitude and height. For example, analyzed winds capture the dominant semidiurnal MLT wind patterns at 55°N in June 2007 measured independently by a meteor radar. The 5-day wave and migrating diurnal tide also modulate water vapor mixing ratios in the polar summer MLT. Possible origins of this variability are discussed.     

Long-term changes in annual maximum snow depth and snowfall in Switzerland based on extreme value statistics

Mountain snow cover is an important source of water and essential for winter tourism in Alpine countries. However, large amounts of snow can lead to destructive avalanches, floods, traffic interruptions or even the collapse of buildings. We use annual maximum snow depth and snowfall data from 25 stations (between 200 and 2,500?m) collected during the last 80 winters (1930/31 to 2009/2010) to highlight temporal trends of annual maximum snow depth and 3-day snowfall sum. The generalized extreme value (GEV) distribution with time as a covariate is used to assess such trends. It allows us in particular to infer how return levels and return periods have been modified during the last 80?years. All the stations, even the highest one, show a decrease in extreme snow depth, which is mainly significant at low altitudes (below 800?m). A negative trend is also observed for extreme snowfalls at low and high altitudes but the pattern at mid-altitudes (between 800 and 1,500?m) is less clear. The decreasing trend of extreme snow depth and snowfall at low altitudes seems to be mainly caused by a reduction in the magnitude of the extremes rather than the scale (variability) of the extremes. This may be caused by the observed decrease in the snow/rain ratio due to increasing air temperatures. In contrast, the decreasing trend in extreme snow depth above 1,500?m is caused by a reduction in the scale (variability) of the extremes and not by a reduction in the magnitude of the extremes. However, the decreasing trends are significant for only about half of the stations and can only be seen as an indication that climate change may be already impacting extreme snow depth and extreme snowfall.     

The value of technology and of its evolution towards a low carbon economy

This paper assesses the economic value associated with the development of various low-carbon technologies in the context of climate stabilization. We analyze the impact of restrictions on the development of specific mitigation technologies, comparing three integrated assessment models used in the RECIPE comparison exercise. Our results indicate that the diversification of the carbon mitigation portfolio is an important determinant of the feasibility of climate policy. Foregoing specific low carbon technologies raises the cost of achieving the climate policy, though at different rates. CCS and renewables are shown to have the highest value, given their flexibility and wide coverage. The costs associated with technology failure are shown to be related to the role that each technology plays in the stabilization scenario, but also to the expectations about their technological progress. In particular, the costs of restriction of mature technologies can be partly compensated by more innovation and technological advancement.     

Evaluation of the Interpretation of Ceilometer Data with RASS and Radiosonde Data

Since 2006 different remote monitoring methods for determining mixing-layer height have been operated in parallel in Augsburg (Germany). One method is based on the operation of eye-safe commercial mini-lidar systems (ceilometers). The optical backscatter intensities recorded with ceilometers provide information about the range-dependent aerosol concentration; gradient minima within this profile mark the tops of mixed layers. Special software for these ceilometers provides routine retrievals of lower atmospheric layering. A second method, based on sodar observations, detects the height of a turbulent layer characterized by high acoustic backscatter intensities due to thermal fluctuations and a high variance of the vertical velocity component. This information is extended by measurements with a radio-acoustic sounding system (RASS) that directly provides the vertical temperature profile from the detection of acoustic signal propagation and thus temperature inversions that mark atmospheric layers. Ceilometer backscatter information is evaluated by comparison with parallel measurements. Data are presented from 2 years of combined ceilometer and RASS measurements at the same site and from comparison with a nearby (60 km) radiosonde for larger-scale humidity information. This evaluation is designed to ensure mixing-layer height monitoring from ceilometer data more reliable.