Measurements of spectral emittance at wavelengths from 5 to 25 m were carried out for various particulate rocks and minerals (granite, calcite, talk) in dependence on particle size. The experimentally found variation of spectral features with particle size is discussed in terms of photon's mean free path and its dependence on particle size in the wavelength regions characterized by normal and anomalous dispersion, respectively. Moreover, a sample consisting of fine- and coarse-grained material was investigated in order to estimate the chance for mineral identification at conditions relevant to remote sensing of planetary objects. The mixture spectrum comprises characteristic features of both grain size fractions. This implies that the mineralogical composition of the fine-grained fraction also should be accessible by use of high-sensitive spectrometers. 相似文献
The water resources that supply most of the megacities in the world are under increased pressure because of land transformation, population growth, rapid urbanization, and climate-change impacts. Dhaka, in Bangladesh, is one of the largest of 22 growing megacities in the world, and it depends on mainly groundwater for all kinds of water needs. The regional groundwater-flow model MODFLOW-2005 was used to simulate the interaction between aquifers and rivers in steady-state and transient conditions during the period 1981–2013, to assess the impact of development and climate change on the regional groundwater resources. Detailed hydro-stratigraphic units are described according to 150 lithology logs, and a three-dimensional model of the upper 400 m of the Greater Dhaka area was constructed. The results explain how the total abstraction (2.9 million m3/d) in the Dhaka megacity, which has caused regional cones of depression, is balanced by recharge and induced river leakage. The simulated outcome shows the general trend of groundwater flow in the sedimentary Holocene aquifers under a variety of hydrogeological conditions, which will assist in the future development of a rational and sustainable management approach.
A 2D horizontal reactive transport model of a chromate-contaminated site near Rivera, Switzerland, was developed using the computer code CrunchFlow to evaluate site remediation strategies. Transport processes were defined according to the results of an existing hydrological model, and the definition of geochemical (reactive) processes is based on the results of a detailed mineralogical and geochemical site characterization leading to a comprehensive conceptual site model. Kinetics of naturally occurring Cr(VI) reduction by Fe(II) and natural solid organic matter is quantified by fitting measured Cr isotope ratios to a modeled 1D section along the best constrained flow line. The simulation of Cr isotope fractionation was also incorporated into the 2D model. Simulation of the measured present day Cr(VI) plume and δ53Cr value distribution was used for the 2D model calibration and corresponds to a situation where only monitored natural attenuation (MNA) is occurring. Other 2D model runs simulate alternate excavation scenarios. The simulations show that with an excavation of the top 2–4 m the groundwater Cr(VI) plume can be minimized, and that a deeper excavation depth only diminishes the plume if all the contaminants can be removed. A combination of an excavation of the top 2–4 m and monitoring of the ongoing natural Cr(VI) reduction is suggested as the most ecological and economical remediation strategy, even though a remaining time period with ongoing subsoil Cr(VI) contamination in the order of 1 ka is predicted. 相似文献
An analysis is presented of an ensemble of regional climate model (RCM) experiments from the ENSEMBLES project in terms of mean winter snow water equivalent (SWE), the seasonal evolution of snow cover, and the duration of the continuous snow cover season in the European Alps. Two sets of simulations are considered, one driven by GCMs assuming the SRES A1B greenhouse gas scenario for the period 1951–2099, and the other by the ERA-40 reanalysis for the recent past. The simulated SWE for Switzerland for the winters 1971–2000 is validated against an observational data set derived from daily snow depth measurements. Model validation shows that the RCMs are capable of simulating the general spatial and seasonal variability of Alpine snow cover, but generally underestimate snow at elevations below 1,000 m and overestimate snow above 1,500 m. Model biases in snow cover can partly be related to biases in the atmospheric forcing. The analysis of climate projections for the twenty first century reveals high inter-model agreement on the following points: The strongest relative reduction in winter mean SWE is found below 1,500 m, amounting to 40–80 % by mid century relative to 1971–2000 and depending upon the model considered. At these elevations, mean winter temperatures are close to the melting point. At higher elevations the decrease of mean winter SWE is less pronounced but still a robust feature. For instance, at elevations of 2,000–2,500 m, SWE reductions amount to 10–60 % by mid century and to 30–80 % by the end of the century. The duration of the continuous snow cover season shows an asymmetric reduction with strongest shortening in springtime when ablation is the dominant factor for changes in SWE. We also find a substantial ensemble-mean reduction of snow reliability relevant to winter tourism at elevations below about 1,800 m by mid century, and at elevations below about 2,000 m by the end of the century. 相似文献
We studied the internal lake processes that control the spatial distribution and characteristics of modern sediments at the
ICDP (International Continental Scientific Drilling Program) deep drilling site in Laguna Potrok Aike, southern Patagonia,
Argentina. Sediment distribution patterns were investigated using a dense grid of 63 gravity cores taken throughout the lake
basin and 40 additional shoreline samples. Analysis of the surficial sediment distribution points to distinct internal depositional
dynamics induced by wind-driven lake internal currents. Distribution maps illustrate that the spatial characteristics of analysed
variables are linked to high erosional wave activity. Persistent wave action and littoral erosion along all shores, especially
the eastern shore, is caused by prevailing Southern Hemispheric Westerlies. Several sediment variables (grain size, benthic
diatoms, total inorganic carbon and calcium) indicate re-suspension of littoral sediment followed by re-distribution to profundal
accumulation areas near the eastern shore. Variations within the catchment influence sediment characteristics in the north-eastern
bay. That area is characterized by different mineralogical and sedimentological conditions as well as greater accumulation
of pollen, inorganic carbon and diatoms. These findings are related to the influence of episodic inflow into this bay. Spatial
differences in stable isotope values throughout the lake suggest that ephemeral tributaries around the lake basin may also
contribute to the detected spatial sediment variations. 相似文献