A Compilation of New and Published Major and Trace Element Data for NIST SRM 610 and NIST SRM 612 Glass Reference Materials

Microanalytical trace element techniques (such as ion probe or laser ablation ICP-MS) are hampered by a lack of well characterized, homogeneous standards. Two silicate glass reference materials produced by National Institute of Standards and Technology (NIST), NIST SRM 610 and NIST SRM 612, have been shown to be homogeneous and are spiked with up to sixty one trace elements at nominal concentrations of 500 μg g-1 and 50 μg g-1 respectively. These samples (supplied as 3 mm wafers) are equivalent to NIST SRM 611 and NIST SRM 613 respectively (which are supplied as 1 mm wafers) and are becoming more widely used as potential microanalytical reference materials. NIST however, only certifies up to eight elements in these glasses. Here we have compiled concentration data from approximately sixty published works for both glasses, and have produced new analyses from our laboratories. Compilations are presented for the matrix composition of these glasses and for fifty eight trace elements. The trace element data includes all available new and published data, and summaries present the overall average and standard deviation, the range, median, geometric mean and a preferred average (which excludes all data outside ± one standard deviation of the overall average). For the elements which have been certified, there is a good agreement between the compiled averages and the NIST data. This compilation is designed to provide useful new working values for these reference materials.     

Estimating the diffuse attenuation coefficient from optically active constituents in UK marine waters

We report a study of the attenuation of submarine Photosynthetically Active Radiation (PAR) in relation to the concentrations of Optically Active Constituents (OACs) in a range of water types around the United Kingdom. 408 locations were visited between August 2004 and December 2005. The diffuse attenuation coefficient (K_d) was estimated from profiles of downwelling PAR. Concentrations of Suspended Particulate Matter (SPM) were measured gravimetrically and concentrations of phytoplankton chlorophyll (chl) were measured by fluorometrically. Chromophoric Dissolved Organic Matter (CDOM) was measured either by fluorescence or as its proxy, salinity.     

Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers

Volcanic ash (tephra) erupted from the frequently active Campi Flegrei volcano forms layers in many palaeoenvironmental archives across Italy and the Mediterranean. Proximal deposits of 50 of the post-15 ka eruptions have been thoroughly sampled and analysed to produce a complete database of glass compositions (>1900 analyses) to aid identification of these units. The deposits of individual eruptions are compositionally diverse and this variability is often greater than that observed between different units. Many of the tephra units do not have a unique glass chemistry, with compositionally similar tephra often erupted over long periods of time (1000s years). Thus, glass chemistry alone is not enough to robustly correlate most of the tephra from Campi Flegrei, especially in the last 10 kyrs. In order to reliably correlate the eruption units it is important to take into account the stratigraphy, chronology, magnitude, and dispersal of the eruptions, which has been collated to aid identification. An updated chronology is also presented, which was constrained using Bayesian analysis (OxCal) of published radiocarbon dates and ⁴⁰Ar/³⁹Ar ages. All the data presented can be employed to help correlate post-15 ka tephra units preserved in archaeological and Holocene palaeoenvironmental archives. The new database of proximal glass compositions has been used to correlate proximal volcanic deposits through to distal tephra layers in the Lago di Monticchio record (Wulf et al., 2004, Wulf et al., 2008) and these correlations provide information on eruption stratigraphy and the tempo of volcanism at Campi Flegrei.     

A simulated τCDM cosmology cluster catalogue: the NFW profile and the temperature–mass scaling relations

We have extracted over 400 clusters, covering more than two decades in mass, from three simulations of the τ CDM cosmology. This represents the largest uniform catalogue of simulated clusters ever produced. The clusters exhibit a wide variety of density profiles. Only a minority are well-fitted in their outer regions by the widely used density profile of Navarro, Frenk & White (NFW), which is applicable to relaxed haloes. Others have steeper outer density profiles, show sharp breaks in their density profiles, or have significant substructure. If we force a fit to the NFW profile, then the best-fitting concentrations decline with increasing mass, but this is driven primarily by an increase in substructure as one moves to higher masses. The temperature–mass relations for properties measured within a sphere enclosing a fixed overdensity all follow the self-similar form, T ∝ M ^2/3; however, the normalization is lower than the value inferred for observed clusters. The temperature–mass relations for properties measured within a fixed physical radius are significantly steeper then this. Both can be accurately predicted using the NFW model.     

Long-lived Coronal Loop Profiles from TRACE

An initial study of long-lived loops observed with TRACE (Lenz et al., 1999) shows that they have no significant temperature stratification and that they are denser than the classic loop model predicts. Models that agree better with the observations include a loop consisting of a bundle of filaments at different temperatures and a loop with momentum input by MHD waves. Some implications for coronal heating models and mechanisms are discussed.     

The Aspen–Amsterdam void finder comparison project

Despite a history that dates back at least a quarter of a century, studies of voids in the large-scale structure of the Universe are bedevilled by a major problem: there exist a large number of quite different void-finding algorithms, a fact that has so far got in the way of groups comparing their results without worrying about whether such a comparison in fact makes sense. Because of the recent increased interest in voids, both in very large galaxy surveys and in detailed simulations of cosmic structure formation, this situation is very unfortunate. We here present the first systematic comparison study of 13 different void finders constructed using particles, haloes, and semi-analytical model galaxies extracted from a subvolume of the Millennium simulation. This study includes many groups that have studied voids over the past decade. We show their results and discuss their differences and agreements. As it turns out, the basic results of the various methods agree very well with each other in that they all locate a major void near the centre of our volume. Voids have very underdense centres, reaching below 10 per cent of the mean cosmic density. In addition, those void finders that allow for void galaxies show that those galaxies follow similar trends. For example, the overdensity of void galaxies brighter than   m _B =−20  is found to be smaller than about −0.8 by all our void finding algorithms.