Chronology of Quaternary terrace deposits at the locality Hohle Gasse (Pratteln,NW Switzerland)

The Quaternary stratigraphy of the Alpine Foreland consists of distinct terrace levels, which have been assigned to four morphostratigraphic units: Höhere (Higher) Deckenschotter, Tiefere (Lower) Deckenschotter, Hochterrasse (High Terrace) and Niederterrasse (Lower Terrace). Here, we focus on the terrace gravels at Hohle Gasse, SSE of Pratteln near Basel, which are mapped as Tiefere Deckenschotter. Petrographic and morphometric data established from clasts allowed to infer the transport mechanisms and sources of the gravels. Sedimentological analyses indicate that the gravels were transported by a braided river and deposited in a distal glaciofluvial setting. In addition, it can be shown that the majority of the clasts display multiple reworking and only a minority maintained a distinct glaciofluvial shape. Cosmogenic multi-isotope dating using ¹⁰Be and ³⁶Cl allowed direct dating of the sediments at the study site. A depth-profile age of \(2 70_{ - 1 90}^{ + 8 30}\) ka for ¹⁰Be was achieved for the deposits at Hohle Gasse. Unfortunately, no age could be modelled from the ³⁶Cl concentrations as the blank correction was too high. Furthermore, this age proves that the studied terrace level should be assigned to the morphostratigraphic unit Hochterrasse.     

The effect of sampling rate and anti-aliasing filters on high-frequency response spectra

The most commonly used intensity measure in ground-motion prediction equations is the pseudo-absolute response spectral acceleration (PSA), for response periods from 0.01 to 10 s (or frequencies from 0.1 to 100 Hz). PSAs are often derived from recorded ground motions, and these motions are usually filtered to remove high and low frequencies before the PSAs are computed. In this article we are only concerned with the removal of high frequencies. In modern digital recordings, this filtering corresponds at least to an anti-aliasing filter applied before conversion to digital values. Additional high-cut filtering is sometimes applied both to digital and to analog records to reduce high-frequency noise. Potential errors on the short-period (high-frequency) response spectral values are expected if the true ground motion has significant energy at frequencies above that of the anti-aliasing filter. This is especially important for areas where the instrumental sample rate and the associated anti-aliasing filter corner frequency (above which significant energy in the time series is removed) are low relative to the frequencies contained in the true ground motions. A ground-motion simulation study was conducted to investigate these effects and to develop guidance for defining the usable bandwidth for high-frequency PSA. The primary conclusion is that if the ratio of the maximum Fourier acceleration spectrum (FAS) to the FAS at a frequency $f_{saa} $ corresponding to the start of the anti-aliasing filter is more than about 10, then PSA for frequencies above $f_{saa} $ should be little affected by the recording process, because the ground-motion frequencies that control the response spectra will be less than $f_{saa} $ . A second topic of this article concerns the resampling of the digital acceleration time series to a higher sample rate often used in the computation of short-period PSA. We confirm previous findings that sinc-function interpolation is preferred to the standard practice of using linear time interpolation for the resampling.     

Trends in marine debris along the U.S. Pacific Coast and Hawai'i 1998-2007

We assessed amounts, composition, and trends of marine debris for the U.S. Pacific Coast and Hawai'i using National Marine Debris Monitoring Program data. Hawai'i had the highest debris loads; the North Pacific Coast region had the lowest debris loads. The Southern California Bight region had the highest land-based debris loads. Debris loads decreased over time for all source categories in all regions except for land-based and general-source loads in the North Pacific Coast region, which were unchanged. General-source debris comprised 30-40% of the items in all regions. Larger local populations were associated with higher land-based debris loads across regions; the effect declined at higher population levels. Upwelling affected deposition of ocean-based and general-source debris loads but not land-based loads along the Pacific Coast. LNSO decreased debris loads for both land-based and ocean-based debris but not general-source debris in Hawai'i, a more complex climate-ocean effect than had previously been found.     

A review of EU bio-economic models for fisheries: The value of a diversity of models

The lessons learned from a review of thirteen existing European bio-economic models used in the evaluation of EU policies are presented. How these models compare and differ in terms of their biological and economic components, the integration between the components, which indicators are selected and how they are used, are described and analysed. The article concludes that the multitude of construction differences reflects the necessity of adapting the modelling approach to answer different questions. Since real life questions in fisheries are so diverse, answering them requires a diversity of models.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Spatial dimensions of New Zealand's environmental management

New Zealand's regional council boundaries drawn as part of the 1989 local government reforms privilege integrated catchment management. This privilege is now challenged by calls to both fragment and amalgamate councils and centralise decision‐making but with little analytic assessment of the spatial differentiation to support them. The spatial underpinnings of these calls were explored using a case study that assessed the spatial dimensions of environment management. Analysis of the Land Environments and River Environment Classification databases and councils' planning documents highlights challenges local governments face in applying integrated natural resource management within single purpose jurisdictions and implications for wider sustainable development policy.     

A land-use-based modelling chain to assess the impacts of Natural Water Retention Measures on Europe’s Green Infrastructure

This article details the process of integrating models to answer a specific policy-driven question: ‘What could be the impact of proposed Natural Water Retention Measures (NWRMs) on Europe’s Green Infrastructure (GI)?’ It describes the new Land Use Modelling Platform (LUMP), now enabling a high spatial scale (100-m) and large coverage (pan-European), whereby several sector-specific models contribute to assessing the impact of regional-level policy on a given spatial topic of concern. The configuration (land claims and land allocations modules) and calibration (accessibility and biophysical suitability) of the LUMP are explained. Four NWRM scenarios (riparian areas, afforestation, grassland and baseline scenario) are configured to run the simulations. For the reference: year 2006, the spatial representation of GI is based on land-use features of a refined version of the CORINE Land Cover (CLC), and resumed as connected components made of nodes and links.

Mathematical morphological image processing and network graph theory model, available from the free software package GUIDOS (the Joint Research Center of the European Commission), enabled the measurement of the GI connectivity and identified most critical links. Results show that the competition for land claimed by different economic sectors, combined with policy-driven rule-sets for the implementation of different NWRMs, yields very different results for the 2030 land-use projections, and subsequently for the morphology of GI. Three indicators associated with the morphology of GI are computed in order to assess the model outputs for 2030. The indicators are computed to answer the following questions: (1) How is the quantity of GI affected by each of the NWRM, and what proportion of that GI is most valuable? (2) What is the location of the most critical nodes and connectors of GI, and what land-use conversions occur under these? (3) Are the average components getting larger or smaller?

Whereas the grassland measure results in the largest net increase of GI, the afforestation measure results in the overall largest number of hectares of key nodes and links within the network. Land conversions occur under the critical GI nodes and links, with a large increase in agricultural areas, especially for the riparian measure under critical nodes and the grassland measure under critical links. Also predominant is the swapping of land from pasture to forest under critical links with the afforestation measure. The riparian measure most increases the average size of GI components, and all three measures contribute to bridging two large components which were divided in the 2006 land-use map, thus increasing the size of the largest component by more than 50%.     

Assessing future risk: quantifying the effects of sea level rise on storm surge risk for the southern shores of Long Island, New York

Sea level rise threatens to increase the impacts of future storms and hurricanes on coastal communities. However, many coastal hazard mitigation plans do not consider sea level rise when assessing storm surge risk. Here we apply a GIS-based approach to quantify potential changes in storm surge risk due to sea level rise on Long Island, New York. We demonstrate a method for combining hazard exposure and community vulnerability to spatially characterize risk for both present and future sea level conditions using commonly available national data sets. Our results show that sea level rise will likely increase risk in many coastal areas and will potentially create risk where it was not before. We find that even modest and probable sea level rise (.5 m by 2080) vastly increases the numbers of people (47% increase) and property loss (73% increase) impacted by storm surge. In addition, the resulting maps of hazard exposure and community vulnerability provide a clear and useful example of the visual representation of the spatial distribution of the components of risk that can be helpful for developing targeted hazard mitigation and climate change adaptation strategies. Our results suggest that coastal agencies tasked with managing storm surge risk must consider the effects of sea level rise if they are to ensure safe and sustainable coastal communities in the future.     

Spatial scan statistics in vulnerability assessment: an application to mountain hazards

In the European Alps, the concept of risk has increasingly been applied in order to reduce the susceptibility of society to mountain hazards. Risk is defined as a function of the magnitude and frequency of a hazard process times consequences; the latter being quantified by the value of elements at risk exposed and their vulnerability. Vulnerability is defined by the degree of loss to a given element at risk resulting from the impact of a natural hazard. Recent empirical studies suggested a dependency of the degree of loss on the hazard impact, and respective vulnerability (or damage-loss) functions were developed. However, until now, only little information is available on the spatial characteristics of vulnerability on a local scale; considerable ranges in the loss ratio for medium process intensities only provide a hint that there might be mutual reasons for lower or higher loss rates. In this paper, we therefore focus on the spatial dimension of vulnerability by searching for spatial clusters in the damage ratio of elements at risk exposed. By using the software SaTScan, we applied an ordinal data model and a normal data model in order to detect spatial distribution patterns of five individual torrent events in Austria. For both models, we detected some significant clusters of high damage ratios, and consequently high vulnerability. Moreover, secondary clusters of high and low values were found. Based on our results, the assumption that lower process intensities result in lower damage ratios, and therefore in lower vulnerability, and vice versa, has to be partly rejected. The spatial distribution of vulnerability is not only dependent on the process intensities but also on the overall land use pattern and the individual constructive characteristics of the buildings exposed. Generally, we suggest the use of a normal data model for test sites exceeding a minimum of 30 elements at risk exposed. As such, the study enhanced our understanding of spatial vulnerability patterns on a local scale.     

Specific effects of background electrolytes on the kinetics of step propagation during calcite growth

The mechanisms by which background electrolytes modify the kinetics of non-equivalent step propagation during calcite growth were investigated using Atomic Force Microscopy (AFM), at constant driving force and solution stoichiometry. Our results suggest that the acute step spreading rate is controlled by kink-site nucleation and, ultimately, by the dehydration of surface sites, while the velocity of obtuse step advancement is mainly determined by hydration of calcium ions in solution. According to our results, kink nucleation at acute steps could be promoted by carbonate-assisted calcium attachment. The different sensitivity of obtuse and acute step propagation kinetics to cation and surface hydration could be the origin of the reversed geometries of calcite growth hillocks (i.e., rate of obtuse step spreading < rate of acute step spreading) observed in concentrated (ionic strength, IS = 0.1) KCl and CsCl solutions. At low IS (0.02), ion-specific effects seem to be mainly associated with changes in the solvation environment of calcium ions in solution. With increasing electrolyte concentration, the stabilization of surface water by weakly paired salts appears to become increasingly important in determining step spreading rate. At high ionic strength (IS = 0.1), overall calcite growth rates increased with increasing hydration of calcium in solution (i.e., decreasing ion pairing of background electrolytes for sodium-bearing salts) and with decreasing hydration of the carbonate surface site (i.e., increasing ion pairing for chloride-bearing salts). Changes in growth hillock morphology were observed in the presence of Li⁺, F⁻ and , and can be interpreted as the result of the stabilization of polar surfaces due to increased ion hydration. These results increase our ability to predict crystal reactivity in natural fluids which contain significant amounts of solutes.