TIMS measurements of Ra and Ra in the Gulf of Lion, an attempt to quantify submarine groundwater discharge

Submarine groundwater discharge (SGD) is now recognized as an important pathway for water and chemical species fluxes to the coastal ocean. In order to determinate SGD to the Gulf of Lion (France), we measured the activities of ²²⁶Ra and ²²⁸Ra by thermal ionization mass spectrometry (TIMS) in coastal waters and in the deep aquifer waters of the Rhone deltaic plain after pre-concentration of radium by MnO₂. Compared to conventional counting techniques, TIMS requires lower quantities of water for the analyses, and leads to higher analytical precision. Radium isotopes were thus measured on 0.25–2 L water samples containing as little as 20 fg of ²²⁶Ra and 0.2–0.4 fg of ²²⁸Ra with precision equal to 2%. We demonstrate that coastal surface waters samples are enriched in ²²⁶Ra and ²²⁸Ra compared to the samples further offshore. The high precision radium measurements display a small but significant ²²⁶Ra and ²²⁸Ra enrichment within a strip of circa 30 km from the coast. Radium activities decrease beyond this region, entrained in the northern current along the shelf break or controlled by eddy diffusion. The radium excess in the first 30 km cannot be accounted for by the river nor by the early diagenesis. The primary source of the radium enrichment must therefore be ascribed to the discharge of submarine groundwater. Using a mass-balance model, we estimated the advective fluxes of ²²⁶Ra and ²²⁸Ra through SGD to be 5.2 × 10¹⁰ and 21 × 10¹⁰ dpm/d respectively. The ²²⁶Ra activities measured in the groundwater from the Rhone deltaic plain aquifer are comparable to those from other coastal groundwater studies throughout the world. By contrast, ²²⁸Ra activities are higher by up to one order of magnitude. Taking those groundwater radium activities as typical of the submarine groundwater end-member, a minimum volume of 0.24–4.5 × 10¹⁰ l/d is required to support the excess radium isotopes on the inner shelf. This has to be compared with the average rivers water runoff of 15.4 × 10¹⁰ l/d during the study period (1.6 to 29% of the river flow).     

The fresnel interferometric imager

The Fresnel Interferometric Imager has been proposed to the European Space Agency (ESA) Cosmic Vision plan as a class L mission. This mission addresses several themes of the CV Plan: Exoplanet study, Matter in extreme conditions, and The Universe taking shape. This paper is an abridged version of the original ESA proposal. We have removed most of the technical and financial issues, to concentrate on the instrumental design and astrophysical missions. The instrument proposed is an ultra-lightweight telescope, featuring a novel optical concept based on diffraction focussing. It yields high dynamic range images, while releasing constraints on positioning and manufacturing of the main optical elements. This concept should open the way to very large apertures in space. In this two spacecraft formation-flying instrument, one spacecraft holds the focussing element: the Fresnel interferometric array; the other spacecraft holds the field optics, focal instrumentation, and detectors. The Fresnel array proposed here is a 3.6 ×3.6 m square opaque foil punched with 10⁵ to 10⁶ void “subapertures”. Focusing is achieved with no other optical element: the shape and positioning of the subapertures (holes in the foil) is responsible for beam combining by diffraction, and 5% to 10% of the total incident light ends up into a sharp focus. The consequence of this high number of subapertures is high dynamic range images. In addition, as it uses only a combination of vacuum and opaque material, this focussing method is potentially efficient over a very broad wavelength domain. The focal length of such diffractive focussing devices is wavelength dependent. However, this can be corrected. We have tested optically the efficiency of the chromatism correction on artificial sources (500 < λ < 750 nm): the images are diffraction limited, and the dynamic range measured on an artificial double source reaches 6.2 10^− 6. We have also validated numerical simulation algorithms for larger Fresnel interferometric arrays. These simulations yield a dynamic range (rejection factor) close to 10^− 8 for arrays such as the 3.6 m one we propose. A dynamic range of 10^− 8 allows detection of objects at contrasts as high as than 10^− 9 in most of the field. The astrophysical applications cover many objects in the IR, visible an UV domains. Examples are presented, taking advantage of the high angular resolution and dynamic range capabilities of this concept.     

Plant migration and plant communities at the time of the “green Sahara”

Around 8500 cal years BP, at the time of the maximum of the African Humid Period, lakes and wetlands expanded in the present-day Sahara while large paleodrainages were formed or re-actived, in response to an orbitally-induced increase in monsoon rainfall. It has been suggested that the direct consequence of this increase in rainfall was the northward displacement of the Sahara/Sahel boundary, thought to have reached 23°N in central and eastern Africa. Here, we show a more complex situation characterized by an increase in biodiversity as the desert accommodated more humid-adapted species from tropical forests and wooded grasslands: tropical plant species now found some 400 to 500 km to the south probably entered the desert as gallery-forest formations along rivers and lakes where they benefited from permanent fresh water. At the same time, Saharan trees and shrubs persisted, giving rise to a vegetation that has no analogue today. In this article, we present distribution maps of selected plant species to show both the amplitude of the vegetation change compared to the present and the composition of the past plant communities. We also estimate the migration rate of tropical plant taxa to their northernmost position in the Sahara. This study is based on the use of several data sets: a data set of the modern plant distribution in northern Africa and a data set of modern and fossil pollen sites (from the African Pollen Database, http://fpd.mediasfrance.org/ and http://medias.obs-mip.fr/apd/).     

Benthic geochemistry of manganese in the Bay of Biscay,and sediment mass accumulation rate

Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations, Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles, but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant. This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized. The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV) species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate. The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides or sediment traps. The method has also been validated with data collected in other marine sedimentary environments. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Atypical hotspot chains: evidence for a secondary melting zone below the Marquesas (French Polynesia)

The atypical age/distance to the hotspot relationships observed for the Marquesas linear chain, which present a considerable scatter, are best explained considering (1) a Pacific plate motion of 10.5 cm yr^?1 in the N115°E direction and (2) rejuvenation of volcanism in Ua Huka island. New K–Ar ages show that the main hotspot activity in Ua Huka emplaced successively shield olivine tholeiites and post‐shield alkali basalts between 3.11 ± 0.04 and 2.43 ± 0.04 Ma. Then, after a quiescence period of 1.28 ± 0.06 Myr, two small basanitic volcanoes were emplaced between 1.15 ± 0.02 and 0.763 ± 0.013 Ma. With respect to the main hotspot volcanics, their lavas originated from weaker partial melting rates of a deeper source. Field, petrologic and geochemical arguments are consistent with the existence of a secondary melting zone located c. 140 km downstream the Marquesas hotspot, which produced the rejuvenated volcanics.     

A note on 10Be‐derived mean erosion rates in catchments with heterogeneous lithology: examples from the western Central Andes

Millennial catchment–mean erosion rates derived from terrestrial cosmogenic nuclides are generally based on the assumption that the lithologies of the parent rock each contain the same proportion of quartz. This is not always true for large catchments, in particular at the edge of mountainous plateaus where quartz‐rich basement rocks may adjoin sedimentary or volcano‐sedimentary rocks with low quartz content. The western Central Andes is an example of this type of situation. Different quartz contents may be taken into account by weighting the TCN production rates in the catchment. We recall the underlying theory and show that weighting the TCN production rate may also lead to bias in the case of a spatial correlation between erosion rate and lithology. We illustrate the difference between weighted and unweighted erosion rates for seven catchments (16 samples) in southern Peru and northern Chile and show variations up to a factor of 2 between both approaches. In this dataset, calculated erosion rates considering only granitoid outcrops are better correlated with catchment mean slopes than those obtained without taking into account the geological heterogeneity of the drained watershed. This dataset analysis demonstrates that weighting erosion rates by relative proportions of quartz is necessary to evaluate the uncertainties for calculated catchment–mean erosion rates and may reveal the correlation with geomorphic parameters. Copyright © 2015 John Wiley & Sons, Ltd.     

Phytolith indices as proxies of grass subfamilies on East African tropical mountains

The main objective of this paper is to provide researchers that investigate fossil phytolith assemblages and model/data comparisons a new tool for estimating C₃/C₄ grass composition over time. We tested the reliability of modern soil phytolith assemblages and phytolith indices for tracing the dominance of different grass subfamilies and tree cover density. We analyzed modern soil phytolith assemblages from sites over elevation gradients on Mount Kenya (Kenya), Mount Rungwe and around Lake Masoko (southern Tanzania). These data were compared with available botanical data. A phytolith index named Ic, proved to be an effective proxy of the proportions of Pooideae, Arundinoideae and Bambusoideae grasses (mainly C₃ grasses) versus Panicoideae grasses (mainly C₄ grasses), increasing with elevation in East-Africa. When tropical mountains are covered by open habitats (e.g. grasses and shrublands), Ic should be a reliable proxy of the C₃/C₄ grass composition. These results highlight the value of the phytolith index Ic, when interpreting paleo-environmental records from tropical mountains, to: 1) better understand past local and regional C₃/C₄ grass distributions and associated climatic changes and 2) increase the set of C₃/C₄ data available for model/data comparisons.     

Origine des eaux des émergences karstiques chlorurées du Languedoc-Roussillon

The origin of chloride-rich karstic spring waters representative of the Languedoc-Roussillon region has been investigated with a hydrochemical approach. To this end, the major and trace elements most often used in the study of saline environments have been considered (Cl, SO₄, Br, B, Li). This study allowed distinguishing the different end-members of the various chloride-rich karstic spring waters (evaporitic, marine, geothermal). Associated with the Cl, Br and B contents, the Li/SO₄ ratio appeared as a relevant tracer for the determination of the origin of lithium and by extension of the considered waters. To cite this article: O. Hébrard et al., C. R. Geoscience 338 (2006).