Digital data acquisition and analysis: An introduction

There is no doubt that although the price of PCs has fallen, the performance for money continues to rise. As this happens, so the suitability of using general-purpose computing platforms, especially PCs, for specific technical applications increases. This article discusses recent developments and reviews some of the systems which are currently available for data acquisition and analysis in the environmental sciences.     

Microstructures in carbonates from the Alnø and Fen carbonatites

The nature of carbonates and related second phase minerals in carbonatite samples from the Alnø and Fen regions has been studied by optical and transmission electron microscopy, aided by X-ray diffraction and electron microprobe analysis.Calcite, dolomite and ankerite have been found to exhibit two phase microstructures. Coherent ribbons of calcitic material occur in dolomite and ankerite, while the calcite grains commonly contain a fine dispersion of plate-like and sometimes rod-like precipitates. Calcite and dolomite frequently occur in contact with the same crystallographic lattice orientation, the small lattice mismatch being indicated by moiré patterns at the grain boundaries and occasional misfit dislocations.The two-phase structure of calcite in dolomite reported for the first time in this paper is thought to be a high temperature analogue of the modulated microstructures reported recently in calcian sedimentary dolomites (Wenk et al. 1983).     

The Indus-Tsangpo suture zone in Ladakh, northwest Himalaya: Further palaeomagnetic data and implications

A total of 81 samples (244 specimens) from Upper Cretaceous Indus Molasse and Middle to Upper Cretaceous Dras Flyschoids of the Indus-Tsangpo suture zone in Ladakh (northwest Himalaya) has been studied by thermal demagnetization methods.Both formations showed a characteristic magnetization component indicative for equatorial to low northern palaeolatitudes of acquisition. Similar palaeolatitudes have been obtained before from secondary magnetization components of Early Tertiary age in the Ladakh Intrusives and in the Tibetan Sedimentary Series of central Nepal. The present characteristic components are interpreted likewise as secondary magnetizations which stabilized between 50 and 60 m.y. ago, during Greater India's collision with Asia's southern margin.The Dras Flyschoids show another magnetic component which, in case of primary origin, indicates acquisition at a low southern palaeolatitude. If correct, this interpretation supports recent suggestions for Late Cretaceous obduction of an island arc on Greater India's northern margin.     

The microstructure of minerals in coarse-grained Ca-Al-rich inclusions from the Allende meteorite

The microstructure and microchemistry of minerals in Ca-Al-rich, coarse-grained inclusions (CAI) from the Allende meteorite have been investigated with transmission electron microscopy (TEM). Spinels contain only low to moderate dislocation densities and are characterized by a ubiquitous, fine black spotty texture believed to originate from a slightly non-stoichiometric composition. Ti-Al-pyroxenes are relatively featureless, but contain veins of secondary phases apparently deposited in unhealed cracks. Chromite has been identified in the veins, suggesting transport of oxidized iron during alteration. Melilites exhibit the greatest variety of microstructures and are the most heavily altered phase in CAI. High dislocation densities are common and crystals exhibit considerable internal strain, indicating that they have not been annealed. Alteration occurs both as veins along cracks and in fronts extending across several grains. Plagioclase is commonly twinned, but dislocations are rare. The size and morphology of antiphase domains suggest a high temperature of formation with significant low-temperature annealing. Submicron pyroxene precipitates are a ubiquitous and unusual feature of Allende plagioclase whose properties are most consistent with prolonged slow cooling and equilibration after plagioclase crystallization. The precipitates appear to be sufficiently abundant to contain the majority of Mg present in plagioclase but do not easily account for Na and Ti abundances. Wollastonite needles from a cavity in a “fluffy” Type A inclusion exhibit the growth habits and relatively perfect external surfaces indicative of direct condensation from a vapor. Alteration products are predominantly crystalline and alteration of melilite appears to have proceeded primarily by solid-state diffusion at a temperature of approximately 920°K. Overall, the TEM observations suggest that CAI formed under near equilibrium conditions characterized by slow cooling and that solid-state bulk diffusion was the major process affecting their post-crystallization history.     

Catastrophic events reveal the dynamic nature of salt-marsh vegetation in Southern California

Recent hydrological disturbances, including flooding, dry-season streamflow, and drought, greatly altered coastal wetland habitats in sourthern California. At Tijuana Estuary, a six-year study of salt-marsh vegetation patterns during these rare conditions documented substantial temporal variability in plant growth and distribution. Important to cordgrass (Spartina foliosa Trin.) dynamics were the amount and timing of streamflows, which reduced soil salinity and alleviated stresses on plant growth. Poorest growing conditions occurred in 1984 when both river and tidal flows were lacking; soils had low moisture and extreme salinities (avg.=104‰ in September). Plant stress was documented in 1984 as high mortality (62% fewer stems than in 1983) and reduced height (19% less than in 1983). Cordgrass height was greatest in 1980 following winter flooding (20% increase over 1979); densities were greatest in 1983 with summer freshwater influxes (60% increase over 1982). A carbon allocation model is proposed to explain the varied responses.     

Determination of Carbonate Carbon in 41 International Geochemical Reference Samples by Coulometric Method

The carbonate-carbon (CO₂) content of forty-one geochemical reference samples has been determined by coulometric method following acid treatment of the sample for releasing CO₂. The method is superior to the conventional methods in speed, accuracy, sensitivity, specificity, and the coverage of CO₂ range. The results on NBS limestone samples agree well with the certified values. The precision of the method is 0.5 % r.s.d., and the practical detection limit is 10 ppm C.     

Carbon dioxide recovery from industrial processes

The ongoing human-induced emission of carbon dioxide (CO₂) threatens to change the earth's climate. One possible way of decreasing CO₂ emissions is to apply CO₂ removal, which involves recovering of carbon dioxide from energy conversion processes and storing it outside the atmosphere. Since the 1980's, the possibilities for recovering CO₂ from thermal power plants received increasing attention.In this study possible techniques of recovering CO₂ from large-scale industrial processes are assessed.In some industrial processes, e.g. ammonia production, CO₂ is recovered from the process streams to prevent it from interfering with the production process. The CO₂ thus recovered can easily be dehydrated and compressed, at low cost. In the iron and steel industry, carbon dioxide can be recovered from blast furnace gas. In the petrochemical industry CO₂ can be recovered from flue gases, using low-temperature heat for the separation process.Carbon dioxide can be recovered from large-scale industrial processes and in some cases the cost of recovery is significantly less than CO₂ recovery from thermal power plants. Therefore this option should be studied further and should be considered if carbon dioxide removal is introduced on a wide scale.     

Autosuspension and the energetics of two-phase flows: Reply to comments on ‘experimental test of autosuspension’ by J. B. Southard and M. E. Mackintosh

The experimental programme of Southard and Mackintosh (1981) provides a definitive refutation of the autosuspension criterion as it was originally defined. A simple energy budget for dilute two-phase flow is derived from continuum theory of mixtures; it shows that Bagnold's criterion is based on an arbitrary comparison of two elements of the complete two-phase system. It is recommended that facile, ab hoc criteria for the behaviour of such complex flows be avoided in favour of analyses based on fundamental equations of motion.