Nondestructive determination of the physical properties of Antarctic meteorites: Importance for the meteorite—parent body connection

Photogrammetry is a low-cost, nondestructive approach for producing 3-D models of meteorites for the purpose of determining sample bulk density. Coupled with the use of a nondestructive magnetic susceptibility/electrical conductivity field probe, we present measurements for the interrogation of several physical properties, on a set of Antarctic meteorites. Photogrammetry is an effective technique over a range of sample sizes, with meteorite bulk density results that are closely comparable with literature values, determined using Archimedean glass bead or laser scanning techniques. The technique is completely noncontaminating and suitable for the analysis of rare or fragile samples, although there are limitations for analyzing reflective samples. It is also flexible, and, with variations in equipment setup, may be appropriate for samples of a wide range of sizes. X-ray computed tomography analyses of the same meteorite samples yielded slightly different bulk density results, predominantly for samples below 10 g, although the reason for this is unclear. Such analyses are expensive and potentially damaging to certain features of the sample (e.g., organic compounds), but may be useful in expanding the measurements to accommodate an understanding of internal voids within the sample, lending itself to measurement of grain density. Measurements of bulk density are valuable for comparisons with estimates of the bulk densities of asteroids that are suggested as meteorite parent bodies.     

Magnetograph measurements with temperature-sensitive lines

Certain discrepancies between theoretical and empirical calibrations of magnetograph response are resolved by recognizing the existence of line profile changes in magnetic regions. Many of the photospheric lines commonly used for magnetic field measurements weaken greatly in magnetic regions outside of sunspots. Unless due account is made of the line profile change, the magnetograph measurements underestimate magnetic flux and field strengths.The 5250.2 Å line is especially sensitive to weakening in magnetic regions. Measurements made with this line underestimate the true field by a factor ranging from about two on the linear portion of the profile to five near the line core.Kitt Peak National Observatory Contribution No. 500.Operated by the Association of Universities for Research in Astronomy Inc., under contract with the National Science Foundation.     

Trace metals and radionuclides reveal sediment sources and accumulation rates in Jordan Cove, Connecticut

Many small estuaries are influenced by flow restrictions resulting from transportation rights-of-way and other causes. The biogeochemical functioning and history of such systems can be evaluated through study of their sediments. Ten long and six short cores were collected from the length of Jordan Cove, Connecticut, a Long Island Sound subestuary, and analyzed for stratigraphy, radionuclides (¹⁴C, ²¹⁰Pb, ²²⁶Ra, ¹³⁷Cs, and ⁶⁰Co), and metals (Ag, Cd, Cu, Pb, Zn, Fe, and Al). For at least 3,800 yr, rising sea level has gradually inundated Jordan Cove, filling it with mud similar to that currently being deposited there. Long-term sediment accumulation in the cove averaged close to 0.1 cm yr⁻¹ over the last three millennia. Recent sediment accumulation rates decrease inland from 0.84 cm yr⁻¹ to 0.40 cm yr⁻¹, and are slightly faster than relative sea-level rise at this site (0.3 cm yr⁻¹). Similarity of depth distributions of trace metals was used to confirm relative sediment accumulation rates. ⁶⁰Co and Ag are derived from sources outside the cove and its watershed, presumably the Millstone nuclear power plant and regional contaminated sediments, respectively. The combined data suggest that Long Island Sound is an important source of sediment to the cove; a minor part of total sediment is supplied from the local watershed. Trace metal levels are strongly correlated with Fe but not with either organic matter or Al. Sediment quality has declined in the cove over the past 60 yr, but only slightly. Cu, Pb, and Zn data correlate strongly with Fe but not with either organic matter or aluminum. Ratios of Ag to Fe and to trace metals suggest that Ag in the cove is derived almost entirely from Long Island Sound. This result supports the notion that Fenormalized Ag can serve as a better tracer of some kinds of contamination than more common and abundant metals, like Cu, Pb, and Zn. *** DIRECT SUPPORT *** A01BY085 00008     

New insights into rare earth element (REE) particulate generated by cigarette lighters: an electron microscopy and materials science investigation of a poorly understood indoor air pollutant and constraints for urban geochemistry

Cigarette smoking is a well-recognized cause of lung cancer and other diseases and is a major contributor to indoor air pollution in numerous settings worldwide. Most cigarette lighters use rare earth element (REE) mischmetal in their flints in order to aid ignition, and these lighters thus have pyrophoric properties. REE particulate emitted from these lighters presents a complexity in the role of health of smokers that has yet to be explored fully. Furthermore, these particles are likely present in numerous urban settings and contribute to the complexities of urban geochemistry. Details of the material properties of rare earth element (REE) particulate derived from smoking lighters are determined first the first time. Particulate was investigated using back-scatter detection scanning electron microscopy techniques and transmission electron microscopy techniques. Several particle types were observed and demonstrate a diverse range of size and textures, many of which are previously not documented and are much smaller than previous basic scanning electron microscopy investigations. These include irregularly shaped fragments of mischmetal, micrometer-scale spherules, aggregates of nanospherules, and platy sponge-like nanoparticles. All of these particles have significant REE content, and most are of a particle size that can be deposited deep in the lung. The available literature regarding toxicity of REEs and the material science data presented here argues very strongly for cause for concern.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

Terrigenous dissolved organic matter along an estuarine gradient and its flux to the coastal ocean

The contribution of terrigenous organic matter (TOM) to high molecular weight dissolved and particulate organic matter (POM) was examined along the salinity gradient of the Delaware Estuary. Dissolved organic matter (DOM) was fractionated by ultrafiltration into 1–30 kDa (HDOM) and 30 kDa–0.2 μm (VHDOM) nominal molecular weight fractions. Thermochemolysis with tetramethylammonium hydroxide (TMAH) was used to release and quantify lipids and lignin phenols. Stable carbon isotopes, fatty acids and lignin content indicated shifts in sources with terrigenous material in the river and turbid region and a predominantly algal/planktonic signal in the lower estuary and coastal ocean. Thermochemolysis with TMAH released significant amounts of short chain fatty acids (C₉–C₁₃), not seen by traditional alkaline hydrolysis, which appear to be associated with the macromolecular matrix. Lignin phenol distributions in HDOM, VHDOM and particles followed predicted sources with higher concentrations in the river and turbid region of the estuary and lower concentrations in the coastal ocean. TOM comprised 12% of HDOM within the coastal ocean and up to 73% of HDOM within the turbid region of the estuary. In the coastal ocean, TOM from high molecular weight DOM comprised 4% of total DOC. The annual flux of TOM from the Delaware Estuary to the coastal ocean was estimated at 2.0×10¹⁰ g OC year⁻¹ and suggests that temperate estuaries such as Delaware Bay can be significant sources of TOM on a regional scale.     

Spectroscopic determinations of solar rotation

Spectral line shift data obtained from full-disk magnetograms recorded at Mt. Wilson are analyzed for differential rotation. The method of analysis is discussed and the results from the data for 1966 through 1968 are presented. The average equatorial velocity over this period is found to be 1.93 km/sec or 13.76 deg/day (sidereal). This corresponds to a sidereal period of 26.16 days. The average results are = 2.78 × 10^-6 - 3.51 × 10^-7 sin² B - 4.43 × 10^-7 sin⁴ B rad/sec, whereB is the solar latitude. This indicates a smaller decrease of angular velocity with latitude than found by earlier investigators. Variations from day to day are caused by large-scale short-lived velocity fields on the solar surface. There also appear to be secular variations.Currently at the Kitt Peak National Observatory, Tucson, Arizona.