川东长兴组台缘礁滩相储层纵向非均质性特征及形成机制——以川东宣汉盘龙洞长兴组剖面为例

近几年,随着四川盆地海相碳酸盐岩储层勘探的不断加强,碳酸盐岩储层强的非均质性已成为制约礁滩气藏勘探开发的现实问题。以川东宣汉盘龙洞长兴组典型台缘礁滩剖面为研究对象,通过对典型台缘礁滩野外剖面的精细观察,结合镜下薄片及岩矿资料分析,重点探讨了盘龙洞礁滩储层纵向非均质性特征及成因。剖面上礁滩体垂向上存在很强的旋回性和储层非均质性,其储集岩分布、储层厚度、白云岩化程度、溶蚀作用等受海平面周期性的升降变化影响而呈现周期性变化。礁滩储层非均质性受高能相带、海平面升降变化和建设性成岩作用的共同控制,高能相带控制储层原生孔隙的发育,决定了储层的沉积非均质性,白云岩化和溶蚀作用有利于礁滩体储层的形成,大气淡水淋滤改造对于优化储层具有关键作用,海平面升降变化决定了礁滩体旋回性发育,而建设性成岩作用的选择性改造深化了储层非均质性。     

辽西金羊盆地北票组烃源岩生物标志化合物特征及意义

采用气相色谱、气相色谱-质谱技术,研究了辽西金羊盆地北票组烃源岩的生物标志化合物特征,剖析其蕴含的有机质生源、沉积环境、有机质热演化程度等信息.金羊盆地北票组烃源岩样品的正构烷烃的正构烷烃分布图（m/z 85）峰型以"前峰型"的单峰态分布为主,表现出成熟源岩的分布特征;甾烷C₂₉-αββ/（ααα+αββ）值介于0.35~0.58之间,平均为0.50,表明金羊盆地北票组绝大多数烃源岩处于成熟阶段,部分已达生油高峰或高成熟阶段.Pr/Ph值主要介于1.0~3.0之间,表现出弱的姥鲛烷优势;Pr/nC₁₇-Ph/nC₁₈交汇图判识北票组烃源岩以Ⅲ型为主,三环萜烷呈C₂₀为主峰的正态分布,整体表现C₂₄四环二萜含量很高,C₂₄四环二萜/C₂₆三环萜烷比值基本都大于1,SZK01、SZK03井烃源岩的三环萜烷/藿烷比值都低于0.4,烃源岩伽马蜡烷指数分布在0.02~0.30之间,平均值为0.12,说明金羊盆地北票组烃源岩形成于偏氧化性的微咸水-淡水的浅水沉积环境,为典型高等植物输入的沉积相带.     

华北克拉通北缘东段“开原岩群”的解体及重新认识

根据近年来的同位素年代学资料,对分布于辽北地区的一套构造变质岩系（"开原岩群"或"清河镇岩群"）进行了重新认识和划分,并将其重新定义为清河构造混杂岩,由中太古代、新太古代、中元古代、新元古代、二叠纪等不同时代、不同构造环境的地质体组成.其中,中太古代、新太古代、中元古代岩石来自华北克拉通,而新元古代、二叠纪岩石则来自兴蒙造山带.将原沈家堡子岩组重新划分为新太古代变质表壳岩和中-新太古代变质深成岩,原板石沟岩组（或芦家堡子岩组）厘定为中元古代石门岩组,原照北山岩组重新划分为新元古代南平岩片和晚二叠世照北山岩组,将原佟家屯岩组和尖山子火山岩合并为晚二叠世佟家屯岩组.最后,提出了清河构造混杂岩带为华北克拉通与兴蒙造山带的界线以及古亚洲洋在华北板块北缘东段的最终闭合时间为中三叠世早期（约245Ma）的认识.     

祁连山新元古代——早古生代火山作用与铁-铜多金属成矿

祁连山造山带新元古代—早古生代是板块构造演化与成矿的最重要时段,铁、铜多金属矿产资源丰富,成矿作用与新元古代—早古生代火山作用密切相关。根据矿床产出构造位置,将祁连山铁、铜多金属矿床分为4类:大陆裂谷型铁(铜)矿床、岛弧-岛弧裂谷型铜多金属矿床、陆缘裂谷型铜多金属矿床、扩张脊型铜矿床。镜铁山铁(铜)型矿床是新元古代大陆裂谷火山作用过程中热水沉积作用的产物;东沟铜矿为晚寒武世大洋扩张脊火山作用的产物;白银矿田铜多属矿床是奥陶纪与岛弧-岛弧裂谷火山作用的产物;石居里铜矿是晚奥陶纪弧后扩张脊有关火山作用的产物;红沟铜矿则是晚奥陶世陆缘裂谷火山作用的产物。     

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.     

Upscaling permeability for three-dimensional fractured porous rocks with the multiple boundary method

Upscaling permeability of grid blocks is crucial for groundwater models. A novel upscaling method for three-dimensional fractured porous rocks is presented. The objective of the study was to compare this method with the commonly used Oda upscaling method and the volume averaging method. First, the multiple boundary method and its computational framework were defined for three-dimensional stochastic fracture networks. Then, the different upscaling methods were compared for a set of rotated fractures, for tortuous fractures, and for two discrete fracture networks. The results computed by the multiple boundary method are comparable with those of the other two methods and fit best the analytical solution for a set of rotated fractures. The errors in flow rate of the equivalent fracture model decrease when using the multiple boundary method. Furthermore, the errors of the equivalent fracture models increase from well-connected fracture networks to poorly connected ones. Finally, the diagonal components of the equivalent permeability tensors tend to follow a normal or log-normal distribution for the well-connected fracture network model with infinite fracture size. By contrast, they exhibit a power-law distribution for the poorly connected fracture network with multiple scale fractures. The study demonstrates the accuracy and the flexibility of the multiple boundary upscaling concept. This makes it attractive for being incorporated into any existing flow-based upscaling procedures, which helps in reducing the uncertainty of groundwater models.     

Effects of Wave–Current Interaction on Salt Intrusion During a Typhoon Event in a Highly Stratified Estuary

Wave–current interaction (WCI) is important in modulating hydrodynamics and water mixing in estuaries, and thereby the transport of water-borne materials. However, the effects of WCI on salt transport and salt intrusion in estuaries during storm events have been rarely examined. In the present study, we use a coupled atmosphere–ocean–wave–sediment transport (COAWST) modeling system to investigate the effects of WCI on salt intrusion in the highly stratified Modaomen Estuary during Typhoon Hagupit (2008). The model is validated by the measured wave, water elevation, and surface salinity data, and several diagnostic model experiments are conducted. WCI increases the storm surge by 0.8 m at the peak surge (25% of the total surge height). The wave-breaking-induced momentum flux and the Stokes drift increase the magnitude of the landward flow by 0.3 m s^?1 (30% of the total landward flow). In addition, the waves increase water mixing by 2–4 times compared with that without waves. Hence, WCI significantly increases the landward advective salt transport and decreases the steady shear transport. The net effect of the WCI is a significant increase of salt import and salt intrusion during the typhoon event. However, in the aftermath of the storm, the imported salt water is rapidly flushed out by the increased river discharge, and the estuary regains its stratification within one day.     

Application of incomplete similarity theory to the estimation of the mean velocity of debris flows

The mean velocity of debris flow is one of the most important parameters in the design of mitigation structures and in quantitative risk analysis. This study develops a model to predict the mean debris flow velocity observed in the field by applying the incomplete similarity argument. An equation for estimating the Darcy-Weisbach resistance coefficient for debris flows with a volumetric sediment concentration larger than 0.19 is accordingly derived using 128 sets of observation data from nine Chinese gullies, in which both the effect of the volumetric sediment concentration and channel slope on resistance are considered. The derived equation is then verified and compared against five previously published equations by using 61 sets of published observation data from six gullies located in four countries. The applications of the proposed equation are discussed, and the improvements made using the proposed equation are clearly very significant when compared with the previously published equations.     

Application of magnetic adsorbent with silicate and phenyl polymers to adsorb Rhodamine B

The extensive use of Rhodamine B (RhB) for textile, paper, pigment, food, cosmetic, and drug manufacturing and its indiscriminate disposal leads to serious human, biological, and environmental hazards. A magnetic adsorbent with silicate and phenyl polymers (Ph/SiO₂/Fe₃O₄) has been prepared to absorb RhB. The morphology and structure of the adsorbents have been characterized by TGA, XRD, FTIR, and adsorption–desorption measurement. The results revealed that Ph/SiO₂/Fe₃O₄ exhibited a paramagnetic behavior and could easily and quickly be separated from a suspension. The RhB adsorption behavior was almost pH independent due to the adsorption between the phenyl ring of Ph/SiO₂/Fe₃O₄ and RhB by π–π electron-donor–acceptor interactions. The adsorption behavior of RhB adsorption was in good agreement with the Langmuir adsorption isotherm, and the maximum adsorption capacity was 142.186 mg g^?1. Good desorption performance of Ph/SiO₂/Fe₃O₄ showed that this novel magnetic adsorbent cannot only be activated by ethanol extraction process but also reuse by the recovery of magnetic force.     

Probabilistic calibration of a coupled hydro-mechanical slope stability model with integration of multiple observations

Multiple types of responses, such as displacements, ground water level, pore water pressures, water contents, etc., are usually measured in comprehensive monitoring programmes for rainfall-induced landslide prevention. In this study, a probabilistic calibration method for coupled hydro-mechanical modelling of slope stability is presented with integration of multiple types of measurements. A numerical example of a soil slope under rainfall infiltration is illustrated to compare the effects of single and multiple types of responses on parameter estimation and model calibration. The results show that the soil parameters can be estimated with less uncertainty and total uncertainty bounds are narrower with multiple types of responses than with a single type of response. Model calibration based on multiple types of responses can compromise different responses and hence the means and standard deviations of model error are the smallest. A feasible correlation coefficient between soil modulus and permeability can be obtained from model calibration with multiple types of responses and single type of response as long as the responses include displacement data.