页岩孔隙系统研究实验方法

基于页岩孔隙系统的特殊性,讨论了FESEM-QEMSCAN、FIB-FESEM、NANO-CT、氮气吸附法、小角中子散射等几种页岩孔隙系统研究方法的特点和适用范围。指出场发射扫描电镜以及与之结合的能谱和矿物定量评价系统(FESEM-QEMSCAN)是研究页岩纳米级孔隙类型、大小、形态以及矿物分布的基础手段;聚焦离子束扫描电镜、微纳米CT可刻画页岩孔隙系统在三维空间的展布特征,利用获得的三维数据体进行数值模拟,可进一步计算孔隙度、渗透率等物性参数;氮气吸附法可对小于100nm的极微孔隙的孔径、形态进行求算;小角中子散射则可利用孔隙中存在的气体分子,获得孔隙系统连通性等重要参数。最后从页岩岩石组构的角度,探讨了页岩孔隙控制因素,指出有机质含量与成熟度,黏土矿物类型、含量,碎屑颗粒的含量以及成岩强度是影响页岩孔隙系统的主要因素。     

委内瑞拉奥里诺科重油带沉积特征

委内瑞拉奥里诺科重油带是世界上储量最大、开发程度最低的重油富集带。目前对油区主力储层的沉积特征及其演化规律认识并不明确。基于钻井岩心、测井、地震及生物化石等资料,结合盆地构造演化、构造特征、地层特征等因素的分析,重点研究了重油带主力储层的沉积演化特征。结果表明:重油带渐新统-中新统主力储层内主要发育12种岩相和6种岩相组合,其中以河流相岩相组合为主;地层由下到上可以划分出3个完整的海进海退沉积旋回(5个沉积单元);在探讨重油带主力储层沉积砂体平面演化规律的基础之上,建立了受河流控制、潮汐和沿岸流共同影响作用下形成的三角洲沉积模式,以期对类似油气聚集区的勘探、开发有所帮助。     

断层EDF技术在复杂断块构造研究中的应用

复杂断块构造具有断层复杂,小断层广泛发育,断层识别难度大,储层分布及连通性复杂,地震成像不清、资料品质较差等特征。对于此类问题,常规地震资料无法满足断层解释精度要求。提出了一种新的断层EDF解释性处理技术,将地震资料处理与解释融为一体,以提高资料的信噪比和断层的识别能力。断层EDF解释性处理技术是利用扩散滤波和中值倾角滤波相结合的断层增强滤波方法来提高资料的信噪比,突出断层和地层的接触关系,再在滤波后的地震资料数据体上进行分频处理,选择最佳成像频带,突出识别不同规模的断层。通过在涠洲A油田的应用,取得了良好的效果。     

底水油层水平井产液剖面均衡性评价

胜利油田开采底水特征高含水油层的水平井数量多,其中油层向水平井非均衡供液现象普遍。为评价此类水平井产液剖面均衡性,量化其生产动态改善潜力,定义了产液剖面基尼系数GN,并结合现场案例介绍其计算方法,随后统计胜利油田60口样本井,分析GN对见水时间tRL和底水突破前累积产油量QRL的影响,最后据此对GN分级。计算和分析结果表明:GN可以整体表征实际非均衡产液剖面偏离理想均衡产液剖面的程度,通常取值0~1之间,数值越大,均衡性越差;划分GN0.1为产液剖面不均衡,其样本井数54口,占比90%,以理想均衡产液状态为基准,tRL和QRL分别至少有100%和69.5%的提升潜力。     

斯维尔德鲁普盆地天然气水合物成藏条件及分布预测

斯维尔德鲁普盆地是北极地区最重要的含油气盆地之一,研究者普遍认为这一地区可能具有良好的水合物资源潜力,已有的钻井勘探成果也显示了大量天然气水合物存在的迹象;目前国内对北极地区油气的研究尚处于起步阶段,对斯维尔德鲁普盆地也缺乏系统的认识。结合测井资料解释及国内外理论研究成果,介绍了斯维尔德鲁普盆地的油气地质背景,综合分析了盆内水合物成藏的气源条件、温压条件、构造条件和沉积条件,对水合物的分布范围做出了预测并初步估算了盆内水合物所含天然气的资源量。结果表明,斯维尔德鲁普盆地较好地满足了天然气水合物的成藏条件,盆内主要有3个水合物勘探远景区,资源潜力巨大。这一结论对未来在北极地区进行的油气勘探具有重要的参考价值。     

Tin partition behavior and implications for the Furong tin ore formation associated with peralkaline intrusive granite in Hunan Province,China

Tin deposits are often closely associated with granitic intrusions. In this study, we analyzed tin partition coefficients between different fluids and melts (\({\text{D}}_{Sn}^{aq.fl./melt}\)) as well as various crystals and melts \({\text{D}}_{Sn}^{aq.fl./melt}\)(\({\text{D}}_{Sn}^{crystal/melt}\)) from the Furong tin deposit associated with the Qitianling A-type granite. Our experimental results indicate that tin partition behavior is affected by the chemical compositions of fluids, melts, and minerals. Tin is prone to partitioning into the residual magma in fractional crystallization or other differential magmatic processes if the magma originated from crustal sources with high alkali content, high volatile content, and low oxygen fugacity. Highly evolved residual peralkaline granitic magma enriched in tin can lead to tin mineralization in a later stage. Furthermore, the volatiles F and Cl in the magma play important roles in tin partitioning behavior. Low F contents in the melt phase and high Cl content in the aqueous fluid phase are favorable factors for tin partitioning in the aqueous fluid phase. High Cl content in the aqueous fluid catalyzes water–rock interaction and leads to the extraction of tin from tin-bearing minerals. All these findings support a hydrothermal origin for the tin deposits. In light of the geotectonic setting, petrochemical characteristics, and mineralizing physicochemical conditions of the Furong tin deposit, it is inferred that the ore-forming fluid of the Furong tin ore deposit could have derived from the Qitianling peralkaline intrusion.     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.     

Groundwater System Division and Description of Asia

Based on landform, climate, river system, geological structure and hydrogeological structure and from the perspective of systematology, the groundwater system of Asia can be divided into 36 secondary groundwater systems under 11 primary ones by the intercontinental scale. This forms part of the work of the groundwater series map of Asia, which is compiled according to groundwater system division and evaluation of the total amount and types of aquifer, reflecting the large-scale features of groundwater resources in Asia. Systematic profiling of groundwater in this way provides a scientific basis for groundwater exploitation planning and management in Asia, and avoiding disputes over groundwater resources and the environment among Asian countries.     

Characteristics and Genetic Mechanisms of Overpressure in the Depressions of Bohai Bay Basin, China

The distribution and genetic mechanisms of abnormal pressures in the Bohai Bay Basin were systematically analyzed. Abnormal pressures are widely developed in the Bohai Bay Basin, primarily in the Paleogene E2s4, E2s3, Es1, and Ed formations. From the onshore area of the Bohai Bay Basin to the center of the Bozhong area, the top depth of the overpressured zone in each depression increases gradually, the overpressured strata in each depression gradually move to younger formations, and the pressure structure successively alters from single-bottom- overpressure to double-bottom-overpressure and finally to double-top-overpressure. The distribution of overpressured area is consistent with the sedimentary migration controlled by the tectonic evolution of the Bohai Bay Basin, which is closely related to the hydrocarbon-generation capability of active source rocks. The overpressured strata are consistent with the source-rock intervals in each depression; the top of the overpressured zone is synchronous with the hydrocarbon generation threshold in each depression; the hydrocarbon generation capability is positively correlated with the overpressure magnitude in each formation. Undercompaction was the main mechanism of overpressure for depressions with fluid pressure coefficients less than 1.2, whereas hydrocarbon generation was the main mechanism for depressions with fluid pressure coefficients greater than 1.5.