Transmission electron microscopy of subsolidus oxidation and weathering of olivine

Olivine crystals in basaltic andesites which crop out in the Abert Rim, south-central Oregon have been studied by high-resolution and analytical transmission electron microscopy. The observations reveal three distinct assemblages of alteration products that seem to correspond to three episodes of olivine oxidation. The olivine crystals contain rare, dense arrays of coherently intergrown Ti-free magnetite and inclusions of a phase inferred to be amorphous silica. We interpret this first assemblage to be the product of an early subsolidus oxidation event in the lava. The second olivine alteration assemblage contains complex ordered intergrowths on (001) of forsterite-rich olivine and laihunite (distorted olivine structure with Fe³⁺ charge balanced by vacancies). Based on experimental results for laihunite synthesis (Kondoh et al. 1985), these intergrowths probably formed by olivine oxidation between 400 and 800°C. The third episode of alteration involves the destruction of olivine by low-temperature hydrothermal alteration and weathering. Elongate etch-pits and channels in the margins of fresh olivine crystals contain semi-oriented bands of smectite. Olivine weathers to smectite and hematite, and subsequently to arrays of oriented hematite crystals. The textures resemble those reported by Eggleton (1984) and Smith et al. (1987). We find no evidence for a metastable phase intermediate between olivine and smectite (M — Eggleton 1984). The presence of laihunite exerts a strong control on the geometry of olivine weathering. Single laihunite layers and laihunite-forsteritic olivine intergrowths increase the resistance of crystals to weathering. Preferential development of channels between laihunite layers occurs where growth of laihunite produced compositional variations in olivine, rather than where coherency-strain is associated with laihunite-olivine interfaces.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Stellar polarization and the structure of the magnetic field of our galaxy

The stellar polarization data have been examined using a new catalogue containing accurate stellar distances. On the assumption of a magnetic alignment hypothesis, correlations on the larger distance scale indicate the existence of a dominant regular magnetic field, although its characteristics are difficult to determine. Within 500 pc its direction is towardsl45° and beyond this towardsl60°, though it is clear that such a longitudinal model is too simple. There is also some evidence for an inclination of this field to the galactic plane. The distribution of the polarization vectors away from the galactic plane has been examined and it is proposed that the two largest loop structures, previously identified as Supernova remnants, are linked by the regular field. Incremental polarization maps have been produced but they show little correlation with the spiral structure. The polarization appears to be saturated at about 1 kpc from the Sun, which is explained as the result of an observational selection effect. On the smaller distance scales an autocorrelation analysis in different directions has revealed no obvious coherence in the irregular component on scales greater than 50 pc.     

Vertical extent of zonal winds on Venus

Possible interrelationships of different observations have been studied to clear up some obvious inconsistencies and develop a coherent picture of the kinematics of the Venus atmosphere. There is a wind shear in the vicinity of 60 km with vertical dimensions on the order of a scale height. The kinematical model has negligible surface winds, speeds increasing with altitude to approximately 45 km, a layer of high-speed retrograde zonal winds extending from approximately 45 to 60 km, a wind shear between 60 and 65 km, and slow atmospheric motions above this. Spacecraft data show that the region of high-speed winds is thicker on the day side of the planet than on the night side.     

Dynamical interpretation of observed plasmasphere deformations

Based on all of the OGO-5 light ion density measurements (covering the period from March, 1968 to May, 1969), a definition of “isolated plasma regions” was employed to locate the most prominent patches of enhanced light ion densities in the midst of the depleted region, outside of the main plasmasphere. On the dayside, the distribution of these isolated plasma in L.T. vs. L coordinates was quite similar to that of the “detached plasma regions” by Chappell (1974a). On the nightside, however, the new distribution revealed more frequent occurrence of these regions. Elongated thick plasmatails produced during periods of sudden enhancement of convection electric fields and subsequentially thinning and corotating of the plasmatails during quieting periods, in general, could account for the statistical distribution as well as the individual events, such as those between March 27 and April 2, 1968 and Oct. 21 and Oct. 24, 1968. As demonstrated by Kivelson (1976), wave-particle interactions could produce tremendously complicated structures observed in the near vicinity of the plasmapause and far away from the plasmasphere. Examination of H⁺ and He⁺ density measurements for period of Aug. 12–Aug. 20, 1968 indicated that the density reduction of the plasmasphere during a magnetic storm was on the same order of magnitude as that obtained from whistler techniques during a magnetospheric substorm.     

Evidence linking coronal transients to the evolution of coronal holes

The positions of X-ray coronal transients outside of active regions observed during Skylab were superposed on H synoptic charts and coronal hole boundaries for seven solar rotations. We confirmed a detailed spatial association between the transients and neutral lines. We found that most of the transients were related to large-scale changes in coronal hole area and tended to occur on the borders of evolving equatorial holes.Skylab Solar Workshop Post-Doctoral Appointee, 1975–1977.     

Surface properties of asteroids: A synthesis of polarimetry,radiometry, and spectrophotometry

The surface compositions of 110 asteroids are analyzed from statistically representative data sets of polarimetry as a function of phase angle, broad-band radiometry near 10 and 20 μm, and visible and near-infrared spectrophotometry. A comparison of albedos and diameters determined by polarimetry and radiometry shows that a modest upward revision of the radiometric albedo scale is needed and that a single law relating the slope of the polarization-phase curve to geometric albedo may not hold for very dark asteroids. We present reliable adopted albedos and diameters for 56 objects. Roughdi ameters for 52 additional objects are obtained from spectrophotometry using a correlation between albedo and color. Corrections for sampling bias permit investigation of asteroid compositions as a function of diameter, orbit, and other parameters.More than 90% of the minor planets fall into two broad compositional groups, defined by several optical parameters, designated by the symbols C and S. Comparisons with meteorite spectral albedo curves suggest that the two groups are compositionally similar to carbonaceous and stony-metallic meteorites, respectively. C-type asteroids predominate in the belt, especially in the outer half. An unusual distribution of compositions is found between 2.77 and 3.0 AU. Many S-type objects have diameters of 100–200 km; C-type objects are much more common at both larger and smaller sizes. Vesta is unique, being apparently the only differentiated asteroid remaining intact in the belt. The largest C-type objects are compositionally distinct from smaller ones and possibly are metamorphosed. We sketch some implications for meteoritics and for the early history of the solar system and point to the need for further systematic sampling of smaller and fainter objects by these three observational techniques.     

Relationship of intertidal surface sediment chlorophyll concentration to hyperspectral reflectance and chlorophyll fluorescence

Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence, especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance and chlorophyll fluorescence. These two approaches were applied in 4 European estuaries with different sediment characteristics. At each site, paired replicate measurements of hyperspectral reflectance, chlorophyll fluorescence (after 15 min dark adaptation, F_o ¹⁵), sediment water content, and chlorophylla concentrations were taken (including breakdown products: [chla+phaeo]). Sediments were further characterized by grain size and organic content analysis. The spectral signatures of tidal flats dominated by benthic microalgae, mainly diatoms, could be easily distinguished from sites dominated by macrophytes; we present a 3 waveband algorithm that can be used to detect the presence of macrophytes. The normalized difference vegetation index (NDVI) was found to be most strongly correlated to sediment [chla+phaeo], except for the predominantly sandy Sylt stations. F_o ¹⁵ was also significantly correlated to sediment [chla+phaeo] in all but one grid (Sylt grid A). Our results suggest that the functional relationships (i.e., the slopes) between NDVI or fluorescence and [chla+ phaeo] were not significantly different in the muddier grids, although the intercepts could differ significantly, especially for F_o ¹⁵. This suggests a mismatch of the optical depth seen by the reflectometer or fluorometer and the depth sampled for pigment analysis. NDVI appears to be a robust proxy for sediment [chla+phaeo] and can be used to quantify MPB biomass in muddy sediments of mid latitude estuaries.     

Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.