The Messinian salinity crisis in Cyprus: a further step towards a new stratigraphic framework for Eastern Mediterranean

A revised stratigraphic framework for the Messinian succession of Cyprus is proposed demonstrating that the three‐stage model for the Messinian salinity crisis recently established for the Western Mediterranean also applies to the Eastern Mediterranean, at least for its marginal basins. This analysis is based on a multidisciplinary study of the Messinian evaporites and associated deposits exposed in the Polemi, Pissouri, Maroni/Psematismenos and Mesaoria basins. Here, we document for the first time that the base of the unit usually referred to the ‘Lower Evaporites’ in Cyprus does not actually correspond to the onset of the Messinian salinity crisis. The basal surface of this unit rather corresponds to a regional‐scale unconformity, locally associated with an angular discordance, and is related to the erosion and resedimentation of primary evaporites deposited during the first stage of the Messinian salinity crisis. This evidence suggests that the ‘Lower Evaporites’ of the southern basins of Cyprus actually belong to the second stage of the Messinian salinity crisis; they can be thus ascribed to the Resedimented Lower Gypsum unit that was deposited between 5.6 and 5.5 Ma and is possibly coeval to the halite deposited in the northern Mesaoria basin. Primary, in situ evaporites of the first stage of the Messinian salinity crisis were not preserved in Cyprus basins. Conversely, shallow‐water primary evaporites deposited during the third stage of the Messinian salinity crisis are well preserved; these deposits can be regarded as the equivalent of the Upper Gypsum of Sicily. Our study documents that the Messinian stratigraphy shows many similarities between the Western and Eastern Mediterranean marginal basins, implying a common and likely coeval development of the Messinian salinity crisis. This could be reflected also in intermediate and deep‐water basins; we infer that the Lower Evaporites seismic unit in the deep Eastern Mediterranean basins could well be mainly composed of clastic evaporites and that its base could correspond to the Messinian erosional surface.     

Canadian Shield brine from the Con Mine, Yellowknife, NT, Canada: Noble gas evidence for an evaporated Palaeozoic seawater origin mixed with glacial meltwater and Holocene recharge

Dissolved noble gas concentrations were measured in high salinity (270 g/L) Ca(Na)-Cl groundwaters from the Con Mine, Yellowknife, Canada in an effort to discriminate between two possible origins, as either a brine generated by evaporative enrichment in a Paleozoic inland sea, or marine water concentrated by freezing during glacial times. Major ion and isotope geochemistry indicate that brines from the deepest level remain relatively undisturbed by mixing with modern water introduced by mining. Mixing calculations are used to quantify fractions of brine, glacial meltwater and modern water. From this, noble gas concentrations were corrected for excess air with Ne and normalized to 100% brine solution. Over-pressuring of helium and argon in the brine provide age constraints based on the accumulation of geogenic ⁴He and ⁴⁰Ar. Radiogenic age calculations together with the local geological history suggest brine emplacement during early Palaeozoic time, likely during the Devonian when evaporitic inland seas existed in this region. The concentrations of the atmospherically derived noble gases in the brine fraction (Kr = 1.4E-8, Xe = 8.5E-10 cc_STP/cc_H2O) are close to atmospheric equilibrium for brine at 25 °C (Kr = 7.3E-9, Xe = 8.0E-10 cc_STP/cc_H2O), but are far lower than would be expected for closed-system concentration of seawater by freezing (Kr = 2.8E-6, Xe = 4.2E-7 cc_STP/cc_H2O). Thus, despite the complicated mixing history of the brine, the atmospheric and geogenic noble gases provide strong evidence for an origin as air-equilibrated brine from evaporated Paleozoic seawater, which infiltrated via density displacement through existing fractures and faults into the Canadian Shield.     

Hopane,sterane and n-alkane distributions in shallow sediments hosting high arsenic groundwaters in Cambodia

The presence of elevated As in ground waters exploited for drinking water and irrigation in South-East Asia is causing serious impacts on human health. A key mechanism that causes the mobilization of As in these waters is microbially mediated reductive transformation of As-bearing Fe(III) hydrated oxides and the role of degradable organic matter (OM) in this process is widely recognized. A number of different types of OM that drive As release in these aquifers have been suggested, including petroleum derived hydrocarbons naturally seeping into shallow sediments from deeper thermally mature source rocks. However, the amount of information on the characteristics of the OM in South-East Asian aquifers is limited. Here the organic geochemical analyses of the saturated hydrocarbon fractions and radiocarbon analysis, of two additional sites in SE Asia are reported. The results show that the OM in a given sedimentary horizon likely derives from multiple sources including naturally occurring petroleum. The importance of naturally occurring petroleum as one of the sources was clearly indicated by the n-alkane CPI of approximately 1, the presence of an unresolved complex mixture, and hopane (dominated by 17α(H),21β(H) hopanes) and sterane distribution patterns. The results also indicate that the OM in these aquifers varies tremendously in content, character and potential bioavailability. Furthermore, the presence of petroleum derived OM in sediments at both sites doubles the number of locations where their presence has been observed in association with As-rich, shallow aquifers, suggesting that the role of petroleum derived OM in microbially mediated As release might occur over a wider range of geographical locations than previously thought.     

New insights on Late Quaternary Asian palaeomonsoon variability and the timing of the Last Glacial Maximum in southwestern China

A ～6.35 m core (06SD) was retrieved from Lake Shudu, Yunnan Province, China. The sediments spanning the period ～22.6–10.5 kcal. yr BP (6.35–1.44 m) were analysed using a combination of variables including pollen, charcoal, particle size, magnetic susceptibility and loss-on-ignition. The resulting palaeorecord provides a high-resolution reconstruction of Late Pleistocene to Early Holocene climatic and environmental changes in southwestern China. Our findings indicate that from c. 22.6 to 17.7 kcal. yr BP, vegetation assemblages were primarily aligned to sparse xerophytic grassland/tundra or cold-tolerant boreal Pinus forest, indicating that climatic conditions in southwestern China were cold and dry. However, from c. 17.7 to 17.4 kcal. yr BP, the Lake Shudu record is punctuated by marked environmental changes. These include the establishment of denser vegetation cover, a marked expansion of boreal Pinus forest and enhanced hydrological activity in the catchment over centennial timescales, perhaps suggesting that stepwise variations in the Asian Monsoon were triggering fundamental environmental changes over sub-millennial timescales. Thereafter, the pollen record captures a period of environmental instability reflected in fluctuations across all of the variables, which persists until c. 17.1 kcal. yr BP. After c. 17.1 kcal. yr BP, the expansion of steppe vegetation cover and cold–cool mixed forest consisting of mesophilous vegetation such as Tsuga and Picea, thermophilous trees including Ulmus and deciduous Quercus inferred from the Lake Shudu pollen record point to the establishment of warmer, wetter and perhaps more seasonal conditions associated with a strengthening Asian Summer Monsoon during the shift from Pleistocene to Holocene climatic conditions.     

Paleoclimate histories improve access and sustainability in index insurance programs

Proxy-based climate reconstructions can extend instrumental records by hundreds of years, providing a wealth of climate information at high temporal resolution. To date, however, their usefulness for informing climate risk and variability in policy and social applications has been understudied. Here, we apply tree-ring based reconstructions of drought for the last 700 years in a climate index insurance framework to show that additional information from long climate reconstructions significantly improves our understanding of the underlying climate distributions and variability. We further show that this added information can be used to better characterize risk to insurance providers, in many cases providing meaningful reductions in long-term contract costs to farmers in stand-alone policies. The impact of uncertainty on insurance premiums can also be reduced when insurers diversify portfolios, and the availability of long-term climate information from tree rings across a broad geographic range provides an opportunity to characterize spatial correlation in climate risk across geographic regions. Our results are robust to the range of climate variability experienced over the last 400 years and in model simulations of the twenty-first century, even within the context of changing baselines due to low frequency variability and secular climate trends. These results demonstrate the utility of longer-term climate histories in index insurance applications. Furthermore, they make the case from a climate-variability perspective for the continued importance of such approaches to improving the instrumental climate record, even into a non-stationary climate future.     

The Mesoproterozoic in the Nordic countries

During the Mesoproterozoic, central Fennoscandia and Laurentia （Greenland） were characterized by a weakly extensional stress regime, as evident from episodic rapakivi granites, dolerite dykes, continental rift intrusives, sandstone basins and continental flood basalts. Along the southwestern active margin of Fennoscandia, the 1.64-1.52 Ga Gothian and 1.52-1.48 Ga Telemarkian accretionary events resulted in oceanwards continental growth. The 1.47-1.42 Ga Hallandian- Danopolonian event included high-grade metamorphism and granite magmatism in southern Fennoscandia. The pre-Sveconorwegian 1.34-1.14 Ga period is characterized by bimodal magmatism associated with sedimentation, possibly reflecting transcurrent tectonics. The Sveconorwegian orogeny involved polyphase imbrication of terranes between 1.14 and 0.97 Ga, as a result of a collision between Baltica and another major plate, followed by relaxation and post-collisional magmatism between 0. 96 and 0. 90 Ga. Recent geologic data support classical models restoring the Sveconorwegian belt directly to the east of the Grenville belt of Laurentia at 1.0 Ga. Fragments of Paleo-to Mesoproterozoic crust showing late Grenvillian-Sveconorwegian （1.00-0.92 Ga） magmatism and/or metamorphism are exposed in several tectonic levels in the Caledonides of Scandinavia, Svalbard and East Greenland, on both sides of the inferred Iapetus suture. Linking these fragments into a coherent late-Grenvillian tectonic model, however, require additional study.