Summary findings of the fourth international radiocarbon intercomparison (FIRI)(1998–2001)

Interlaboratory comparisons have been widely used in applied radiocarbon science. These are an important part of ongoing quality assurance (QA) programmes, which are vital to the appropriate interpretation of the evidence provided by the ¹⁴C record in Quaternary applications (including climate change and environmental reconstruction). International comparisons of laboratory performance are an essential component of the quality assurance process in radiocarbon dating. If the user community is to have confidence in radiocarbon results, it needs to be assured that laboratories world wide are producing measurements that are reliable and in accordance with ‘good practice’. The findings from the most recent (completed in 2001) and extensive (more than 90 participating laboratories) radiocarbon intercomparison (FIRI) are reported here. This study was designed (i) to assess comparability, or otherwise, of the results from different laboratories and (ii) to quantify the extent and possible causes of any interlaboratory variation. The results demonstrate that there are no significant differences amongst the main measurement techniques (gas proportional counting, liquid scintillation counting and accelerator mass spectrometry (AMS)) but there is evidence of small laboratory offsets relative to known age samples for some laboratories. There is also evidence in some cases of underestimation of measurement precision. Approximately 10% of all results were classified as extreme (outliers) and these results were generated by 14% of the laboratories. Overall, the evidence supports the fact that radiocarbon laboratories are generally accurate and precise but that, notwithstanding internal QA procedures, some problems still occur, which can best be detected by participation in independent intercomparisons such as FIRI, where the results allow individual laboratories to assess their performance and to take remedial measures where necessary. The results from FIRI are significant in that they show a broad measure of agreement between measurements made in different laboratories on a wide range of materials and they also demonstrate no statistically significant difference between measurements made by radiometric or AMS techniques. Copyright © 2002 John Wiley & Sons, Ltd.     

Geomorphic controls on the physical and hydrologic properties of soils in a valley floor

The distribution of soil hydraulic and physical properties strongly influences runoff processes in landscapes. Although much work has been done to quantify and predict the properties of hillslope soils, far less is known about the distribution of soil properties in valley floors. A technique that links the estimation and distribution of soil hydraulic properties in valleys, with easily identified geomorphic features, was developed along a 2 km length of a valley at Brooks Creek in New South Wales, Australia. Soil physical and hydraulic property data were collected across a set of floodplain and fan features within the valley and analysed statistically to determine if soil properties varied significantly between geomorphic features and stratigraphic layers. The results show that the depth‐averaged saturated hydraulic conductivity, K_s, of the soil varies significantly with landform: fan units have K_g values that are twice that of floodplains and colluvial toeslope deposits have K_s values four times higher than floodplains. Given the notorious variability of K_s values in space, the strong statistical separation of soil properties by landform, backed up by strong separation of soil particle size by landform, suggests a way forward in understanding the distribution of soil properties in valleys and their influence on catchment hydrology. Copyright © 2000 John Wiley & Sons, Ltd.     

卡斯特地区的公路设计

１场地考察第一步是利用现有岩土工程资料,如州和政府的资料、航空照片、卫星图像和设计单位的数据库。这些对考察卡斯特地区有用的资料包括：（１）详细地图（这些地图不全发表）,一些州的调查实际上包含有碳酸盐岩石详细地图,从中可了解到已知的或可疑落水洞地区。（...     

Regional Fluxes Of Momentum And Sensible Heat Over A Sub-Arctic Landscape During Late Winter

Based on measurements at Sodankylä Meteorological Observatory the regional (aggregated) momentum and sensible heat fluxes are estimated for two days over a site in Finnish Lapland during late winter. The forest covers 49% of the area. The study shows that the forest dominates and controls the regional fluxes of momentum and sensible heat in different ways. The regional momentum flux is found to be 10–20% smaller than the measured momentum flux over the forest, and the regional sensible heat flux is estimated to be 30–50% of the values measured over a coniferous forest.The regional momentum flux is determined in two ways, both based on blending height theory. One is a parameterised method, the other represents a numerical solution of an aggregation model. The regional sensible heat flux is determined from the theory of mixed-layer growth. At near neutral conditions the regional momentum flux can be determined independently of the regional sensible heat flux. At unstable conditions the two models become coupled.The information that is needed by the parameterised blending height method and by the mixed-layer evolution method in order to derive the regional fluxes of momentum and sensible heat can be obtained from radiosonde profiles of wind speed and temperature.     

Current and future atmospheric circulation at 500 hPa over Greenland simulated by the CMIP3 and CMIP5 global models

The Greenland ice sheet is projected to be strongly affected by global warming. These projections are either issued from downscaling methods (such as Regional Climate Models) or they come directly from General Circulation Models (GCMs). In this context, it is necessary to evaluate the accuracy of the daily atmospheric circulation simulated by the GCMs, since it is used as forcing for downscaling methods. Thus, we use an automatic circulation type classification based on two indices (Euclidean distance and Spearman rank correlation using the daily 500 hPa geopotential height) to evaluate the ability of the GCMs from both CMIP3 and CMIP5 databases to simulate the main circulation types over Greenland during summer. For each circulation type, the GCMs are compared to three reanalysis datasets on the basis of their frequency and persistence differences. For the current climate (1961–1990), we show that most of the GCMs do not reproduce the expected frequency and the persistence of the circulation types and that they simulate poorly the observed daily variability of the general circulation. Only a few GCMs can be used as reliable forcings for downscaling methods over Greenland. Finally, when applying the same approach to the future projections of the GCMs, no significant change in the atmospheric circulation over Greenland is detected, besides a generalised increase of the geopotential height due to a uniform warming of the atmosphere.     

Verification of a scattering-based algorithm for estimating rainfall over the open ocean

Summary An algorithm for estimating rainfall (based upon scattering of upwelling radiation at 85 GHz) using the Special Sensor Microwave Imager (SSM/I) 85 GHz sensor data has recently been developed at the National Oceanographic and Atmospheric Administration's Office of Research and Applications (NOAA ORA). Spatial and temporal variability in the differences between simple areal-averaged rainfall estimates from a raingage and satellite-derived estimates are examined. These initial comparisons provide insight into the nature of the differences; however, due to substantial amounts of spatial sampling error in the raingage spatial averages, this approach is ineffective at identifying statistically significant differences.Thus, rainfall estimates for this algorithm are examined over the tropical Pacific using a statistical technique, called the noncontiguous raingage method (NCR), which minimizes spatial sampling error so that the statistical significance of relationships may be determined. The results indicate that, adjusted with calibration coefficients, the ORA algorithm could produce unbiased estimates of areal rainfall for the tropical Pacific region examined in this study.With 8 Figures     

Magnetic resonance sounding applied to aquifer characterization

Magnetic resonance sounding (MRS) is distinguished from other geophysical tools used for ground water investigation by the fact that it measures a magnetic resonance signal generated directly from subsurface water molecules. An alternating current pulse energizes a wire loop on the ground surface and the MRS signal is generated; subsurface water is indicated, with a high degree of reliability, by nonzero amplitude readings. Measurements with varied pulse magnitudes then reveal the depth and thickness of water saturated layers. The hydraulic conductivity of aquifers can also be estimated using boreholes for calibration. MRS can be used for both predicting the yield of water supply wells and for interpolation between boreholes, thereby reducing the number of holes required for hydrogeological modeling. An example of the practical application of MRS combined with two-dimensional electrical imaging, in the Kerbernez and Kerien catchments area of France, demonstrates the efficiency of the technique.     

Chalcophile element geochemistry of the Boggy Plain zoned pluton, southeastern Australia: a S-saturated barren compositionally diverse magmatic system

The behavior of the platinum group elements (PGE) and Re in felsic magmas is poorly understood due to scarcity of data. We report the concentrations of Ni, Cu, Re, and PGE in the compositionally diverse Boggy Plain zoned pluton (BPZP), which shows a variation of rock type from gabbro through granodiorite and granite to aplite with a SiO₂ range from 52 to 74 wt %. In addition, major silicate and oxide minerals were analyzed for Ni, Cu, and Re, and a systematic sulfide study was carried out to investigate the role of silicate, oxide, and sulfide minerals on chalcophile element geochemistry of the BPZP. Mass balance calculation shows that the whole rock Cu budget hosted by silicate and oxide minerals is <13 wt % and that Cu is dominantly located in sulfide phases, whereas most of the whole rock Ni budget (>70 wt %) is held in major silicate and oxide minerals. Rhenium is dominantly hosted by magnetite and ilmenite. Ovoid-shaped sulfide blebs occur at the boundary between pyroxene phenocrysts and neighboring interstitial phases or within interstitial minerals in the gabbro and the granodiorite. The blebs are composed of pyrrhotite, pyrite, chalcopyrite, and S-bearing Fe-oxide, which contain total trace metals (Co, Ni, Cu, Ag, Pb) up to ~16 wt %. The mineral assemblage, occurrence, shape, and composition of the sulfide blebs are a typical of magmatic sulfide. PGE concentrations in the BPZP vary by more than two orders of magnitude from gabbro (2.7–7.8 ppb Pd, 0.025–0.116 ppb Ir) to aplite (0.05 ppb Pd, 0.001 ppb Ir). Nickel, Cu, Re, and PGE concentrations are positively correlated with MgO in all the rock types although there is a clear discontinuity between the granodiorite and the granite in the trends for Ni, Rh, and Ir when plotted against MgO. Cu/Pd values gradually increase from 6,100 to 52,600 as the MgO content decreases. The sulfide petrology and chalcophile element geochemistry of the BPZP show that sulfide saturation occurred in the late gabbroic stage of magma differentiation. Segregation and distribution of these sulfide blebs controlled Cu and PGE variations within the BPZP rocks although the magma of each rock type may have experienced a different magma evolution history in terms of crustal assimilation and crystal fractionation. The sulfide melt locked in the cumulate rocks must have sequestered a significant portion of the chalcophile elements, which restricted the availability of these metals to magmatic-hydrothermal ore fluids. Therefore, we suggest that the roof rocks that overlay the BPZP were not prospective for magmatic-hydrothermal Cu, Au, or Cu–Au deposits.     

An integrated zircon geochronological and geochemical investigation into the Miocene plutonic evolution of the Cyclades, Aegean Sea, Greece: Part 1: Geochronology

We use 369 individual U–Pb zircon ages from 14 granitoid samples collected on five islands in the Cyclades in the Aegean Sea, Greece, for constraining the crystallisation history of I- and S-type plutons above the retreating Hellenic subduction zone. Miocene magmatism in the Cyclades extended over a time span from 17 to 11 Ma. The ages for S-type granites are systematically ~2 million years older than those for I-type granites. Considering plutons individually, the zircon data define age spectra ranging from simple and unimodal to complex and multimodal. Seven of the 14 investigated samples yield more than one distinct zircon crystallisation age, with one I-type granodiorite sample from Mykonos Island representing the most complex case with three resolvable age peaks. Two samples from S-type granites on Ikaria appear to have crystallised zircon over 2–3 million years, whereas for the majority of individual samples with multiple zircon age populations the calculated ages deviate by 1–1.5 million years. We interpret our age data to reflect a protracted history involving initial partial melting at deeper lithospheric levels, followed by crystallisation and cooling at shallower crustal levels. Our study corroborates published research arguing that pluton construction is due to incremental emplacement of multiple magma pulses over a few million years. Assuming that multiple age peaks of our 14 samples can indeed serve to quantify time spans for magmatic emplacement, our data suggest that Aegean plutons were constructed over a few million years. Our tectonic interpretation of the U–Pb ages is that the S-type granites resulted from partial melting and migmatisation of the lower crust, possibly starting at ~23 Ma. The I-type granites and associated mafic melts are interpreted to reflect the magmatic arc stage in the Cyclades starting at ~15 Ma.     

Nutrient Budgets and Management Actions in the Patuxent River Estuary,Maryland

Multi-year nitrogen (N) and phosphorus (P) budgets were developed for the Patuxent River estuary, a seasonally stratified and moderately eutrophic tributary of Chesapeake Bay. Major inputs (point, diffuse, septic, and direct atmospheric) were measured for 13 years during which, large reductions in P and then lesser reductions in N-loading occurred due to wastewater treatment plant improvements. Internal nutrient losses (denitrification and long-term burial of particulate N and P) were measured in tidal marshes and sub-tidal sediments throughout the estuary as were nutrient storage in the water column, sediments, and biota. Nutrient transport between the oligohaline and mesohaline zones and between the Patuxent and Chesapeake Bay was estimated using a salt and water balance model. Several major nutrient recycling terms were directly and indirectly evaluated and compared to new N and P inputs on seasonal and annual time-scales. Major findings included: (1) average terrestrial and atmospheric inputs of N and P were very close to the sum of internal losses plus export, suggesting that dominant processes are captured in these budgets; (2) both N and P export were a small fraction (13% and 28%, respectively) of inputs, about half of that expected for N based on water residence times, and almost all exported N and P were in organic forms; (3) the tidal marsh-oligohaline estuary, which by area comprised ~27% of the full estuarine system, removed about 46% and 74% of total annual upland N and P inputs, respectively; (4) recycled N and P were much larger sources of inorganic nutrients than new inputs during warm seasons and were similar in magnitude even during cold seasons; (5) there was clear evidence that major estuarine processes responded rapidly to inter-annual nutrient input variations; (6) historical nutrient input data and nutrient budget data from drought periods indicated that diffuse nutrient sources were dominant and that N loads need to be reduced by about 50% to restore water quality conditions to pre-eutrophic levels.