On the mechanics of basin formation in the Pannonian basin: Inferences from analogue and numerical modelling

We present the results of a thrust fault reactivation study that has been carried out using analogue (sandbox) and numerical modelling techniques. The basement of the Pannonian basin is built up of Cretaceous nappe piles. Reactivation of these compressional structures and connected weakness zones is one of the prime agents governing Miocene formation and Quaternary deformation of the basin system. However, reactivation on thrust fault planes (average dip of ca. 30°) in normal or transtensional stress regimes is a problematic process in terms of rock mechanics. The aim of the investigation was to analyse how the different stress regimes (extension or strike-slip), and the geometrical as well as the mechanical parameters (dip and strike of the faults, frictional coefficients) effect the reactivation potential of pre-existing faults.

Results of analogue modelling predict that thrust fault reactivation under pure extension is possible for fault dip angle larger than 45° with normal friction value (sand on sand) of the fault plane. By making the fault plane weaker, reactivation is possible down to 35° dip angle. These values are confirmed by the results of numerical modelling. Reactivation in transtensional manner can occur in a broad range of fault dip angle (from 35° to 20°) and strike angle (from 30° to 5° with respect to the direction of compression) when keeping the maximum horizontal stress magnitude approximately three times bigger than the vertical or the minimum horizontal stress values.

Our research focussed on two selected study areas in the Pannonian basin system: the Danube basin and the Derecske trough in its western and eastern part, respectively. Their Miocene tectonic evolution and their fault reactivation pattern show considerable differences. The dominance of pure extension in the Danube basin vs. strike-slip faulting (transtension) in the Derecske trough is interpreted as a consequence of their different geodynamic position in the evolving Pannonian basin system. In addition, orientation of the pre-existing thrust fault systems with respect to the Early to Middle Miocene paleostress fields had a major influence on reactivation kinematics.

As part of the collapsing east Alpine orogen, the area of the Danube basin was characterised by elevated topography and increased crustal thickness during the onset of rifting in the Pannonian basin. Consequently, an excess of gravitational potential energy resulted in extension (σ_v > σ_H) during Early Miocene basin formation. By the time topography and related crustal thickness variation relaxed (Middle Miocene), the stress field had rotated and the minimum horizontal stress axes (σ_h) became perpendicular to the main strike of the thrusts. The high topography and the rotation of σ_h could induce nearly pure extension (dip-slip faulting) along the pre-existing low-angle thrusts. On the contrary, the Derecske trough was situated near the Carpathian subduction belt, with lower crustal thickness and no pronounced topography. This resulted in much lower σ_v value than in the Danube basin. Moreover, the proximity of the retreating subduction slab provided low values of σ_h and the oblique orientation of the paleostress fields with respect to the master faults of the trough. This led to the dominance of strike-slip faulting in combination with extension and basin subsidence (transtension).     

High temperature alteration of Abyssal ultramafics from the Islas Orcadas Fracture Zone,South Atlantic

Ultramafic rocks dredged from the Islas Orcadas Fracture Zone, along the SW Indian Ocean Ridge (6° E and 54° S), show evidence of progressive hydration beginning at temperatures greater than 600° C (and perhaps as high as 900° C) and continuing to less than 50° C. There are two principal types of alteration present in the ultramafic rocks, both of which are the result of hydration reactions. The first type of alteration involves hydration of original clinopyroxene, orthopyroxene and olivine to amphibole, talc, secondary olivine, and serpentine. The second is a vein type of alteration and results in the formation of veins of amphibole, chlorite, talc and serpentine. — The alteration appears to be episodic. The sequence of events suggested by the petrography is: 1) clinopyroxene altering to amphibole; 2) orthopyroxene altering to talc, or talc + olivine; 3) supersolvus hornblende veining; 4) coexisting actinolite + hornblende veining; 5) chlorite, chlorite + actinolite, or chlorite + secondary clinopyroxene veining; 6) talc veining; 7) serpentine veining; and 8) pervasive serpentinization. — The alteration fluid is most likely seawater. It is suggested that the high temperature alterations may reflect seawater circulation into the upper mantle.     

Mineralogic variability of the uppermost mantle along mid-ocean ridges

Modal analyses of 273 different peridotites representing 43 dredge stations in the Atlantic, Caribbean, and Indian Oceans define three separate melting trends. Peridotites dredged in the vicinity of “mantle plumes” or hot spots have the most depleted compositions in terms of basaltic components, while peridotites dredged at locations removed from such regions are systematically less depleted. The modal data correlate well with mineral compositions, with the peridotites most depleted in pyroxene also having the most refractory mineral compositions. This demonstrates that they are the probable residues of variable degrees of mantle melting. Further, there is a good correlation between the modal compositions of the peridotites and the major element composition of spatially associated dredged basalts. This demonstrates for the first time that the two must be directly related, as is frequently postulated. The high degree of depletion of the peridotites in basaltic major element components in the vicinity of some documented mantle plumes provides direct evidence for a thermal anomaly in such regions—justifying their frequent designation as “hot spots”. The high incompatible element concentrations in these “plume” basalts, however, are contrary to what is expected for such high degrees of melting, and thus require either selective contributions from locally more abundant enriched veins and/or contamination by a volatile-rich metasomatic front from depth.     

Breaching in fine sands and the generation of sustained turbidity currents in submarine canyons

Abstract Natural, moderately loosely packed sands can only erode from the surface of the bed after an increase in pore volume. Because of this shear dilatancy, negative pore pressures are generated in the bed. In cases of low permeability, these negative pressures are released relatively slowly, which retards the maximum rate of erosion. This effect is incorporated in a new, analytically derived, pick‐up function that can explain the observation of gradual retrogressive failure of very steep subaqueous slopes, sometimes more than 5 m high, in fine non‐cohesive sands. This process, termed ‘breaching’ in the field of sediment dredging, may produce large failures in sand bars or river banks. The analytical function that describes the breaching process in fine sand is incorporated in a one‐dimensional, steady‐state numerical model of turbidity currents describing the spatial development of flow. This model is applied to simulate a large ‘flushing’ event in Scripps Submarine Canyon, Pacific coast of California. Breach retrogradation and the successive evolution in time of the resulting turbidity current in the canyon are predicted in a sequence of discrete steps. Predicted velocities are compared with values measured during a flushing event. Implications for the interpretation of deep‐water massive sands are discussed.     

Organotin accumulation in an estuarine food chain: comparing field measurements with model estimations

The bioaccumulation model OMEGA (optimal modelling for ecotoxicological applications) is used to explore accumulation of organotins in the Western Scheldt food chain, consisting of herbi-detritivores, primary and secondary carnivorous fish and a piscivorous bird. Organotins studied are tributyltin (TBT) and triphenyltin (TPT) and the respective di- and mono-organotin metabolites. Empirical elimination rate constants are compared to model predictions for organic substances and metals. It is found that field bioaccumulation ratios are higher than predicted based on elimination kinetics relevant for organic compounds. The results indicate that uptake of organotins mainly occurs via hydrophobic mechanisms, whereas elimination may occur via metal-like kinetics. This results in very low elimination rates, which are comparable to model predictions for metals.     

Spatial Discontinuities in Support for Hydraulic Fracturing: Searching for a “Goldilocks Zone”

Recent research suggests that those located closer to energy development are, on average, more supportive of this development. However, case studies in specific locations reveal additional nuance. In a case study of Bakken Shale residents, Junod et al. identified a “Goldilocks Zone” of unconventional oil and gas development (UOGD) acceptance—an area on the periphery of development that is “just right” because residents feel close enough to receive economic benefits but far enough away to avoid negative impacts. We explore whether this Goldilocks Zone extends nationally by combining geocoded public opinion data (N?=?23,154) with UOGD locations. Using multilevel regression modeling, we find that respondents located within 115?km of newly active UOGD are more supportive of hydraulic fracturing while those located within 115–305?km are comparatively less supportive. While we do not uncover a national-level Goldilocks Zone, our work highlights innovative approaches for examining spatial relationships in energy development opinion.     

A weight-of-evidence approach to assessing the ecological impact of organotin pollution in Dutch marine and brackish waters; combining risk prognosis and field monitoring using common periwinkles (Littorina littorea)

In the present study an integrated ecological risk assessment based on multiple lines of evidence (LOEs) was evaluated in order to better assess the risk from TBT in Dutch harbours and open coastal waters. On the basis of spatial distributions of measured tributyltin (TBT) concentrations in sediments and suspended matter, predictions of the intersex index (ISI) in Littorina littorea and the ecological risk expressed as the Potentially Affected Fraction (PAF) of species were made. The results were compared to actual ISI measurements and presence of L. littorea in the field. The PAF calculated on the basis of TBT levels for open coastal waters ranged from 4.2% to 15.3%; for harbours it ranged from 3.5% to 26.9%. Significant intersex levels were observed only in waters where the risk was calculated above 10% PAF. This study suggests that the absence of L. littorea from some harbours with high ecological risk values can be explained by high TBT concentrations. A call is made for the use of integrated approaches like weight-of-evidence (WOE) to help practitioners improve ecological risk assessment.     

Pyroxenites from the Southwest Indian Ridge, 9-16{degrees}E: Cumulates from Incremental Melt Fractions Produced at the Top of a Cold Melting Regime

The Southwest Indian Ridge (SWIR) at 9–16°E and 52–53°Sis characterized by ultra-slow, oblique spreading and containsone of the few documented occurrences of pyroxenite veins associatedwith abyssal peridotites. The origin of these uncommon lithologiesis still debated. We present a detailed study (including electronmicroprobe and laser ablation inductively coupled plasma massspectrometry) of spinel websterites collected during Cruise162, Leg 9, of the R.V. Knorr. Rare earth element patterns inclinopyroxenes (Cpx) lead us to discard a possible origin ofthe pyroxenites as residues from partial melting of garnet pyroxenites(i.e. relics of a layered mantle protolith). Their compositionand cumulate texture (when not obscured by mylonitization relatedto emplacement on the seafloor) are better interpreted in termsof fractional crystallization from a basaltic melt at relativelyhigh pressure. Evidence for a high pressure of crystallizationincludes the lack of plagioclase in the cumulate assemblageand the high Al₂O₃ contents of the pyroxenes: up to 5 wt % inorthopyroxene (Opx) and up to 7 wt % in Cpx. These values areamong the highest reported for pyroxenes in a mid-ocean ridgesetting. Sub-solidus breakdown of spinel to plagioclase (nowaltered) is observed in one sample, providing a rough estimateof the final equilibration pressure of these cumulates, around0· 6–0· 7 GPa (plagioclase–spineltransition for a bulk pyroxenite composition). The inferredpyroxenite parent melts were close to equilibrium with the associatedresidual peridotites; some samples have a slightly evolved compositionin terms of the Mg-number [Mg/(Mg + total Fe)]. These parentalmelts had major and trace element compositions consistent witha mid-ocean ridge basalt (MORB) affinity, although they werenot rigorously identical to MORB. Among other characteristics,these melts were relatively depleted in highly incompatibleelements. We propose that they correspond to the latest, shallowest,incremental melt fractions produced during fractional decompressionmelting of a normal MORB (N-MORB) mantle source. These meltsexperienced fractional crystallization as soon as they segregatedfrom the peridotite matrix, moved upward, and crossed the lithosphere–asthenosphereboundary (defined here as the base of the conductive lid). Asa consequence, these shallow melt fractions produced beneathmid-ocean ridges did not fully mix with melt fractions producedand extracted at greater depths. Our study provides concreteevidence for the actuality of pyroxene crystallization in meltchannels beneath mid-ocean ridges at relatively high pressures,a process frequently invoked to account for the ‘pyroxeneparadox’ in MORB petrogenesis. KEY WORDS: abyssal pyroxenites; cumulates; lithospheric mantle; melt migration; Southwest Indian Ridge