Levels of Organohalogenated Pollutants in Human Milk Samples from Konya City,Turkey

This study reports the levels of organochlorine pesticides (OCPs, α‐, β‐, γ‐ and Δ‐HCHs, p,p′‐DDE, p,p′‐DDD and p,p′‐DDT), polychlorinated biphenyls (PCBs, PCB 28, 52, 101, 153, 138 and 180 congeners) and polybrominated diphenyl ethers (PBDEs, PBDE 47, 99, 100, 153 and 154 congeners) in 45 individual human milk samples collected from Konya City, Turkey. Average concentrations of ΣHCHs, ΣDDTs, ΣPCBs and ΣPBDEs were 22.62, 37.10, 104.95 and 67.34 ng/g lipid wt., respectively. No significant differences in investigated pollutants were found between primiparous and multiparous mothers. There was no correlation between levels of each group of pollutants in human milk and the age of mothers. Moreover, there was no significant difference in the levels of ΣDDTs, between mothers who have eaten fish more than once a week and those who consumed fish less than once. An analysis of the infant exposure to DDTs, HCHs and PCBs via mother's milk indicated that the estimated daily intakes of these pollutants were below the guideline proposed by the World Health Organization (WHO) and the Health Canada which means that there is definitely no concern on children health.     

A new method for aquifer system identification and parameter estimation

The standard practice for assessing aquifer parameters is to match groundwater drawdown data obtained during pumping tests against theoretical well function curves specific to the aquifer system being tested. The shape of the curve derived from the logarithmic time derivative of the drawdown data is also very frequently used as a diagnostic tool to identify the aquifer system in which the pumping test is being conducted. The present study investigates the incremental area method (IAM) to serve as an alternative diagnostic tool for the aquifer system identification as well as a supplement to the aquifer parameter estimation procedure. The IAM based diagnostic curves for ideal confined, leaky, bounded and unconfined aquifers have been derived as part of this study, and individual features of the plots have been identified. These features were noted to be unique to each aquifer setting, which could be used for rapid evaluation of the aquifer system. The effectiveness of the IAM methodology was investigated by analyzing field data for various aquifer settings including leaky, unconfined, bounded and heterogeneous conditions. The results showed that the proposed approach is a viable method for use as a diagnostic tool to identify the aquifer system characteristics as well as to support the estimation of the hydraulic parameters obtained from standard curve matching procedures. Copyright © 2012 John Wiley & Sons, Ltd.     

Sensitivity Study of Hydrodynamic Parameters During Numerical Simulations of Tsunami Inundation

This paper describes the analysis of a parameter, “hydrodynamic demand,” which can be used to represent the potential for tsunami drag force related damage to structures along coastlines. It is derived from the ratio of drag force to hydrostatic force caused by a tsunami on the structure. It varies according to the instantaneous values of the current velocities and flow depths during a tsunami inundation. To examine the effects of a tsunami in the present study, the analyses were performed using the tsunami numerical model in two altered regular-shaped basins having different bottom slopes. The simulations were implemented using a single sinusoidal wave with particular initial conditions, such as leading elevation wave and leading depression wave profiles with different wave periods. Two different initial wave amplitudes were employed to assess the diversity in the distribution of the square of the Froude number Fr ² along the coastline. The numerical results were compared quantitatively.     

Chromatographic Separation and Analytic Procedure for Priority Organic Pollutants in Urban Air

A separation procedure was developed for analysis of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in urban air, while simultaneously eliminating the interfering compounds. This was carried out by optimization of a column chromatograph with regard to the eluent type (n‐hexane and n‐pentane), volume of eluent, type of sorbent material (silica gel and florisil) and activation level of the sorbent material. The determination of the level of PCBs and PAHs was carried out using gas chromatography (GC) equipped with a mass selective detector (MSD), while determination of the OCPs was carried out by GC equipped with an electron capture detector (μ‐ECD). The use of a silica gel column (10 g, 5% deactivated with H₂O) with 70 mL of n‐hexane gave satisfactory separation of PCBs from PAHs and OCPs. After collecting the PCBs with 70 mL of n‐hexane, 3·20 mL of n‐hexane:ethyl acetate, (1:1, v:v) was adequate for elution of the PAHs and OCPs from the column. The primary aim of this study was to develop a multimethod for analyses of PCBs, PAHs, and OCPs in urban air as well as reducing solvent and sorbent consumption and analysis time during the clean‐up procedure compared to the US EPA standard methods (EPA methods TO‐13A for PAHs and TO‐4A for both PCBs and OCPs).     

Two-dimensional joint inversion of radiomagnetotelluric and direct current resistivity data

An algorithm for the two-dimensional (2D) joint inversion of radiomagnetotelluric and direct current resistivity data was developed. This algorithm can be used for the 2D inversion of apparent resistivity data sets collected by multi-electrode direct current resistivity systems for various classical electrode arrays (Wenner, Schlumberger, dipole-diplole, pole-dipole) and radiomagnetotelluric measurements jointly. We use a finite difference technique to solve the Helmoltz and Poisson equations for radiomagnetotelluric and direct current resistivity methods respectively. A regularized inversion with a smoothness constrained stabilizer was employed to invert both data sets. The radiomagnetotelluric method is not particularly sensitive when attempting to resolve near-surface resistivity blocks because it uses a limited range of frequencies. On the other hand, the direct current resistivity method can resolve these near-surface blocks with relatively greater accuracy. Initially, individual and joint inversions of synthetic radiomagnetotelluric and direct current resistivity data were compared and we demonstrated that the joint inversion result based on this synthetic data simulates the real model more accurately than the inversion results of each individual method. The developed 2D joint inversion algorithm was also applied on a field data set observed across an active fault located close to the city of Kerpen in Germany. The location and depth of this fault were successfully determined by the 2D joint inversion of the radiomagnetotelluric and direct current resistivity data. This inversion result from the field data further validated the synthetic data inversion results.     

Assessment of advective–dispersive contaminant transport in heterogeneous aquifers using a meshless method

Groundwater solute transport phenomena typically occur in water-bearing zones with heterogeneous solute dispersive characteristics and/or media hydraulic properties. A radial basis function collocation method (RBFCM)-based numerical method was developed in order to investigate the ability of RBFCM to accurately portray solute transport phenomena under heterogeneous conditions. Simulations were performed for 1-D and 2-D transport scenarios in which scale-dependent dispersivity fields were taken into consideration and compared with available analytical solutions. Different radial basis functions (RBFs) were employed for assessing the sensitivity of the present method on the selected RBFs. The simulation results were also compared with the results of MT3DMS which is a modular three-dimensional transport model with alternative solution schemes including the method of characteristics, the implicit central finite difference and the third order total variation diminishing finite volume. The proposed model was also used to simulate a real case condition where solute transport through a two-layer soil medium had been investigated experimentally. The results showed that RBFCM represented a powerful tool for predicting the solute transport occurrence under heterogeneous conditions with high accuracy.     

Character of active faulting in the North Aegean Sea

A re-evaluation of the reprocessed seismic reflection data was made for the investigation of the presumed western continuation of the North Anatolian Fault (NAF) in the Aegean and mapping geometries of active faults in the Aegean Sea. Seismic data collected and processed by various national and international companies were selected from the data archives and they were reprocessed after stacking to bring them to the same processing and signal-to-noise ratio standards. The total length of the selected lines is 8000 km. We investigated the character of active faulting in the North Aegean Sea using seismic reflection data. Moreover, the relations of active faults with earthquakes were examined using earthquake fault plane solutions (FPS). We show that the active faults are dominantly normal in character in the NNE Aegean where FPS for earthquakes with M>5 indicate strike-slip movements along these faults. We propose a simple mechanism that potentially explains this inconsistency. Active normal faults are oriented in a NE–SW direction in alignment with the SW escape motion of the Anatolian block in this region and this orientation facilitates instantaneously strike-slip movements along these otherwise normal faults.     

Responses of the stratified flows to their driving conditions—A field study

The Bosphorus is oceanographically very complicated two-layer stratified strait where denser water from the Marmara Sea flows towards North under the lighter water which is frequently flowing from the Black Sea towards South. The water level difference between both ends of the Bosphorus varies seasonally within the range of ?0.2 and 0.6 m. The seasonal variability depends mainly on the water level changes in the adjacent basins related to the hydrological cycle, short-term changes in the atmospheric pressure and the wind characteristics. These variations together with the depth and alignment of the cross section along the strait dominate the spatial and temporal variations and sometimes sharp changes in the flow pattern in three dimensions. Although these hydrodynamic conditions are critical for all marine and hydraulic works along the Bosphorus, there was not continuous long-term measurement for a sufficient time span in the strait for detailed evaluation of the current climate. An extensive site surveying work including current, wind, pressure and water level measurements was carried out between September 2004 and January 2006 in relation to the design and construction requirements of the Bosphorus Tube Crossing Project. In this study, the characteristics of stratified flow in the Bosphorus Strait and their relation to local and regional, short- and long-term changes in the meteorological parameters are studied by using the measurement data and the results are discussed comparatively.     

Direct interpretation of magnetotelluric sounding data based on the frequency-normalized impedance function

An important aspect of any non-linear inversion method is the generation of a suitable or good initial model as this controls the rate of convergence and accuracy of the result. To overcome the problem, a numerical method is presented for direct interpretation of magnetotelluric sounding data based on the frequency-normalized impedance (FNI) function. The expressions used to calculate the parameters are developed, first for a two-layer case under the assumption that deeper layers do not contribute to the early part of the FNI curve, and they are then generalized for an n -layer situation. The parameters of the first layer are computed by using successive sample values and the final estimate is obtained from the arithmetic mean of selected values by excluding unacceptable results in the logarithmic space. The top layer is then removed using a reduction equation. The repetition of the procedure on successive branches of the FNI function gives successive layer parameters, the resistivity of the substratum being obtained at the final step, when the reduction equation becomes equal to the square root of that resistivity.   The proposed method can be used as a complementary method for iterative inversion as it creates an initial guess which is close to the optimal solution. The solution produced by the direct interpretation may also be modified by the interpreter to incorporate prior geological information before being input to iterative interpretation schemes.