Degradation of Malathion and Parathion by Ozonation,Photolytic Ozonation,and Heterogeneous Catalytic Ozonation Processes

The oxidation of organophosphorus pesticides (OPPs), such as malathion and parathion, in aqueous solution was studied using conventional ozonation (O₃), photolytic ozonation (O₃/UV, O₃/UV/H₂O₂), and heterogeneous catalytic ozonation (O₃/TiO₂/UV) processes. Experiments were performed in batch mode at laboratory scale and processes were compared in terms of disappearance kinetics. The best results of pesticide mineralization were obtained when TiO₂ particles in combination with ozone (O₃) and UV photolysis (λ = 254 nm) were applied. Decomposition of 99% of parent compounds were achieved in 10 min and oxon derivatives were completely removed in 30 min. The initial reaction rate increases linearly with increasing catalyst amount. Toxicity measurements of the treated solutions were carried out in order to evaluate the efficiency of the treatment methods. No detoxification was achieved for O₃ and O₃/UV applications. Heterogeneous photocatalytic ozonation was shown to be feasible for achieving complete decomposition of OPPs and their oxon intermediates.     

Investigation of the nature of slip surface using geochemical analyses and 2-D electrical resistivity tomography: a case study from Lapseki area, NW Turkey

The nature and subsurface structure of the slip surface of a landslide was studied on the basis of geochemical analyses and 2-D electrical resistivity tomography (ERT) survey. Head scarp and lateral slip surfaces of the landslide marked by clear slickensided shear planes were composed of the average amounts of clayey silt (32.5%) and sand (67.5%). Energy dispersive X-ray spectroscopy (EDX) data revealed the enrichment of Si (23.24%), Fe (12.2%), Al (9.51%) and C (8.34%) in the elemental composition of the disturbed slip surface. From X-ray diffractometry (XRD) data, six main clay types were determined, such as Volkonskoite, Halloysite, Ferrosilite, Saponite, Illite and Nontronite. The ERT survey displayed that the landslide developed as a reactivation on the upper part of an old landslide body.     

Measurement and evaluation of the hydrodynamics and secondary currents in and near a strait connecting large water bodies—A field study

The straits connect two large water bodies show highly strong and stratified currents related to meteorological, morphological and hydrodynamic conditions. In some cases, spatial and temporal changes of the stratified currents and their thickness, direction and magnitude are so complex. This complexity directly affects the circulation pattern in the region, water exchange between both ends of the straits and migration of fish species. In order to understand general characteristics of this kind of straits and identifying the complexity of the hydrodynamics of the region and evaluate the secondary currents and recirculation need long term, intensive, field work and measurement studies. As an example of this kind of hydrodynamically complex straits, Bosphorus strait is selected for a field study. The Bosphorus strait has a strongly stratified two-layer system and a unique case of the maximal exchange regime typical of strait flows, which is largely determined by conditions at the Black Sea. Although the Bosphorus strait has distinct two-layer stratification with an associated two-layer system exchange, no continuous current measurements have been made so far, previous measurements all having been random sampling.In this paper, a detailed measurement program has been applied to Bosphorus strait. In the measurement program, a short-term current profile measurement at selected locations at southern part of the strait has been conveyed. Additionally a long-term measurement of current profile has been performed at a selected critical location (in front of the Dolmabahçe Palace) where a recirculation flow exists in the strait. The scope of this paper is to present the techniques and the results of analysis of measurement data. In the measurements the current profile (magnitude and direction) has been determined at every 1 m depth intervals from the surface to the sea bottom at 3 min duration at every hour. Measurements provide that lower-layer flows in northward direction from the Sea of Marmara towards the Black Sea, whereas the upper-layer flow comes from the Black Sea and flows towards the Sea of Marmara in the opposite direction of lower layer. The Bosphorus strait exhibits distinctive features associated with variations in its width and depth. The meandering features of Bosphorus also cause recirculation flows. These results of measurements are presented, discussed and compared with previous studies.     

Constructing a 3D structural block diagram of the Central Basin in Marmara Sea by means of bathymetric and seismic data

In this study we made a comparative interpretation of multibeam bathymetric and seismic reflection data with different resolutions and penetration properties collected in the Central Basin of the Marmara Sea. Our main objectives were (i) to investigate and compare the active tectonic deformation observed on the sea bottom and within the uppermost sedimentary layers to that of the deep-seated deformation within the limits of resolution and penetration of the available geophysical data and (ii) to build a three-dimensional (3D) block diagram of the active tectonic and buried features by means of a sliced mapping technique. In this approach, we produced slice maps of the active and buried structural features at selected depths and then combined them to form a 3D structural block diagram. Motivation for our work was to produce a 3D structural diagram to derive a more detailed image of the structural features in the Central Basin where there is no available 3D seismic data. The observations from the bathymetry and seismic data and developed 3D diagram support the presence of a through-going strike-slip fault that forms a rotational depression zone against a right-stepping strike-slip faulting causing a pull-apart basin in the Central Depression zone.     

River suspended sediment modelling using a fuzzy logic approach

Correct estimation of sediment volume carried by a river is very important for many water resources projects. Conventional sediment rating curves, however, are not able to provide sufficiently accurate results. In this paper, a fuzzy logic approach is proposed to estimate suspended sediment concentration from streamflow. This study provides forecasting benchmarks for sediment concentration prediction in the form of a numerical and graphical comparison between fuzzy and rating‐curve models. Benchmarking was based on a 5‐year period of continuous streamflow and sediment concentration data of Quebrada Blanca Station operated by the United States Geological Survey. The benchmark results showed that the fuzzy model was able to produce much better results than rating‐curve models. The fuzzy model proposed in the study is site specific and does not simulate the hysteresis effects. Copyright © 2006 John Wiley & Sons, Ltd.     

Interpretation of gravity anomalies to delineate some structural features of Biga and Gelibolu peninsulas,and their surroundings (north-west Turkey)

On the basis of gravity data, derived anomaly traces were presented for the interpretation of some shallow structural features of Biga and Gelibolu peninsulas. Since building general understanding of subtle details about subsurface geology is of great importance considering that the study area is tectonically important, some advanced data processing techniques were implemented to gravity anomalies in a detailed manner. The procedures were performed using a MATLAB-based software package (Gravity and Magnetic Interpretation – GMINTERP). First, a finite element method was utilised to produce the residual data-set which is expected to reflect short wavelength anomalies arising from shallower geological structures, and thereafter some derivative-based algorithms were executed to analyse the residual data. The general anomaly patterns obtained from the applications clearly corresponded to the well-known surface geology map of the study area. Derivative-based anomaly maps put forward some findings about the existence of an old caldera structure in the western part of the Biga Peninsula. Additionally, abrupt lateral changes in anomaly amplitudes indicated the presence of some major structural discontinuities. Thus, findings yielded to make significant geological interpretations that might be important for further investigations. This study also showed that GMINTERP software package proved useful in assisting geological interpretation using geophysical potential field data-sets.     

Sedimentary evolution of Lake Van (Eastern Turkey) reconstructed from high-resolution seismic investigations

This paper presents results of a multi-channel seismic reflection survey at Lake Van and provides constraints on the sedimentary evolution of the lake. The geophysical data of the lake confirm the existence of three physiographic provinces: a shelf, a slope, and a deep, relatively flat basin. The most prominent features identified on the shelf and slope are clinoforms, submerged channels, as well as closely spaced lake floor depressions, reflecting a highly variable lake-level history. The morphological depressions are interpreted as resulting from subaquatic erosion by channelized, sediment-laden currents into horizontally bedded fan sediments. Submerged channels on the eastern shelf are interpreted as meandering-slope channels, probably as a consequence of a lake-level fall that exposed the shelf area. Clinoforms on the Eastern fan may represent relict deltas formed during stationary or slightly rising lake-level intervals. Merging subsurface imaging interpretation with morphological studies of exposed sediments reveals lake-level fluctuations of several hundreds of meters during the past ca. ~550 ka. The lake has three prominent basins (Tatvan, Deveboynu, and the Northern basin) separated by basement ridges (e.g., the Northern ridge). The seismic units in the Tatvan and Northern basins are dominated by alternations of well-stratified and chaotic reflections, while the Deveboynu basin subsurface consists mainly of chaotic units. The chaotic seismic facies are interpreted as mass-flow deposits, probably triggered by earthquakes and/or rapid lake-level fluctuations. The moderate-to-high-amplitude, well-stratified facies seen in the deeper parts of the basins are interpreted as lacustrine deposits intercalated with tephra layers. The occurrence of a clinoform in the deepest part of the lake suggests a major flooding stage of Lake Van more than ~400 ka ago. Seismic profiles from the deepest part of the lake basin show remarkably uniform and continuous stratigraphic units without any major erosional feature following the flooding event, indicating that the lake was never completely dry afterward and therefore significantly older than previously suggested.