实散组合桩承载原理及应用

本文提出了实散组合桩概念,即一根桩由上下两段组成,上段是实体桩,下段是散体桩。这样就克服了散体桩通常桩头承载能力低的缺陷。本文对实散组合桩的受力概念进行了分析研究,给出了其承载力、沉降、临界桩长等计算方法和公式。最后介绍了首次工程实例。     

江西大吉山五里亭花岗岩单颗粒锆石U-Pb同位素年龄及其地质意义探讨

江西大吉山五里亭花岗岩一直被认为是与大吉山钨矿有关的早阶段花岗岩体 ,时代为燕山早期。但实际上大吉山地区各阶段花岗岩体之间的时空关系并不清楚 ,前人的某些年龄数据也存在相互矛盾之处。本文利用单颗粒锆石 U - Pb化学法 ,对五里亭花岗岩进行了年代学研究 ,获得 2 38.4± 1Ma的岩体侵位年龄 ,这个年龄属印支期。本文还结合某些岩石学、地球化学特征研究及与相邻岩体的对比 ,认为五里亭花岗岩确应归属于印支期 ,因此 ,五里亭岩体与大吉山钨矿没有成因上的直接联系。五里亭花岗岩侵位年龄的厘定和该地区更多印支期花岗岩的不断发现 ,表明印支运动在华南的影响超出了人们以往的认识。在此基础上 ,本文还对华南印支运动和印支期花岗岩的问题进行了简单的讨论     

Laihunite—A new iron silicate mineral

Laihuite reported in the present paper is a new iron silicate mineral found in China with the following characteristics:

1. This mineral occurs in a metamorphic iron deposit, associated with fayalite, hypersthene, quartz, magnetitc, etc.
2. The mineral is opaque, black in colour, thickly tabular in shape with luster metallic to sub-metallic, two perfect cleavages and specific gravity of 3.92.
3. Its main chemical components are Fe and Si with Fe³⁺>Fe²⁺. The analysis gave the formula of Fe Fe _1.00 ³⁺ ·Fe _0.58 ²⁺ ·Mg _0.03 ²⁺ ·Si_0.96O₄.
4. Its DTA curve shows an exothermic peak at 713°C.
5. The mineral has its own infrared spectrum distinctive from that of other minerals.
6. This mineral is of orthorhombic system; space group:C _2h ^/5 ?P2₁/c; unit cell:α=5.813ű0.005,b=4.812ű0.005,c=10.211ű0.005,β=90.87°.
7. The Mössbauer spectrum of this mineral is given, too.

     

铅在高岭石表面的解吸动力学

经过酸性条件下（pH=3.1)Pb(Ⅱ）高岭石表面解吸动力学的研究，发现解吸反应与吸附反应动力学相似，也是一个二阶段的过程，即初始的快速解吸之后伴随着一个缓慢的释放过程。在快速解吸阶段，7min内解吸量即已达到41％。吸附铅没有完全解吸，有近38％残留在高岭石表面，即解吸和吸附过程不是完全可逆的。解吸过程可以用扩展Elovich方程、Elovich方程、双常数方程和一级扩散方程较好地似合。     

The Classification and Model of Coalbed Methane Reservoirs

Coalbed methane has been explored in many basins worldwide for 30 years, and has been developed commercially in some of the basins. Many researchers have described the characteristics of coalbed methane geology and technology systematically. According to these investigations, a coalbed methane reservoir can be defined: "a coal seam that contains some coalbed methane and is isolated from other fluid units is called a coalbed methane reservoir". On the basis of anatomization, analysis, and comparison of the typical coalbed methane reservoirs, coalbed methane reservoirs can be divided into two classes: the hydrodynamic sealing coalbed methane reservoirs and the self-sealing coalbed methane reservoirs. The former can be further divided into two sub-classes: the hydrodynamic capping coalbed methane reservoirs, which can be divided into five types and the hydrodynamic driving coalbed methane reservoirs, which can be divided into three types. The latter can be divided into three types. Currently, hydrodynamic s     

赣南天门山-红桃岭钨锡矿田成岩成矿时代精细测定及其地质意义

素有“世界钨都”美誉的赣南产有密集的与花岗岩类侵入体密切相关的钨锡多金属矿床,然而,目前对钨锡成矿和花岗岩成岩年龄还缺乏很好的约束。本文以天门山-红桃岭钨锡矿田为对象,在详细的矿田地质调查和典型矿床解剖基础之上,采用高精度测年技术开展了成岩成矿年代学研究。利用锆石SHRIMPU-Pb法,分别获得天门山似斑状黑云母二长花岗岩体和红桃岭黑云母花岗岩体成岩年龄分别为151.8±2.9Ma(n=14,MSWD=1.3)和151.4±3.1Ma(n=11,MSWD=0.34);利用辉钼矿Re-Os等时线法,分别获得牛岭内带石英脉型和樟斗外带石英脉型钨矿成矿年龄分别为154.9±4.1~154.6±9.7Ma和149.1±7.1Ma(n=6,MSWD=1.3)。可见,本区钨矿床成矿和与之有密切成因关系的花岗岩成岩年龄限定在晚侏罗世,对应于区域华南中生代第二次大规模成矿作用,钨成矿与花岗岩成岩基本不存在时差。     

Acidities of confined water in interlayer space of clay minerals

The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na⁺ and Mg²⁺). For all models, the interlayer structures are characterized in detail. Na⁺ and Mg²⁺ show significantly different hydration characteristics: Mg²⁺ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na⁺ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg²⁺-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg²⁺ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg²⁺-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities.     

滇东地区煤田构造格局与煤系赋存规律的研究

滇东地区位于特提斯和环太平洋构造体系的交接部位,煤田构造格局的总体特征是呈NNE向条带状展布。区内断层以NNE、NE向为主,受主要断裂影响,煤田在南北向呈带状,东西向呈段状展布,各煤矿区在平面上呈NE向带状分布。研究区煤系赋存受基底主干断裂的控制作用明显,变形强度由北向南逐渐增强,北部地区以褶皱构造为主,断层较少,煤层多保存于向斜构造中,保存较完整,煤层埋藏较深;南部受弥勒-师宗断裂带影响,断裂构造极为发育,对煤层破坏严重,煤系赋存不稳定。     

743离子交换快速分离—等离子体光谱法同时测定十五个稀土元素

本文研制了适用于地质样品中15个稀土元素分析的快速方法。样品经碱熔沉淀分离和743阳离子交换树脂分离富集将稀土元素制备成溶液用等离子体光谱法(ICP-AES)进行测量。方法检出限为0.002-0.3μg/g,当稀土元素含量为0.5-80,μg/g时,方法相对标准偏差为15％-2％。本方法经过多年的样品分析考验以及不断的改进和完善,证明方法简便快速,分析数据稳定可靠,能很好地满足地质样品中15个稀土分量测定的要求。     

Preliminary study of lateral variation in crustal structure of Northeast China from teleseismic receiver functions

We conducted comprehensive receiver function analyses for a large amount of high-quality broadband teleseismic waveforms data recorded at 19 China National Digital Seismic Network (CNDSN) stations deployed in Northeast China.An advanced H-κ domain search method was adopted to accurately estimate the crustal thickness and vP/vS ratio.The crust has an average thickness of about 34.4 km.The thinnest crust occurs in the central region of Northeast China,while the thickest crust is beneath the Yanshan belt.The v...