Uptake and Accumulation of Arsenic in Different Organs of Carrot Irrigated with As‐Rich Water

Irrigation with arsenic (As)‐rich water in agricultural soil may increase high levels of As in crops and cause food chain contamination. In this study, a greenhouse experiment was established using Spanish agricultural soil (Valladolid and Segovia provinces), that are extensively cultivated for carrot plant, to investigate the process of As uptake, bioaccumulation, and translocation of As from root to shoot and leaves in carrot plant. Arsenic concentrations in different organs of carrot plant, rhizosphere soil, and soil solutions were determined by hydride generation atomic absorption spectrometry (AAS). High concentrations of As in irrigation water, and the alkaline and sandy character of this soil enhanced As uptake in carrot plants indicating the potential health risk from consumption of carrots cultivated in these areas. Bioaccumulation of As into the leaves and roots increased with increase of As concentration in irrigation water. Both roots and leaves demonstrated a higher accumulation rate of As at an As concentration of 41 than 131 µg L^?1 in the soil solution. The ratios of As_root/As_leaves showed no statistically significant differences for the different irrigation treatments, and had an average value of 0.36 indicating the high magnitude of As translocation from roots to leaves in carrot plants. The leaves of carrots had a higher affinity for As than roots did. The correlation between As uptake by leaves or roots of carrots and the soluble As in rhizosphere soil did not demonstrate a linear or a plateau curve, indicating a slow but continuous constant As absorption which could be prolonged over time with high potential environmental risks.     

Coupling the terrestrial hydrology model with biogeochemistry to the integrated LAND surface model: Amazon Basin applications

ABSTRACT

We coupled the hydrologic routing and flood dynamics model Terrestrial Hydrology Model with Biogeochemistry (THMB) to the Integrated LAND Surface Model (INLAND) and compared simulations of the discharge and flood extent area against gauge station and satellite-based information in the Amazon Basin. The coupled model represents well the seasonality of the flooding and discharge, but underestimates both of them. This can be related to an already discussed underestimate of the precipitation in the east of the Andes Mountains. A photosynthesis limitation on the flooded area was also included, showing changes in plant productivity and reduction in vegetation carbon stocks. Despite its limitations, the model proves to be a valuable tool for studies of the hydrological cycle and flood dynamics response to climate change projections, allowing it to be used to represent the feedbacks between continental surface water cycle and vegetation.     

Monthly streamflow forecasting using neuro-wavelet techniques and input analysis

ABSTRACT

Combinations of low-frequency components (also known as approximations) resulting from the wavelet decomposition are tested as inputs to an artificial neural network (ANN) in a hybrid approach, and compared to classical ANN models for flow forecasting for 1, 3, 6 and 12 months ahead. In addition, the inputs are rewritten in terms of the flow, revealing what type of information was being provided to the network, in order to understand the effect of the approximations on the forecasting performance. The results show that the hybrid approach improved the accuracy of all tested models, especially for 1, 3 and 6 months ahead. The input analyses show that high-frequency components are more important for shorter forecast horizons, while for longer horizons, they may worsen the model accuracy.     

How do management alternatives of fast-growing forests affect water quantity and quality in southeastern Brazil? Insights from a paired catchment experiment

Fast-growing forest plantations have been expanding in Brazil in the last 50 years, which reach productivities by over 40 m³ ha⁻¹ year⁻¹ in reduced rotation between 5 and 15 years. In the 1990s, environmental warnings about these plantations guided research projects seeking to understand their effects on water and propose forest management actions to minimize them. The assessment of forest management effects on water resources is conducted by long-term experiments in paired catchments. In this paper we present results of some studies conducted at the hydrological monitoring centre of Itatinga Experimental Forest Station, of the University of São Paulo, where hydrological monitoring began in 1987, and currently include three catchments (83–98 ha) under different forest management regimes: short-rotation Eucalyptus plantation, long-term forest plantation mosaic and native forest restoration. Results show that at similar conditions observed at study area including deep soils and good natural water regulation, hydrological effects vary according to the forest management regime adopted, increasing water consumption and making the flow regime vulnerable to intra- and inter-annual seasonality. Regarding water quality, weekly sampling results showed suspended sediments and nitrate concentrations below water quality thresholds criteria by silvicultural operations, and the effects were transient but higher concentrations of nutrients were observed in intensive management regime. In the study area, reducing the management intensity of forest plantation by increasing the rotation time, adopting forest age mosaic and avoiding the coppice technique are alternative choices that reduced water use and increased flow regulation. Different adopted forest management schemes directly affected water use, showing that in water-deficit tropical regions, management regime of fast-growing forest plantations controls water availability.     

Effect of deposit alterations on the dating of herbivorous teeth from Arago cave by the ESR–U-series method

Geochemical alteration processes in archaeological sites may affect the environmental dose rate during the burial history and cause inaccuracy in age determination by palaeodosimetric dating methods, such as luminescence or ESR. In Arago Cave (Tautavel, France), the original composition of the sandy aeolian sediments of palaeoanthropological level G, where the Homo heidelbergensis Arago XXI skull was found, has been modified by both carbonation and phosphatization processes. Eight fossil teeth were collected from different geochemically affected parts of level G and analyzed by the ESR–U-series method. All the teeth are presumably contemporaneous. The results show that the samples from the phosphated area agree within error with those from the carbonated area. Surprisingly, the samples from the non-altered area show ages 100–150 ka younger. This difference is mainly due to the remarkable changes in the gamma dose rate over time. The measured in situ dose rate accounts for more than 50% of the total dose rate for all the samples. We observed that the samples' equivalent dose (D_E) were generally 20% lower in the non-altered area than in the carbonated and phosphated ones. These results show the crucial effect of the geochemical processes affecting the age calculation by ESR–U-series method in comparison with independent chronological data.     

Multi‐objective risk‐informed design of floor isolation systems

The design of floor isolation systems (FISs) for the protection of acceleration sensitive contents is examined considering multiple objectives, all quantified in terms of the probabilistic system performance. The competing objectives considered correspond to (i) maximization of the level of protection offered to the sensitive content (acceleration reduction) and (ii) minimization of the demand for the isolator displacement capacity and, more importantly, for the appropriate clearance to avoid collisions with surrounding objects (floor displacement reduction). Both of these objectives are probabilistically characterized utilizing a versatile, simulation‐based framework for quantifying seismic risk, addressing all important uncertainties related to the seismic hazard and the structural model. FIS performance is assessed through time‐history analysis, allowing for all important sources of nonlinearity to be directly addressed in the design framework. The seismic hazard is described through a stochastic ground motion model. For efficiently performing the multi‐objective optimization, an augmented surrogate modeling methodology is established, considering development of a single metamodel with respect to both the uncertain model parameters and the design variables for the FIS system. This surrogate model is then utilized to simultaneously support the probabilistic risk assessment and the design optimization to provide the Pareto front of dominant designs. Each of these designs establishes a different compromise between the considered risk‐related objectives offering a variety of potential options to the designer. Within the illustrative example, the efficiency of the established framework is exploited to compare three different FIS implementations, whereas the impact of structural uncertainties on the optimal design is also evaluated. Copyright © 2016 John Wiley & Sons, Ltd.     

Microbiological and physicochemical analysis of the coastal waters of southern Brazil

The aim of this study was to assess the impact of sewage discharge on coastal waters by evaluating the influence of physicochemical parameters on the presence of enteric microorganisms in seawater samples collected from 11 beaches in Florianopolis, Santa Catarina, Brazil, over a one-year period (August 2009 to July 2010). Samples were assessed for the presence of human adenoviruses (HAdV), polyomavirus (JCPyV), hepatitis A virus (HAV), and noroviruses (HuNoV GI and GII). Escherichia coli and physicochemical parameters (salinity, temperature, pH and dissolved oxygen) were also evaluated. From the 132 samples analyzed, 55% were positive for HAdV, 51.5% for HAV, 7.5% for HuNoV GI, 4.5% for HuNoV GII, and 3% for JCPyV. E. coli levels ranged from 8 to 1325 CFU/100mL at all sites. The overall results highlight the problem of sewage discharge into coastal waters and confirm that there is no correlation between viral presence and bacterial contamination.     

A simplified storm index method to extrapolate intensity–duration–frequency (IDF) curves for ungauged stations in central Chile

Most of meteorological stations in Chile register rainfall amounts once every 24 h. The creation of intensity–duration–frequency (IDF) curves requires continuous recorded data, and this insufficiency of proper instrumentation has resulted in a lack of IDF curves nationwide. The objective of this study is to further develop and evaluate the feasibility of a new method to estimate IDF curves in ungauged stations under Mediterranean climates of central Chile. A technique used to address this problem is the use of a storm index (S_I), also known as the ‘K’ method, which allows the construction of IDF curves from stations with discontinuous data, by extrapolating data from stations with continuous records, as long as daily rainfall intensities for both stations differ by less than 2 mm h^?1. To test the applicability of this method, S_I values were calculated for 40 meteorological stations located throughout Central Chile (latitudes 30°S to 40°S). The extrapolated IDF curves were then compared with observed data, and the goodness of fit was determined. The results indicate that the storm index method can adequately estimate hourly IDF curve values for stations lacking of continuous rainfall data. Copyright © 2014 John Wiley & Sons, Ltd.     

Evapotranspiration of deforested areas in central and southwestern Amazonia

Considering the high rates of evapotranspiration of Amazonian forests, understanding the impacts of deforestation on water loss rates is important for assessing those impacts on a regional and global scale. This paper quantifies evapotranspiration rates in two different pasture sites in Amazonia and evaluates the differences between the sites. In both places, measured evapotranspiration varies seasonally, decreasing during the dry season. The decrease is higher at the southwestern Amazonia site, while at the central Amazonia site, the decrease is less pronounced. During the dry season, average values of evapotranspiration are around 2.2?±?0.6?mm?day^?1 in central Amazonia and 2.4?±?0.6?mm?day^?1 in southwestern Amazonia, while during the wet season, those values are 2.1?±?0.6?mm?day^?1 in central Amazonia and 3.5?±?0.8?mm?day^?1 in southwestern Amazonia. On an annual basis, the pasture in southwestern Amazonia has higher evapotranspiration than in central Amazonia. We conclude that the main reason for this difference is the lower available energy in the wet season at the central Amazonian site, combined with a lower leaf area index at this site during the whole year. Still, the evapotranspiration is significantly controlled by the vegetation, which is well coupled with the local moisture conditions in the dry season.     

U–Pb ages,geochemistry, C–O–Nd–Sr–Hf isotopes and petrogenesis of the Catalão II carbonatitic complex (Alto Paranaíba Igneous Province,Brazil): implications for regional-scale heterogeneities in the Brazilian carbonatite associations

International Journal of Earth Sciences - The Catalão II carbonatitic complex is part of the Alto Paranaíba Igneous Province (APIP), central Brazil, close to the Catalão I complex....