Upper Limit of Iodine Oxide in the Lower Stratosphere

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.     

Tunicate species as marine pollution indicators

Tunicates may serve as marine pollution indicators for monitoring the release of industrial and/or radioactive wastes into the marine environment. Their ability to accumulate certain trace elements from the seawater can be employed in order to define a suitable organism as indicator for some specific pollutants. In this work the concentration of the elements cobalt, zinc, chromium, caesium, silver, iron, rubidium, selenium, scandium and antimony has been determined by instrumental neutron activation analysis and γ-ray spectroscopy, in two tunicates, Microcosmus sulcatus (Pyuridae) and Ciona intestinalis (Cionidae).According to the concentration factors found for these species Ciona intestinalis can be used as indicator for iron, while Microcosmus sulcatus as indicator for the elements selenium, chromium, zinc and cobalt.     

Microtextural analysis of a glacially ‘deformed’ bedrock: implications for inheritance of preferred clast orientations in diamictons

Although analysis of clast macrofabrics has been used to differentiate between different types of glacial diamictons and to determine palaeo‐ice flow directions, no account appears to have been made of preferred clast orientations inherited from the parental source material. Clast macrofabrics in tills are typically interpreted as having developed in response to an imposed subglacial deformation and as such provide a link between the sedimentary record and glacier dynamics. They rely on the assumption that any preferred clast orientation is a result of deformation/flow. The results of the micromorphological study of the Langholm Till exposed at North Corbelly near Dumfries (southwestern Scotland) clearly demonstrate that bedrock structure can influence clast orientation (macrofabric) within diamictons. In the lower part of the till, the orientation of elongate clasts preserves the geometry of the tectonic cleavage present within the underlying bedrock. The intensity of this steeply inclined, ‘inherited’ clast fabric decreases upward through the till, to be replaced by a more complex pattern of successive generations of clast microfabrics developed in response to deformation/flow. These results indicate potential limitations of applying clast macrofabric or microfabric analysis in isolation to establish till genesis or palaeo ice‐flow directions. Consequently, due account should be made of other glacial palaeo‐environmental and ice flow indicators, as well as rockhead depth and morphology in relation to the selection of fabric measurements sites. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.     

2MASS near-infrared photometry of symbiotic stars

We present Two Micron All Sky Survey photometry for 216 symbiotic and possible symbiotic stars. This represents the most comprehensive near-infrared photometry for these sources which has been published to date. The results are used to define the statistics of S- and D-type stars; to investigate the photometric properties of Magellanic S-type symbiotics; and to define the possible evolution of D-type symbiotics within the J − H / H − K _S colour plane. It appears that the colours of D-type symbiotics are consistent with differing mass-loss rates d M /d t , provided that the grains have a silicate-like composition, and maximum temperatures of the order of ∼800 K.     

Density gradients in Galactic ultra-compact H ii regions

We have used recent radiative transfer solutions for cavity-centred shells to investigate the prevalence of density gradients in Galactic ultra-compact H  ii regions. We find that an analysis of 5 and 1.4 GHz data, taken from the recent compilation of Giveon et al., implies that ∼76 per cent of sources may have appreciable density gradients. It would also seem that the central cavities of these sources must be relatively small, with radii no greater than ∼20 per cent of those of the outer shells. The remainder of these sources are presumably homogenous, have much larger cavities, or possess reverse density gradients (densities which increase with increasing radius). A good fraction of the H  ii regions also appear to have high brightness temperatures, implying mean electron temperatures  〈 T _e〉  of the order of  ≈1.3 × 10⁴ K  . This value is higher than has been determined for other such sources.     

Petrologic insights from the spectra of the unbrecciated eucrites: Implications for Vesta and basaltic asteroids

Abstract– We investigate the relationship between the petrology and visible–near infrared spectra of the unbrecciated eucrites and synthetic pyroxene–plagioclase mixtures to determine how spectra obtained by the Dawn mission could distinguish between several models that have been suggested for the petrogenesis of Vesta’s crust (e.g., partial melting and magma ocean). Here, we study the spectra of petrologically characterized unbrecciated eucrites to establish spectral observables, which can be used to yield mineral abundances and compositions consistent with petrologic observations. No information about plagioclase could be extracted from the eucrite spectra. In contrast, pyroxene dominates the spectra of the eucrites and absorption band modeling provides a good estimate of the relative proportions of low‐ and high‐Ca pyroxene present. Cr is a compatible element in eucrite pyroxene and is enriched in samples from primitive melts. An absorption at 0.6 μm resulting from Cr³⁺ in the pyroxene structure can be used to distinguish these primitive eucrites. The spectral differences present among the eucrites may allow Dawn to distinguish between the two main competing models proposed for the petrogenesis of Vesta (magma ocean and partial melting). These models predict different crustal structures and scales of heterogeneity, which can be observed spectrally. The formation of eucrite Allan Hills (ALH) A81001, which is primitive (Cr‐rich) and relatively unmetamorphosed, is hard to explain in the magma ocean model. It could only have been formed as a quench crust. If the magma ocean model is correct, then ALHA81001‐like material should be abundant on the surface of Vesta and the Vestoids.