A mineral equilibria study of the hydrothermal alteration in mafic greenschist facies rocks at Kalgoorlie, Western Australia

The influx of a H₂O–CO₂‐dominated fluid into actinolite‐bearing metabasic rocks during greenschist facies metamorphism in the Kalgoorlie area of Western Australia resulted in a zoned alteration halo around inferred fluid conduits that contain gold mineralisation. The alteration halo is divided into two outer zones, the chlorite zone and the carbonate zone, and an inner pyrite zone adjacent to the inferred fluid conduits. Reaction between the fluid and the protolith resulted in the breakdown of actinolite and the development of chlorite, dolomite, calcite and siderite. In addition, rocks in the pyrite zone developed muscovite‐bearing assemblages as a consequence of the introduction of potassium by the fluid. Mineral equilibria calculations undertaken using the computer software thermocalc in the model system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ show that mineral assemblages in the outer zones of the alteration halo are consistent with equilibrium of the protoliths with a fluid of composition X_CO2 = CO₂/(CO₂ + H₂O) = 0.1–0.25 for temperatures of 315–320 °C. The inner zone of the alteration halo reflect equilibrium with a fluid of composition X_CO2≈ 0.25. Fluid‐rock buffering calculations show that the alteration halo is consistent with interaction with a single fluid composition and that the zoned structure of the halo reflects the volume of this fluid with which the rocks reacted. This fluid is likely to have also been the one responsible for the gold mineralisation at Kalgoorlie.     

Density gradients in Galactic ultra-compact H ii regions

We have used recent radiative transfer solutions for cavity-centred shells to investigate the prevalence of density gradients in Galactic ultra-compact H  ii regions. We find that an analysis of 5 and 1.4 GHz data, taken from the recent compilation of Giveon et al., implies that ∼76 per cent of sources may have appreciable density gradients. It would also seem that the central cavities of these sources must be relatively small, with radii no greater than ∼20 per cent of those of the outer shells. The remainder of these sources are presumably homogenous, have much larger cavities, or possess reverse density gradients (densities which increase with increasing radius). A good fraction of the H  ii regions also appear to have high brightness temperatures, implying mean electron temperatures  〈 T _e〉  of the order of  ≈1.3 × 10⁴ K  . This value is higher than has been determined for other such sources.     

Winter daily precipitation variability over the South West Peninsula of England

Summary Daily precipitation totals for five consecutive winters (1995–99) were obtained for 127 stations in Devon and Cornwall to explore spatial variations in rainfall. This dataset was assembled with the explicit aim of assessing the appropriateness of current arrangements for daily rainfall forecasts in the SW Peninsula of England. Firstly, the extent to which fundamental geographic variables determine precipitation was investigated by correlating each station’s mean wet day amount (WDA) and percentage of wet days (PERWET) with altitude, latitude, longitude and distance from the coast. Altitude emerged as the most important control on precipitation, with a two-variable multiple linear regression model containing altitude and latitude being able to explain 39.3% (29.8%) of the variance in WDA (PERWET) values. The main spatial modes of variability in the region’s precipitation field were identified by using S mode principal components analysis (PCA). Six PCs were statistically significant and explained 83.4% of the geographic variance in precipitation over Devon and Cornwall. The components were interpreted physically by examining the synoptic flow environment (pressure and wind anomalies) on days with high positive and negative PC scores. Explaining 25.1% of the variance, the most important pattern (PC1) depicts a location’s degree of exposure or shelter in a moist, unstable W–NW airflow. The higher PCs describe modes of variability that accentuate rainfall in East Devon (PC2), Cornwall (PC3), Dartmoor and Bodmin Moor (PC4), South Devon (PC5), and North Cornwall and NW Devon (PC6) relative to other areas of the Peninsula. Finally, a winter precipitation regionalisation was derived by applying agglomerative hierarchical cluster analysis to the PC loadings of the significant components. In most cases, the six coherent precipitation regions do not reflect the familiar administrative or topographic areas used for forecasting, suggesting that forecasts issued on such a basis are likely to be insufficiently detailed and misleading.     

27Al, 29Si,and 23Na MAS NMR study of an Al,Si ordered alkali feldspar solid solution series

Solid-state ²⁷Al, ²⁹Si and ²³Na MAS NMR spectra have been obtained for an Al,Si ordered low albite to low microcline ion exchange series for which unit-cell parameters and ²⁹Si NMR data have previously been reported. ²⁷Al δ_i vary continuously with composition from 63.4 (±0.5) ppm for albite to 58.9 (±0.5) ppm for microcline, and parallel the ²⁹Si chemical shifts assigned to the T2m-site. The ²⁷Al and ²⁹Si chemical shifts for this series correlate well with composition-dependent lattice parameters, most notably cell volume and the angle [201]¹b. The linewidths of the ²⁹Si and ²⁷Al resonances indicate a significant amount of structural disorder in the intermediate compositions due to Na, K substitution. The 1 σ width of the distribution of average Si-O-T angles for each T-site is estimated to be about 1° for the Or33 sample. The average ²³Na δ_i varies monotonically from -8.5 (±1) ppm for albite to -24.3 (±1)ppm for Or83. Similarly, the average ²³Na nuclear quadrupole coupling constant decreases from 2.60 to 1.15 (±0.05) MHz and the asymmetry parameter of the electric field gradient increases from 0.25 to 0.6 with increasing K-content from albite to Or83. The observed variations in the quadrupole coupling parameters are consistent with simple electrostatic calculations. Higher resolution ²³Na spectra of the intermediate compositions obtained at 11.7 T indicate the presence of an inhomogeneous linebroadening which is related to the distribution of Na-environments. A model based on a random distribution of local compositions does not simulate the spectra, suggesting that the distribution of Na is skewed toward Na-rich clusters. Observation of the ²³Na NMR lineshape of Or49 after short periods of heat treatment indicate that ²³Na NMR is very sensitive to the changes in the Na, K distribution accompanying the early stages of exsolution. Reversible changes occur after heating at 530° C for 3 h, whereas heating at 600° C produces no changes, possibly bracketing the position of the coherent spinodal for Al, Si ordered alkali feldspars at this composition.     

Data reporting norms for 40Ar/39Ar geochronology

Data reported in ⁴⁰Ar/³⁹Ar geochronology studies are commonly insufficient to allow computation of ages. This deficiency renders it difficult to compare ages based on different standards or constants, and often hinders critical evaluation of the results. Herein are presented an enumeration of the data that should be reported in all ⁴⁰Ar/³⁹Ar studies, including a discussion in support of these requirements. The minimum required data are identified and distinguished from parameters that are useful but may be derived from them by calculation. Finally, recommendations are made for metadata needed to document age calculations (e.g., from age spectrum or isochron analyses).     

Precise Relative Location of 25-ton Chemical Explosions at Balapan Using IMS Stations

—?We test how well low-magnitude (m _bLg 1.8 to 2.6), 25-ton chemical explosions at Balapan, Kazakhstan, can be located using IMS stations and standard earth models, relying on precisely determined relative arrival times of nearly similar, regional and teleseismic waveforms. Three 1997 Balapan explosions were recorded by a number of currently reporting and surrogate IMS stations. Three regional stations and two teleseismic arrays yielded consistent waveforms appropriate for relative picking. Master-event locations based on the AK135 model and ground-truth information from the first, shallowest and best-recorded explosion, fell under 1 km from known locations, for depths constrained to that of the master event. The resulting 90% confidence ellipses covered 12–13?km² and contained the true locations; however, results for depth constrained to true depth were slightly less satisf actory. From predictions based on ground truth, we found a P _g -coda phase at Makanchi, Kazakhstan to be misidentified and poorly modeled. After accounting for this, 90% ellipses shrank to 2–3?km² and true-depth mislocation vectors became more consistent with confidence-ellipse orientations. These results suggest that a high level of precision could be provided by a tripartite array of calibration shots in cases where models are poorly known. We hope that the successful relocation of these small Balapan shots will support the role of calibration explosions in verification monitoring and special event studies, including on-site inspection.     

HUMAN IMPACTS ON THE ENVIRONMENT: UNPREDICTABILITY AND THE PRIMACY OF PLACE

Landscapes, environments, and ecosystems (i.e., places) are historically and spatially contingent and therefore unique. Generalizations and laws are based on “all other things being equal.” Owing to historical and spatial contingency, all other things are never completely equal and often do not approach that ideal closely enough to allow for reliable prediction. The problem is illustrated by examining effects of grazing and fire suppression on transitions between grass and woody vegetation communities. In three different environments in the southern United States (central Texas, southwestern Virginia, and eastern North Carolina), three different relationships exist between grazing and fire regime, and vegetation. Other examples are common in the geographic and environmental literature. This suggests that the search for a single applicable generalization or predictive model of a given human-induced environmental change that can be applied without accounting for the particular characteristics of places may be futile. Several general ways to address this issue are suggested. First is the recognition that place matters. Conditions specific to a location or region will influence what, how, or even if generalizations apply. Second is the adoption of a “demographic” approach. This is based on the idea that for places, like people, it is possible to make aggregate or probabilistic generalizations or predictions, but these cannot be applied to deterministic prediction of individuals. Third is a synoptic approach based on forecasting not via simple cause-effect relationships, but based on a typology of situations that recognizes and incorporates the unique characteristics of site and situation. Several converging threads of inquiry in geography and geosciences explicitly or implicitly address the issue of historical and spatial contingency. [Key words: landscape, environment, place, prediction.]