Estimation of streambed groundwater fluxes associated with coaster brook trout spawning habitat

We hypothesized that the spatial distribution of groundwater inflows through river bottom sediments is a critical factor associated with the distribution of coaster brook trout (a life history variant of Salvelinus fontinalis) spawning redds. An 80-m reach of the Salmon Trout River, in the Huron Mountains of the upper peninsula of Michigan, was selected to test the hypothesis based on long-term documentation of coaster brook trout spawning at this site. A monitoring well system consisting of 22 wells was installed in the riverbed to measure surface and subsurface temperatures over a 13-month period. The array of monitoring wells was positioned to span areas where spawning has and has not been observed. Over 200,000 total temperature measurements were collected from five depths within each monitoring well. Temperatures in the substrate beneath the spawning area were generally less variable than river temperatures, whereas temperatures under the nonspawning area were generally more variable and closely tracked temporal variations in river temperatures. Temperature data were inverted to obtain subsurface groundwater velocities using a numerical approximation of the heat transfer equation. Approximately 45,000 estimates of groundwater velocities were obtained. Estimated groundwater velocities in the spawning area were primarily in the upward direction and were generally greater in magnitude than velocities in the nonspawning area. Both the temperature and velocity results confirm the hypothesis that spawning sites correspond to areas of significant groundwater flux into the river bed.     

Recovery and curation of the Winchcombe (CM2) meteorite

The Winchcombe meteorite fell on February 28, 2021 and was the first recovered meteorite fall in the UK for 30 years, and the first UK carbonaceous chondrite. The meteorite was widely observed by meteor camera networks, doorbell cameras, and eyewitnesses, and 213.5 g (around 35% of the final recovered mass) was collected quickly—within 12 h—of its fall. It, therefore, represents an opportunity to study very pristine extra-terrestrial material and requires appropriate careful curation. The meteorite fell in a narrow (600 m across) strewn field ~8.5 km long and oriented approximately east–west, with the largest single fragment at the farthest (east) end in the town of Winchcombe, Gloucestershire. Of the total known mass of 602 g, around 525 g is curated at the Natural History Museum, London. A sample analysis plan was devised within a month of the fall to enable scientists in the UK and beyond to quickly access and analyze fresh material. The sample is stored long term in a nitrogen atmosphere glove box. Preliminary macroscopic and electron microscopic examinations show it to be a CM2 chondrite, and despite an early search, no fragile minerals, such as halite, sulfur, etc., were observed.     

Impact of beaver dam analogues on hydrology in a semi-arid floodplain

Natural beaver ponds help connect the stream to the floodplain, maintain late summer low flows and reduce peak flow during high flow events by offering temporary surface water (SW) storage. When beavers are extirpated from the landscape, stream degradation often ensues. This study assesses the impact of beaver dam analogues (BDA) as a stream restoration technique to help maintain low flow water levels and enhance stream-floodplain interactions on a seasonal basis in Red Canyon Creek, Lander, WY. BDAs increased SW and groundwater (GW) levels, favoured the occurrence of flow reversals (i.e., stream-to-floodplain GW flow) during high flow events associated with mid-winter and early-spring thaw events, and reduced the groundwater-to-stream hydraulic gradient on an annual basis. Although GW temperatures varied seasonally, relatively cooler GW temperatures were observed in the BDA impacted reach compared to the control reach away from BDA influence. BDAs however did not significantly impact stream temperatures. Overall, results suggest that when installed in sequence, BDA complexes can successfully reconnect the stream to its floodplain, and ultimately increase SW-GW exchange at the floodplain scale by allowing flow reversals to occur and by reducing the GW to stream hydraulic gradient. Although BDAs built with fence posts, willow branches, sediments and small boulders are naturally porous and require regular maintenance, this study also highlights the viability of small BDAs as a restoration practice to enhance landscape resilience to drought and high flow events in deeply incised channels where beavers would not come back naturally.     

Kelvin and Faraday kimberlite emplacement geometries and implications for subterranean magmatic processes

The Kennady North Project kimberlites (Northwest Territories of Canada) comprises multiple shallow dipping dykes and several volcaniclastic bodies that have an unusual shallow plunging geometry and complex “pipe” shapes that are termed chonoliths. The detailed exploration of the entire system provides exceptional evidence for subterranean volcanic conduit growth processes. The possible processes leading to the development of the kimberlite bodies are discussed, with emphasis on the importance of the subsurface intrusive system geometry and the local stress tensor. Emplacement into a locally compressive stress regime (i.e. σ₁ and σ₂ inclined at a low angle to surface) could change the kimberlite emplacement geometries to that observed at Kennady North. Models are proposed for the development of the chonoliths, to emphasize aspects of the growth of kimberlite systems that are not well understood. The conclusions challenge or evolve current emplacement models and should influence kimberlite exploration and resource definition assumptions.

     

Development of an electrically-driven automatic downhole seismic source

To improve upon the downhole testing program, an automatic seismic source was developed for use in seismic piezocone testing. A new source, named the AutoSeis, was initially tested at the national geotechnical experimentation site in Spring Villa, Alabama and compared to available crosshole data to assess its ability to meet the primary and secondary goals. Later testing was conducted at two test sites in the Mid-America earthquake region near Memphis. With reliable shear waves generated to a depth of 20 m, the first iteration of the AutoSeis has proven successful and has provided the necessary information for the design of an improved version.     

Superhumps in the helium dwarf nova KL Draconis

We report on the discovery of a 25.5-min superhump period for the suspected helium dwarf nova system KL Draconis in a high state. The presence of superhumps combined with the previously observed helium spectrum and large-amplitude photometric variations confirm that KL Dra is an AM CVn system similar to CR Bootis, V803 Cen and CP Eridani. We also find a low-state photometric period at 25.0 min that we suggest may be the orbital period. With this assumption, we estimate   q =0.075  ,   M ₁=0.76 M_⊙  and   M ₂=0.057 M_⊙  .     

Elucidating microbial processes in nitrate- and sulfate-reducing systems using sulfur and oxygen isotope ratios: The example of oil reservoir souring control

Sulfate-reducing bacteria (SRB) are ubiquitous in anoxic environments where they couple the oxidation of organic compounds to the production of hydrogen sulfide. This can be problematic for various industries including oil production where reservoir “souring” (the generation of H₂S) requires corrective actions. Nitrate or nitrite injection into sour oil fields can promote SRB control by stimulating organotrophic nitrate- or nitrite-reducing bacteria (O-NRB) that out-compete SRB for electron donors (biocompetitive exclusion), and/or by lithotrophic nitrate- or nitrite-reducing sulfide oxidizing bacteria (NR-SOB) that remove H₂S directly. Sulfur and oxygen isotope ratios of sulfide and sulfate were monitored in batch cultures and sulfidic bioreactors to evaluate mitigation of SRB activities by nitrate or nitrite injection. Sulfate reduction in batch cultures of Desulfovibrio sp. strain Lac15 indicated typical Rayleigh-type fractionation of sulfur isotopes during bacterial sulfate reduction (BSR) with lactate, whereas oxygen isotope ratios in unreacted sulfate remained constant. Sulfur isotope fractionation in batch cultures of the NR-SOB Thiomicrospira sp. strain CVO was minimal during the oxidation of sulfide to sulfate, which had δ¹⁸O_SO4 values similar to that of the water-oxygen. Treating an up-flow bioreactor with increasing doses of nitrate to eliminate sulfide resulted in changes in sulfur isotope ratios of sulfate and sulfide but very little variation in oxygen isotope ratios of sulfate. These observations were similar to results obtained from SRB-only, but different from those of NR-SOB-only pure culture control experiments. This suggests that biocompetitive exclusion of SRB took place in the nitrate-injected bioreactor. In two replicate bioreactors treated with nitrite, less pronounced sulfur isotope fractionation and a slight decrease in δ¹⁸O_SO4 were observed. This indicated that NR-SOB played a minor role during dosing with low nitrite and that biocompetitive exclusion was the major process. The results demonstrate that stable isotope data can contribute unique information for understanding complex microbial processes in nitrate- and sulfate-reducing systems, and offer important information for the management of H₂S problems in oil reservoirs and elsewhere.     

The kinetics of oxygen exchange between the GeO4Al12(OH)24(OH2)12(aq) molecule and aqueous solutions

We report rates of oxygen exchange with bulk solution for an aqueous complex, ^IVGeO₄Al₁₂(OH)₂₄(OH₂)₁₂⁸⁺(aq) (GeAl₁₂), that is similar in structure to both the ^IVAlO₄Al₁₂(OH)₂₄(OH₂)₁₂⁷⁺(aq) (Al₁₃) and ^IVGaO₄Al₁₂(OH)₂₄(OH₂)₁₂⁷⁺(aq) (GaAl₁₂) molecules studied previously. All of these molecules have ε-Keggin-like structures, but in the GeAl₁₂ molecule, occupancy of the central tetrahedral metal site by Ge(IV) results in a molecular charge of +8, rather than +7, as in the Al₁₃ and GaAl₁₂. Rates of exchange between oxygen sites in this molecule and bulk solution were measured over a temperature range of 274.5 to 289.5 K and 2.95 < pH < 4.58 using ¹⁷O-NMR.Apparent rate parameters for exchange of the bound water molecules (η-OH₂) are k_ex²⁹⁸ = 200 (±100) s⁻¹, ΔH^‡ = 46 (±8) kJ · mol⁻¹, and ΔS^‡ = −46 (±24) J · mol⁻¹ K⁻¹ and are similar to those we measured previously for the GaAl₁₂ and Al₁₃ complexes. In contrast to the Al₁₃ and GaAl₁₂ molecules, we observe a small but significant pH dependence on rates of solvolysis that is not yet fully constrained and that indicates a contribution from the partly deprotonated GeAl₁₂ species.The two topologically distinct μ₂-OH sites in the GeAl₁₂ molecule exchange at greatly differing rates. The more labile set of μ₂-OH sites in the GeAl₁₂ molecule exchange at a rate that is faster than can be measured by the ¹⁷O-NMR isotopic-equilibration technique. The second set of μ₂-OH sites have rate parameters of k_ex²⁹⁸ = 6.6 (±0.2) · 10⁻⁴ s⁻¹, ΔH^‡ = 82 (±2) kJ · mol⁻¹, and ΔS^‡ = −29 (±7) J · mol⁻¹ · K⁻¹, corresponding to exchanges ≈40 and ≈1550 times, respectively, more rapid than the less labile μ₂-OH sites in the Al₁₃ and GaAl₁₂ molecules. We find evidence of nearly first-order pH dependence on the rate of exchange of this μ₂-OH site with bulk solution for the GeAl₁₂ molecule, which contrasts with Al₁₃ and GaAl₁₂ molecules.     

The very depleted nature of certain primary mid-ocean ridge basalts

Many mid-ocean ridge basalts (MORBs) might be ultimately derived from primary magmas that are very depleted in Na₂O and TiO₂. These very depleted primary magmas have 0.60 to 1.50 wt.% Na₂O and 0.10 to 0.50 wt.% TiO₂ compared to MORBs, which typically have > 1.90% Na₂O and >0.60% TiO₂. Evidence for these depleted primary magma compositions is obtained from megacrysts in MORBs, from glass inclusions within these megacrysts, and from the highly calcic plagioclases (An_91–96) and depleted clinopyroxenes (Na₂O mostly between 0.10 and 0.35) in certain abyssal peridotites.Cumulate ultramanfi and gabbroic rocks from the North Arm Mountain Massif of the Bay of Islands ophiolite complex show a progressive increase in the Na₂O and TiO₂ abundances in clinopyroxene crystals with stratigraphic height in the ophiolite. The use of mineral-liquid distribution coefficients and cumulate mineral compositions indicate that the liquids from which these minerals crystallized had 0.10 to 0.20 wt.% TiO₂ and 0.60 to 0.80 wt.% Na₂O for the lowermost cumulate ultramafic rocks, with TiO₂ and Na₂O abundances of liquids increasing progressively to normal MORB abundances during crystallization of higher-level gabbroic cumulates. These data clearly demonstrate that primary basalts that are very depleted in Na₂O and TiO₂ can differentiate to form residual magmas that are indistinguishable from MORBs.     

The integrated effects of climate and hydrologic uncertainty on future flood risk assessments

This work examines future flood risk within the context of integrated climate and hydrologic modelling uncertainty. The research questions investigated are (1) whether hydrologic uncertainties are a significant source of uncertainty relative to other sources such as climate variability and change and (2) whether a statistical characterization of uncertainty from a lumped, conceptual hydrologic model is sufficient to account for hydrologic uncertainties in the modelling process. To investigate these questions, an ensemble of climate simulations are propagated through hydrologic models and then through a reservoir simulation model to delimit the range of flood protection under a wide array of climate conditions. Uncertainty in mean climate changes and internal climate variability are framed using a risk‐based methodology and are explored using a stochastic weather generator. To account for hydrologic uncertainty, two hydrologic models are considered, a conceptual, lumped parameter model and a distributed, physically based model. In the conceptual model, parameter and residual error uncertainties are quantified and propagated through the analysis using a Bayesian modelling framework. The approach is demonstrated in a case study for the Coralville Dam on the Iowa River, where recent, intense flooding has raised questions about potential impacts of climate change on flood protection adequacy. Results indicate that the uncertainty surrounding future flood risk from hydrologic modelling and internal climate variability can be of the same order of magnitude as climate change. Furthermore, statistical uncertainty in the conceptual hydrological model can capture the primary structural differences that emerge in flood damage estimates between the two hydrologic models. Copyright © 2014 John Wiley & Sons, Ltd.