Generation of CO2-rich melts during basalt magma ascent and degassing

To test mechanisms of basaltic magma degassing, continuous decompressions of volatile-bearing (2.7–3.8 wt% H₂O, 600–1,300 ppm CO₂) Stromboli melts were performed from 250–200 to 50–25 MPa at 1,180–1,140 °C. Ascent rates were varied from 0.25 to ~1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 10⁴ to 10⁶ cm^?3, similar to Stromboli pumices. Vesicularities range from 0 to ~20 vol%. Final melt H₂O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO₂ concentration. High vesicularity charges have glass CO₂ concentrations that follow theoretical equilibrium degassing paths, whereas glasses from low vesicularity charges show marked deviations from equilibrium, with CO₂ concentrations up to one order of magnitude higher than solubilities. FTIR profiles and maps reveal glass CO₂ concentration gradients near the gas–melt interface. Our results stress the importance of bubble nucleation and growth, and of volatile diffusivities, for basaltic melt degassing. Two characteristic distances, the gas interface distance (distance either between bubbles or to gas–melt interfaces) and the volatile diffusion distance, control the degassing process. Melts containing numerous and large bubbles have gas interface distances shorter than volatile diffusion distances, and degassing proceeds by equilibrium partitioning of CO₂ and H₂O between melt and gas bubbles. For melts where either bubble nucleation is inhibited or bubble growth is limited, gas interface distances are longer than volatile diffusion distances. Degassing proceeds by diffusive volatile transfer at the gas–melt interface and is kinetically limited by the diffusivities of volatiles in the melt. Our experiments show that CO₂-oversaturated melts can be generated as a result of magma decompression. They provide a new explanation for the occurrence of CO₂-rich natural basaltic glasses and open new perspectives for understanding explosive basaltic volcanism.     

Optical remote sensing of submerged aquatic vegetation: Opportunities for shallow clearwater streams

Remote sensing has rarely been used as a tool to map and monitor submerged aquatic vegetation (SAV) in rivers, due to a combination of insufficient spatial resolution of available image data and strong attenuation of light in water through absorption and scattering. The latter process reduces the possibility to use spectral reflectance information to accurately classify submerged species. However, increasing availability of very high resolution (VHR) image data may enable the use of shape and texture features to help discriminate between species by taking an object based image analysis (OBIA) approach, and overcome some of the present limitations.This study aimed to investigate the possibility of using optical remote sensing for the detection and mapping of SAV. It firstly looked at the possibilities to discriminate submerged macrophyte species based on spectral information only. Reflectance spectra of three macrophyte species were measured in situ across a range of submergence depths. The results showed that water depth will be a limiting factor for the classification of species from remote sensing images. Only Spiked Water Milfoil (Myriophyllum spicatum) was indicated as spectrally distinct through ANOVA analysis, but subsequent Jeffries–Matusita distance analysis did not confirm this. In particular Water Crowfoot (Ranunculus fluitans) and Pondweed (Potamogeton pectinatus) could not be discriminated at 95% significance level. Spectral separability of these two species was also not possible without the effect of an overlying water column.Secondly, the possibility to improve species discrimination, using spatial and textural information was investigated for the same SAV species. VHR image data was acquired with a Near Infrared (NIR) sensitive DSLR camera from four different heights including a telescopic pole and a Helikite UAS. The results show that shape and texture information can improve the detection of the spectrally similar Pondweed and Water Crowfoot from VHR image data. The best performing feature ‘length/width ratio of sub-objects’ was obtained through expert knowledge. All of the shape and texture based features performed better at species differentiation than the spectrally based features.In conclusion this study has shown that there is considerable potential for the combination of VHR data and OBIA to map SAV in shallow stream environments, which can benefit species monitoring and management.     

Effects of hydrophobicity on splash erosion of model soil particles by a single water drop impact

Raindrop impact can be a major contributor to particle mobilization for soils and other granular materials. In previous work, water repellent soils, comprised of hydrophobic particles, have been shown to exhibit greater splash erosion losses under multiple drop impact. However, the underlying principle differences in splash behavior between hydrophobic and hydrophilic granular surfaces have not been studied to date. In this study the effects of particle hydrophobicity on splash behaviour by a single water drop impact were examined using high‐speed videography. Water drops (4 mm in diameter) were dropped on beds of hydrophilic and hydrophobic glass beads (sieved range: 350–400 µm), serving as model soil particles. The drop velocity on impact was 2.67 m s^‐1, which corresponds to ~30% of the terminal velocity of a raindrop of similar size. The resulting impact behaviour was measured in terms of the trajectories of particles ejected from the beds and their final resting positions. The response to the impacting water drop was significantly different between hydrophilic and hydrophobic particles in terms of the distance distribution, the median distance travelled by the particles and number of ejected particles. The greater ejection distances of hydrophobic particles were mainly the result of the higher initial velocities rather than differences in ejecting angles. The higher and longer ejection trajectories for hydrophobic particles, compared with hydrophilic particles, indicate that particle hydrophobicity affects splash erosion from the initial stage of rainfall erosion before a water layer may be formed by accumulating drops. The ~10% increase in average splash distance for hydrophobic particles compared with hydrophilic particles suggests that particle hydrophobicity can result in greater net erosion rate, which would be amplified on sloping surfaces, for example, by ridges in ploughed agricultural soils or hillslopes following vegetation loss by clearing or wildfire. Copyright © 2012 John Wiley & Sons, Ltd.     

Raman spectroscopic detection of key biomarkers of cyanobacteria and lichen symbiosis in extreme Antarctic habitats: Evaluation for Mars Lander missions

With proposals that micro-miniaturised Raman spectrometers could soon be part of a suite of analytical instrumentation on the surface of Mars, it is critically important to examine the spectral information that could be forthcoming from attempts to determine key molecular biosignatures under the hostile conditions of extra-terrestrial planetary exploration. Current approaches include the analysis of genuine martian geological material in the form of the SNC class meteorites, the formulation of simulated martian regoliths and the examination of putative martian terrestrial analogues; the latter provide the basis of this paper in the form of Antarctic extremophile habitats. In particular, specimens of epilithic, chasmolithic and endolithic lichen and cyanobacterial colonies sampled along a progressively worsening transect towards a “limits of life” situation, beyond which survival of organisms becomes impossible, provide what is arguably the best terrestrial proving-ground for prototype Raman spectrometers for martian exploration. Here, we report the results of experiments on these extant Antarctic extremophile colonies using a range of Raman excitation wavelengths and experimental conditions and also include a compilation of molecular spectral biosignatures, which may be considered as a suitable database for recognition of bioorganic modification of geological strata.     

Tephrabase: tephrochronology and the development of a centralised European database

Tephrabase was launched on the World Wide Web in 1995 as a tool for tephrochronological research. In order to facilitate the identification, correlation and dating of tephra deposits, this database may be interrogated through multiple routes, including by source volcano, date, location, and tephra chemistry; datasets include stratigraphy, geochemistry, chronology and spatial information. Currently all the European data refer to Late Quaternary Icelandic‐sourced tephras, post‐12 k yr BP. The sites (62) where the tephra deposits are found include Iceland, the United Kingdom, Ireland, the Faroe Islands, Sweden and Russia. In addition, there are also data on tephra layers in central Mexico. Use of Tephrabase highlights the importance of selected geochemical data, but this has to be used with care as major element characteristics alone do not always produce unique definitions for single tephra deposits. For the most accurate results multiple criteria must be used. Tephrabase can be found at http://www.tephrabase.org . Copyright © 2007 John Wiley & Sons, Ltd.     

NWA 1152 and Sahara 00182: New primitive carbonaceous chondrites with affinities to the CR and CV groups

Abstract— We have investigated the mineralogy, petrography, bulk chemistry, and light element isotope composition of the ungrouped chondrites North West Africa (NWA) 1152 and Sahara 00182. NWA 1152 contains predominantly type 1 porphyritic olivine (PO) and porphyritic olivinepyroxene (POP) chondrules. Chondrule silicates are magnesium‐rich (Fo_{98.8 ± 1.2}, n = 36; Fs_{2.3 ± 2.1} Wo_{1.2 ± 0.3}, n = 23). Matrix comprises ?40 vol% of the sample and is composed of a micron sized silicate groundmass with larger silicate, sulfide, magnetite, and Fe‐Ni metal (Ni ?50 wt%) grains. Phyllosilicates were not observed in the matrix. Refractory inclusions are rare (0.3 vol%) and are spinel pyroxene aggregates or amoeboid olivine aggregates; melilite is absent from the refractory inclusions. Sahara 00182 contains predominantly type 1 PO chondrules, POP chondrules are less common. Most chondrules contain blebs of, and are often rimmed with, Fe‐Ni metal and sulfide. Chondrule phenocrysts are magnesium‐rich (Fo_{92.2 ± 0.6}, n = 129; Fs_{4.4 ± 1.8} Wo_{1.3 ± 1.1}, n = 16). Matrix comprises ?30 vol% of the meteorite and is predominantly sub‐micron silicates, with rare larger silicate gains. Matrix Fe‐Ni metal (mean Ni = 5.8 wt%) and sulfide grains are up to mm scale. No phyllosilicates were observed in the matrix. Refractory inclusions are rare (1.1 vol%) and melilite is absent. The oxygen isotope composition of NWA 1152 falls within the range of the CV chondrites with δ¹⁷O = ?3.43%0 δ¹⁸O = 0.70%0 and is similar to Sahara 00182, δ¹⁷O = ?3.89%0, δ¹⁸O = ?0.19%0 (Grossman and Zipfel 2001). Based on mineralogical and petrographic characteristics, we suggest NWA 1152 and Sahara 00182 show many similarities with the CR chondrites, however, oxygen isotopes suggest affinity with the CVs. Thus, neither sample can be assigned to any of the currently known carbonaceous chondrite groups based on traditionally recognized characteristics. Both samples demonstrate the complexity of inter‐ and intra‐group relationships of the carbonaceous chondrites. Whatever their classification, N WA 1152 and Sahara 00182 represent a source of relatively pristine solar system material.