The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.     

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.     

Rain on snow induced urban floods in cold maritime climate: Risk,indicators and trends

Urban floods pose a societal and economical risk. This study evaluated the risk and hydro-meteorological conditions that cause pluvial flooding in coastal cities in a cold climate. Twenty years of insurance claims data and up to 97 years of meteorological data were analysed for Reykjavík, Iceland (64.15°N; <100 m above sea level). One third of the city's wastewater collection system is combined, and pipe grades vary from 0.5% to 10%. Results highlight semi-intensive rain (<7 mm/h; ≤3 year return period) in conjunction with snow and frozen ground as the main cause for urban flood risk in a climate which undergoes frequent snow and frost cycles (avg. 13 and 19 per season, respectively). Floods in winter were more common, more severe and affected a greater number of neighbourhoods than during summer. High runoff volumes together with debris remobilized with high winds challenged the capacity of wastewater systems regardless of their age or type (combined vs. separate). The two key determinants for the number of insurance claims were antecedent frost depth and total precipitation volume per event. Two pluvial regimes were particularly problematic: long duration (13–25 h), late peaking rain on snow (RoS), where snowmelt enhanced the runoff intensity, elongated and connected independent rainfall into a singular, more voluminous (20–76 mm) event; shorter duration (7–9 h), more intensive precipitation that evolved from snow to rain. Closely timed RoS and cooling were believed to trigger frost formation. A positive trend was detected in the average seasonal snow depth and volume of rain and snowmelt during RoS events. More emphasis, therefore, needs to be placed on designing and operating urban drainage infrastructure with regard to RoS co-acting with frozen ground. Furthermore, more detailed, routine monitoring of snow and soil conditions is important to predict RoS flood events.     

Assessing the ‘two water worlds’ hypothesis and water sources for native and exotic evergreen species in south‐central Chile

Recent studies using water‐stable isotopes (δ¹⁸O and δ²H) have suggested an ecohydrological separation of water flowing to streams or recharging groundwater and water used by trees, known as the ‘two water worlds’ (TWW) hypothesis. In this study, we measured water isotopic composition in precipitation [open field and throughfall, i.e. local meteoric water line (LMWL)] and the mobile water compartment (i.e. stream and soil solution), bulk soil water and xylem water over a period of 1.5 years in two headwater catchments: NF, covered with old growth native evergreen forest (Aetoxicon punctatum, Laureliopsis philippiana and Eucriphya cordifolia), and EP, covered with 4 and 16‐year‐old Eucalyptus nitens stands. Our results show that precipitation, stream and soil solution plot approximately along the LMWL, while xylem waters from all studied tree species plot below the LMWL, supporting the TWW hypothesis. However, we also found evidence of ecohydrological connectivity during the wet season, likely controlled by the amount of antecedent precipitation. These observations hold for all investigated tree species. On both sites, a different precipitation source for stream and xylem water was observed. However, in EP, bulk soil showed a similar precipitation source as xylem water from both E. nitens stands. This suggests that E. nitens may use water that is recharging the bulk soil compartment. We conclude that under a rainy temperate climate, the TWW hypothesis is temporal and does not apply during wet seasons. Copyright © 2016 John Wiley & Sons, Ltd.