Generation and performance of automated jarosite mineral detectors for visible/near-infrared spectrometers at Mars

We have developed two automated detectors that can recognize the sulfate mineral jarosite in unknown visible to near-infrared spectra (350-2500 nm). The two detectors are optimized for use within the terrestrial and martian atmospheres. The detectors are built from Support Vector Machines trained using a generative model to create linear mixtures of library mineral spectra. Both detectors performed with an average ∼90% accuracy on laboratory spectra of single minerals and the laboratory and field spectra of rocks collected in a hydrothermal environment. This type of algorithm will contribute to the efficiency of onboard data analysis of landed and orbital visible/near-infrared spectrometers at Mars.     

Comment on “An extended STIRPAT model-based methodology for evaluating the driving forces affecting carbon emissions in existing public building sector: evidence from China in 2000–2015” by Ma et al. (2017)

Natural Hazards - This contribution highlights that the paper presented by Ma et al. (Nat Hazards 89(2):741–756, 2017) presents VIF lower than 1 which does not coincide with the natural...     

Frasnian–Famennian crisis in the Malaguide Complex (Betic Cordillera,Spain)

Devonian sediments of the Malaguide Complex potentially could include the Frasnian–Famennian boundary, one of the five greatest Phanerozoic biotic crises. Conodont biofacies and microfacies of carbonate clasts from a pebbly mudstone underlying Tournaisian radiolarites allows identification, for the first time in the Malaguide Complex, of Devonian shallow marine environments laterally grading to deeper realms. The clasts yielded Frasnian conodont associations of the falsiovalis to rhenana biozones, with six biofacies that reveal different environmental conditions in their source areas. Source sediments were dismantled and redeposited within the pebbly mudstone, whose origin is tentatively related to one of the events that are associated worldwide with the Frasnian–Famennian crisis. The latter is recorded, in two equivalent Malaguide pelagic successions, by stratigraphic discontinuities, and it was, probably, tectonically and/or eustatically controlled, as in other Alpine‐Mediterranean Paleotethyan margins.     

Climatic vs. tectonic signals in a continental extensional basin (Teruel,NE Spain) from stable isotope (δ18O) and sequence stratigraphical evolution

Alluvial fans and shallow carbonate lakes interfered in the Teruel half‐graben during the Late Miocene–Pliocene. Tectonic influence is recorded in alluvial and lacustrine–palustrine successions, with long‐term climate changes being recorded in detail in the isotopic signatures of carbonates. Episodes of tectonic activity induced alluvial fan progradation and lake retraction in the whole basin. Three lacustrine stages have been identified, which support the idea that climate also exerted an important control on sedimentation. The transition between stages 1 and 2 occurred during a tectonically calm episode due to an increase in aridity in the Early Turolian; small fans with source areas next to the lake margin prograded, inducing lake‐shore retraction. The transition from stage 2 to 3 was caused by the superimposition of increasing tectonic activity and aridity effects. Our study demonstrates that discrimination of allogenic factors controlling sedimentation in continental closed basins is possible using sequence stratigraphy in combination with other techniques such as geochemistry of carbonates.     

A stress and displacement discontinuity element method for elastic transversely anisotropic rock

The paper presents closed‐form solutions for stress and displacement influence functions for stress discontinuity (SD) and displacement discontinuity (DD) elements, for a two‐dimensional plane‐strain elastic, transversely anisotropic medium. The solutions for SD elements are based on Kelvin's problem and for DD elements on the concept of dipoles. Stress and displacement influence functions are derived for the following elements: constant SD, linear SD, constant DD, linear DD, square root DD, parabolic DD, constant DD surface, and linear DD surface elements. The formulations are incorporated into FROCK, a hybridized boundary element method code, and are validated by providing comparisons between the results from FROCK and the finite element code ABAQUS. A limited parametric analysis shows the effects of slight anisotropy on the stress field around the tip of a crack and of the orientation of the crack with respect to the axes of elastic symmetry. Copyright © 2014 John Wiley & Sons, Ltd.     

Spatially distributed tracer‐aided modelling to explore water and isotope transport,storage and mixing in a pristine,humid tropical catchment

Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km² San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.     

Late Quaternary (Marine Isotope Stage 3 to Recent) sedimentary evolution of the Basque shelf (southern Bay of Biscay)

Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ¹⁸O_bull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From ～56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.     

Ecological distribution of Stephanodiscus niagarae Ehrenberg in central Mexico and niche modeling for its last glacial maximum habitat suitability in the Nearctic realm

Journal of Paleolimnology - Stephanodiscus niagarae Ehrenberg is currently restricted to specific regions of central Mexico, however, during the late Pleistocene, it had a wider distribution in the...