Organochlorinated compounds in Caspian Sea sediments

Several organochlorinated contaminants, including numerous pesticides, were determined in coastal sediments from the Caspian Sea. The most important contaminants were p,p'-DDT (up to 7400 pg g(-1)) and its breakdown products, p,p'-DDD (up to 3400 pg g(-1)) and p,p'-DDE (up to 1300 pg g(-1)). Although the contamination was most severe in Azerbaijan, the sediment concentrations and percentage distribution of the three DDT-related compounds indicated that such contamination constitutes a contemporary and ubiquitous problem in the Caspian Sea. Lindane represented the second most significant contaminant, particularly in the Russian Federation, with concentrations up to 609 pg g(-1). The concentrations of HCB and other chlorinated pesticides (cis- and trans-chlordane, methoxychlor, heptachlor, heptachlor epoxide, aldrin, endrin, and endosulfans) were lower and not generally of concern, but the pesticides did demonstrate markedly different distributions reflecting differing agricultural usage in the region. The concentrations of Sigma PCBs were also quite low and ranged from 0.03 to 6.4 ng g(-1), with the highest amounts in the Russian Federation and Azerbaijan.     

An Anisotropic Attenuation Law of Macroseismic Intensity Performed on Virtual Intensity Distribution of Seismogenic Zones

An anisotropic attenuation law, based on an anisotropic characterization of intensity distribution for seismogenic zones, is proposed. This approach, that distinguishes itself for its consistency to the observed data, initially reconfigured by filtering procedures, is particularly suitable for seismic hazard evaluation.     

Minimum 1-D velocity model in Southeastern Sicily (Italy) from local earthquake data: an improvement in location accuracy

The monitoring of seismic activity inSoutheastern Sicily (Italy) has beenrecently improved by a digital seismicnetwork. This effort has produced ahomogeneous and complete dataset which weused to define a reference 1-D velocitymodel. We have inverted P- and S-wavearrival times from 51 selected localearthquakes by using several initialvelocity and layer thickness models. Then,the range of possible velocity modelsobtained was tested with earthquakelocations to select the best velocitymodel. Improvements in location accuracy byusing the Minimum 1-D velocity model, withrespect to the locations obtained by usingthe routine velocity model, were evidencedfrom the reduced residuals, the smallerestimated location errors, and theincreased tendency of foci to cluster. Thedistribution of relocated hypocentersconfirmed the lack of seismic activity inthe central part of the area.     

Contexte lithostructural, âges 40K40Ar et géochimie du volcanisme calco-alcalin tertiaire de Cap-d'Ail dans le tunnel ferroviaire de Monaco

Lithostratigraphic and structural framework, chronology and geochemistry of the Tertiary calc-alkaline volcanism of Cap-d'Ail (French Maritime Alps) are specified according to the new data collected during the earthworks of the recent railway tunnel built between Cap-d'Ail and Monaco. Two different magmatic events were dated: the first one, to Palaeogene, the other one, to Neogene. To cite this article: J.-P. Ivaldi et al., C. R. Geoscience 335 (2003).     

The detrital record of late‐Miocene to Pliocene surface uplift and exhumation of the Venezuelan Andes in the Maracaibo and Barinas foreland basins

A multidisciplinary approach, combining sediment petrographic, palynological and thermochronological techniques, has been used to study the Miocene‐Pliocene sedimentary record of the evolution of the Venezuelan Andes. Samples from the Maracaibo (pro‐wedge) and Barinas (retro‐wedge) foreland basins, proximal to this doubly vergent mountain belt, indicate that fluvial and alluvial‐fan sediments of similar composition were shed to both sides of the Venezuelan Andes. Granitic and gneissic detritus was derived from the core of the mountain belt, whereas sedimentary cover rocks and uplifted foreland basin sediments were recycled from its flanks. Palynological evidence from the Maracaibo and Barinas basins constrains depositional ages of the studied sections from late Miocene to Pliocene. The pollen assemblages from the Maracaibo Basin are indicative of mountain vegetation, implying surface elevations of up to 3500–4000 m in the Venezuelan Andes at this time. Detrital apatite fission‐track (AFT) data were obtained from both stratigraphic sections. In samples from the Maracaibo basin, the youngest AFT grain‐age population has relatively static minimum ages of 5 ± 2 Ma, whereas for the Barinas basin samples AFT minimum ages are 7 ± 2 Ma. With exception of two samples collected from the Eocene Pagüey Formation and from the very base of the Miocene Parángula Formation, no evidence for resetting and track annealing in apatite due to burial heating in the basins was found. This is supported by rock‐eval analyses on organic matter and thermal modelling results. Therefore, for all other samples the detrital AFT ages reflect source area cooling and impose minimum age constraints on sediment deposition. The main phase of surface uplift, topography and relief generation, and erosional exhumation in the Venezuelan Andes occurred during the late Miocene to Pliocene. The Neogene evolution of the Venezuelan Andes bears certain similarities with the evolution of the Eastern Cordillera in Colombia, although they are not driven by exactly the same underlying geodynamic processes. The progressive development of the two mountain belts is seen in the context of collision of the Panama arc with northwestern South America and the closure of the Panama seaway in Miocene times, as well as contemporaneous movement of the Caribbean plate to the east and clock‐wise rotation of the Maracaibo block.     

Introduction to the PICES practical workshop: objectives,overview of the study area,and projects conducted by the participants

We coordinated a collaborative research project to investigate environmental conditions in Vancouver Harbour, British Columbia, Canada, between 23 May and 7 June 1999. This special volume of Marine Environmental Research presents a collection of papers giving results of these studies. The project was part of a practical workshop sponsored by the Marine Environmental Quality (MEQ) committee of the North Pacific Marine Science Organization (PICES). Twenty-four scientists from PICES countries (USA, Canada, Russia, Japan, Korea, and China) participated. A wide variety of data was collected, including community structure of benthic invertebrates and fish, evaluation of fish health using biological markers and exposure data, evaluation of contaminant exposure in inter-tidal invertebrates, imposex in gastropods, and information about natural toxins produced by algae. The workshop provided an opportunity for PICES participants to gain an improved appreciation of the approaches and techniques used by other member countries to assess the effects of marine pollution. The purpose of this introductory paper is to briefly describe the project, provide background information on how it was organized, and give an overview of our knowledge about the harbour's environment.     

Organic and trace metal contaminants in sediments and English sole tissues from Vancouver Harbour,Canada

As part of a multinational workshop on marine environmental quality, sediments were collected from seven sites in Vancouver Harbour and analyzed for polynuclear aromatic hydrocarbons (PAHs) and organochlorines (OCs), and for trace metals. English sole were collected from five sites, and muscle was analyzed for trace metals and liver for OCs. As expected, sediment PAH and OC concentrations and tissue OC concentrations were higher at sites east of the First Narrows, compared to the outer harbor and reference sites. Sediment PAH concentrations east of the First Narrows were similar to concentrations at moderately contaminated sites in Puget Sound, south of Vancouver Harbour. In contrast, concentrations of OCs in sediments and tissue were low to moderate, even at relatively contaminated sites within Vancouver Harbour. Although several trace metals in sediments were higher than in contaminated sediments from Puget Sound, trace metals measured in fish muscle were lower.     

Distribution of sterol and fatty alcohol biomarkers in particulate matter from the frontal structure of the Alboran Sea (S.W. Mediterranean Sea)

Sterol and fatty alcohol biomarkers were analyzed in suspended and sinking particles from the water column (20–300 m) of the Almeria–Oran frontal zone to characterize the biogenic sources and biogeochemical processes. Diatom- and haptophyte-related sterols were predominant at all sites and vertical distributions of sterol, and fatty alcohol biomarkers in sinking particles were markedly different from suspended particles. In contrast to the relatively fresh sinking particles with elevated concentrations of phyto- and zooplanktonic sterols, suspended particles were extensively degraded with increasing depth and exhibited a more terrestrial and zooplanktonic signature with depth.Sterol and alcohol biomarkers distributions and δ¹³C values from the jet core and the associated gyre of Atlantic waters showed a decoupling between the sinking particles of 100- and 300-m depth, demonstrating the influence of lateral advection in the frontal zone. In contrast, vertical transport of the particulate organic matter in Mediterranean waters was interpreted from the similar isotopic and molecular composition at both depths. The high abundance of phytosterols and phytol below the euphotic zone at 100 m signified that downwelling of biomass occurred on the downstream side of the gyre. The high concentrations of phytosterols and POC, in combination with the high phytosterols/phytol ratio, indicated the accumulation of detrital plant material in the oligotrophic Mediterranean waters near the frontal zone.A higher contribution of phytol in the sinking particles collected during the night at the surface of the jet and at the upstream side of the gyre provided evidence of diel vertical zooplankton migration and important grazing by herbivorous zooplankton.Carbon isotope ratios of sterols confirmed that the 24-ethylcholest-5-en-3β-ol, commonly associated with terrestrial sources, was a substantial constituent of the phytoplankton in this area. However, the more δ¹³C depleted values obtained for this compound in suspended particles suggested that there was some terrestrial contribution that only becomes evident after degradation of the more labile marine organic matter.