Toxicopathic liver lesions in English sole and chemical contaminant exposure in Vancouver Harbour,Canada

The prevalence of toxicopathic liver lesions in English sole (Pleuronectes vetulus) was determined along a presumed gradient of chemical contamination in Vancouver Harbour, Canada. Fish were captured from five sites in or near Vancouver Harbour, British Columbia, Canada. No toxicopathic lesions were observed in fish examined at the reference site (Howe Sound outside Vancouver Harbour), or at the outer harbour site. In contrast, 20-23% of the fish from three sites located in the central harbour, Indian Arm and Port Moody Arm had one or more types of toxicopathic lesions. Likewise, aromatic hydrocarbon (AH) metabolites measured in bile exhibited a gradient in levels from lower concentrations at the reference site to significantly higher levels in fish from Indian Arm and Port Moody Arm harbour sites. The occurrence of toxicopathic liver lesions was statistically associated with concentrations of AHs measured in sediment and AH metabolite levels measured in bile.     

Zonation and Ecology of Epiphytic Hydroids in a Mediterranean Coastal Lagoon: The 'Stagnone' of Marsala (North-West Sicily)

Abstract. Distribution patterns of epiphytic hydroids of seagrass ( Posidonia occanica and Cymodocea nodosa ) beds were studied in the 'Stagnone', a moderately hypcrhaline lagoon in Sicily. The role of water movement in determining the spatial and temporal zonation of epiphytic hydroids and their morpho-physiological variations is evaluated. Remarks on systematics arc also included.     

Micropores in plagioclase

Plagioclase feldspar is often surprisingly porous on a small scale. Pores range in size from less than 1 μm to about 40 μm, and occupy up to 2.3 % by volume. In general, the highest plagioclase porosities occur in rocks which would have had a comparatively “wet” history: normal granites and pegmatites. Rocks which were drier—gabbro, a diabase and an exceptionally dry granite—have much lower plagioclase porosities, as do two lowgrade metamorphic samples. It is suggested that the nearly equant pores represent sites of former fluid inclusions, while the planar cavities of cracklike cross-section may be partially annealed fractures formed early in the history of the rock.     

Environmental geochemistry and mineralogy of lead at the old mine area of Baccu Locci (south-east Sardinia,Italy)

About a century of exploitation of the galena-arsenopyrite deposit of Baccu Locci in Sardinia (Italy) has caused a severe, persistent arsenic contamination that extends downstream from the mine for several kilometres. Differently from As, the contamination of lead in surface waters is only localised in the upper part of the mine despite very high Pb concentrations in geologic materials (waste rocks, tailings, stream sediments, soils) over the whole Baccu Locci stream catchment. The aqueous and solid speciation of Pb in various environmental media of the Baccu Locci system was determined by means of a combined analytical (ICP-MS, SEM-EDX, TEM-EDX, chemical extraction) and thermodynamic approach (PHREEQC). The study has pointed out that relatively little Pb (up to 30 µg/L) is initially released to surface waters (pH = 7–8, Eh = 0.4–0.6 V) very rapidly due to dissolution of anglesite that is the first product of galena oxidation. Subsequently, Pb is removed (down to 0.6 µg/L) by probable sorption onto hydrous ferric oxides (e.g. ferrihydrite) and/or possible precipitation of As-containing plumbojarosite that is the main secondary Pb-bearing phase in stream sediments/tailings along the Baccu Locci stream course. The latter hypothesis is controversial since it is reported from the literature that plumbojarosite is formed under acidic conditions, although there is contrary field evidence as well. Bearing in mind the uncertainties introduced from thermodynamic and analytical data, the solubility calculations indicate strong undersaturation of surface waters with respect to plumbojarosite (SI: ? 19.9 to ? 3.7). On the contrary arsenatian plumbojarosite is at or close to saturation (SI: ? 0.6 to 3.2) in most surface waters and beudantite is clearly above saturation (SI: 4.1 to 12.7). This suggests that the incorporation of As might increase the stability of plumbojarosite, extending it up to near-neutral conditions. As a consequence, Pb is prevented from being released downstream to surface waters, and dissolved Pb concentrations remain definitely below the Italian and WHO limits for drinking waters (50 µg/L and 10 µg/L, respectively).     

Evidence of a partial melt zone beneath Stromboli volcano (Italy) from inversion of teleseismic receiver functions

Teleseismic body waves from broadband seismic stations are used to investigate the crustal and uppermost mantle structure of Stromboli volcano through inversion of the receiver functions (RFs). First, we computed RFs in the frequency domain using a multiple-taper spectral correlation technique. Then, the non-linear neighbourhood algorithm was applied to estimate the seismic shear wave velocity of the crust and uppermost mantle and to define the main seismic velocity discontinuities. The stability of the inversion solution was tested using a range of initial random seeds and model parameterizations. A shallow Moho, present at depth of 14.8 km, is evidence of a thinned crust beneath Stromboli volcano. However, the most intriguing and innovative result is a low S velocity layer in the uppermost mantle, below 32 km. The low S velocity layer suggests a possible partial melt region associated with the volcanism, as also recently supported by tomographic studies and petrological estimations.     

Land Cover Classification Using High‐Resolution Aerial Photography in Adventdalen,Svalbard

A methodology was tested for high‐resolution mapping of vegetation and detailed geoecological patterns in the Arctic Tundra, based on aerial imagery from an unmanned aerial vehicle (visible wavelength – RGB, 6 cm pixel resolution) and from an aircraft (visible and near infrared, 20 cm pixel resolution). The scenes were fused at 10 and 20 cm to evaluate their applicability for vegetation mapping in an alluvial fan in Adventdalen, Svalbard. Ground‐truthing was used to create training and accuracy evaluation sets. Supervised classification tests were conducted with different band sets, including the original and derived ones, such as NDVI and principal component analysis bands. The fusion of all original bands at 10 cm resolution provided the best accuracies. The best classifier was systematically the maximum neighbourhood algorithm, with overall accuracies up to 84%. Mapped vegetation patterns reflect geoecological conditioning factors. The main limitation in the classification was differentiating between the classes graminea, moss and Salix, and moss, graminea and Salix, which showed spectral signature mixing. Silty‐clay surfaces are probably overestimated in the south part of the study area due to microscale shadowing effects. The results distinguished vegetation zones according to a general gradient of ecological limiting factors and show that VIS+NIR high‐resolution imagery are excellent tools for identifying the main vegetation groups within the lowland fan study site of Adventdalen, but do not allow for detailed discrimination between species.     

10Be surface exposure dating reveals unexpected high deformation rates in the central Andean wedge interior

Understanding deformation associated with active thrust wedges is essential to evaluate seismic hazards. In this study, we investigate the spatial distribution, timing, and rates of deformation across the central Andean backarc of Argentina, where deformation and shortening have been assumed to occur within a narrow wedge‐front zone. The combined results of our geomorphic mapping, topographic surveying, and ¹⁰Be exposure dating demonstrate that fault activity related to the growth of the Andean orogenic wedge is not only limited to a narrow thrust front zone but also occurs in the Andean wedge interior. There, internal structures with deformation rates of ca. 1.3 mm/year have been active during the last ~140 ka. Widely distributed deformation implies that seismic hazards may have been underestimated in the internal part of the Andean orogen.