Re-examination of the crystal structure of weberite

Summary The crystal structure of weberite, Na₂MgAlF₇, was redetermined from 3-dim. X-ray data and refined by least squares methods in space groupImma to a conventional reliability factorR=0.036. Mg and Al have octahedral 6-coordination. Two crystallographically independent kinds of Na atoms form different NaF₈-polyhedra with the F atoms at the corners of a flattened hexagonal bipyramid and of a square prism, respectively.

---

Neubestimmung der Kristallstruktur des Weberits

Zusammenfassung Die Kristallstruktur des Weberits, Na₂MgAlF₇, wurde aus 3-dim. Röntgendaten neu hestimmt und mit der Methode der kleinsten Quadrate in RaumgruppeImma auf den konventionellen ZuverlässigkeitsfaktorR=0,036 verfeinert. Mg und Al haben oktaedrische 6-Koordination. Zwei kristallographisch unabhängige Arten von Na-Atomen bilden mit den F-Atomen zwei verschiedene NaF₈-Polyeder; in einem sitzen die F-Atome an den Ecken einer abgeflachten hexagonalen Bipyramide, im anderen an den Ecken eines quadratischen Prismas.

---

---

With 2 Figures     

Uranium-lead geochronology of the Archean Imataca Series,Venezuelan Guayana Shield

Uranium and lead isotopic analyses of total-rock and feldspar samples from the Imataca Series indicate an early Archean (3.5⁺ b.y.) age for the basement gneisses. Lead isotopic evolution in most gneiss samples may approximately be described by a three-stage model. The start of the third stage is marked by a pervasive metamorphic event, locally up to pyroxene-granulite grade, at 2 b.y. ago, which commonly resulted in extensive depletion of uranium relative to lead.     

Can Rock Composition Affect Sublittoral Epibenthic Communities?

Abstract. Biomineralogy, as the complex of interactions at different levels (cell, organism, species, and community) between organisms and minerals, may play a significant role in the spatial distribution and structure of marine communities. For instance, a negative influence of quartz has been underlined on the Mediterranean benthic communities, which show a species-poorer structure in quartz-rich environments. Excluding the role of quartz, the aim of this work is to verify whether the composition of various mineralogical substrata can affect a hard-bottom benthic community. In the Ligurian Sea, the Levanto area shows an astonishing complex of substrata with different petrographic characters: in a few kilometres, sandstones, serpentinites, gabbros, and basalts occur in geometric association. Consequently, this area represents a suitable frame for this type of study. Herein, algal photophilic assemblages growing on the four mineralogical substrata show significant differences in number of species and percentage cover or abundance. This suggests a significant influence of rock mineral composition on the hard bottom community. Therefore, rock composition must be taken into account for a better understanding of the processes at the basis of hard-bottom community development and diversity.     

Archaeological and historiographical implications of recent uplift of the Peloro Peninsula, NE Sicily

In ancient times, the name “Peloro” was used to indicate an anthropic area that gradually developed around the first known human settlement on the Sicilian shore near the Straits of Messina. Since the 5th century BC, historians have documented that numerous naval armadas landed for long periods at Peloro. However, the present-day morphology of the Peloro Cape Peninsula does not have any protected inlet that would offer a location to repair hundreds of ships, as has been documented by historical sources. To address this discrepancy, geomorphologic data were collected and analyzed to verify whether historical documents were consistent with the palaeotopography of the area. This approach is based on the analysis of the morphotectonic evolution of the coastal lowland that resulted from regional uplift over the Quaternary and Holocene. The results indicate that the harbour was located in the basin of the Pantano Piccolo salt marsh, and was large and deep enough to have sheltered up to 320 ships.     

Quantum-mechanical calculation of the vibrational spectrum of beryl (Al4Be6Si12O36) at the Γ point

A quantum-mechanical calculation of the zone-centre phonon spectrum of beryl has been performed, by using an hybrid HF/DFT Hamiltonian (B3LYP). An excellent agreement with the experiment has been obtained, being the difference between the calculated and the experimental vibrational frequencies (Raman, IR-TO and IR-LO) less than 5 cm^?1 on average. In the few cases where a relatively large disagreement between calculated and experimental data is observed, an explanation can be found which attributes the reason of the discrepancies to the experimental data rather than to the calculated ones. The calculation (i) allows the identification, in the experimental spectra, of the peaks corresponding to fundamental modes, overtones, combination bands and leakage; (ii) solves problems of band assignements due to the presence of LO–TO splitting in the IR spectra; (iii) provides the frequencies of silent modes; (iv) permits a full analysis of the atomic motion corresponding to each normal mode.     

A proposed format for geotechnical data

Large quantities of raw geotechnical data presently exist in the individual collections of institutions and agencies throughout the world. In order to increase the usefulness of this vast amount of data to the scientific community, the National Geophysical Data Center (NGDC) intends to develop a comprehensive data bank for geotechnical information to be located at NGDC, along with a common format for the exchange of geotechnical information. This format would facilitate not only the transfer of geotechnical information between researchers, but also simplify the exchange and development of computer software with which to manipulate the data.     

Rare Earth Element Geochemistry of the Zigzag - Klondyke Sedimentary Rock Formations: Clues to the Evolution of the Baguio Mineral District (Luzon), Philippines

Abstract. Petrographic analysis of the Oligocene-Miocene Zigzag Formation and Miocene Klondyke Formation of the Baguio Mineral District reveals a transitional arc source for the former and an undissected arc source for the latter. Whole rock geochemistry of these sedimentary rock formations show affiliation of the Zigzag Formation to active continental margin whereas the Klondyke Formation appears to have been derived from an oceanic island arc source. A different aspect of the geology of the district is further gleaned from the whole rock rare earth element geochemistry of these rocks. Samples from the Zigzag Formation are characterized by higher REE concentrations compared to the Klondyke Formation samples. The REE data indicate that the sedimentary rocks of the Klondyke Formation had geochemically-less fractionated igneous lithologies as their progenitor whereas the older Zigzag Formation was derived from a more differentiated source. This new set of information contributes to the understanding of the evolution of this district from a marginal basin to an island arc setting.     

Empirical mass balance modelling of South American tropical glaciers: case study of Antisana volcano,Ecuador

Abstract

Most Latin American glaciers are located in the tropical Andes. The melting processes of Glacier “15” on Antisana volcano were studied to understand the relationship between glacier retreat and natural climate variability and global climate change. Glaciers on the Antisana volcano are crucial sources of water as they feed the headwater rivers that supply Quito with potable water. The aim of this study was to build empirical models based on multiple correlations to reconstruct the mass loss of glaciers over a period of 10 years at three scales: local (data recorded by meteorological stations located around the volcano), regional (data from stations located around the country) and global (re-analysis data). Data quality was checked using graphical and statistical methods. Several empirical models based on multiple correlations were created to generate longer time series (42 and 115 years) of the mass balance for the glacier ablation zone. The long mass balance series were compared with the temperature variation series of the Earth’s surface in the Southern Hemisphere to estimate the relation between the mass balance and global warming. Our results suggest that the meteorological factors that best correlate with mass balance are temperature and wind.

Editor D. Koutsoyiannis     

Recruitment,habitat selection and larval photoresponse of Paraleucilla magna (Porifera,Calcarea) in Rio de Janeiro,Brazil

Little is known about the recruitment and behaviour of sponge larvae, especially of the class Calcarea. The calcareous sponge Paraleucilla magna is very common in Southeast Brazil, where it is considered a cryptogenic species. This study quantified recruitment rates in shaded and illuminated habitats for 2 years in Rio de Janeiro, Brazil, and analyzed larval photoresponses of this species. Four structures, each containing a shaded and an illuminated surface, were exchanged every 3 months for 2 years. The number of recruits was quantified on each plate. In the laboratory, larvae of P. magna were placed in half‐shaded Petri dishes and the number of settlers in each side was counted after 24 h. Paraleucilla magna recruited continuously throughout the experiment. Recruits occurred in greater abundance on shaded surfaces than on illuminated surfaces, and the larvae were negatively phototactic in vitro. Despite the possible influence of other factors in the recruitment of sponges (such as sedimentation, competition and predation), the prevalence of P. magna in shaded habitats may also be related to larval choice.     

Concentration of Ciprofloxacin in Brazilian Hospital Effluent and Preliminary Risk Assessment: A Case Study

This study was carried out to evaluate the occurrence of the fluoroquinolone antimicrobial agent ciprofloxacin (CIP) in the effluent of the Hospital of the Federal University of Santa Maria (HUSM). Measured environmental concentrations (MECs) of CIP in the hospital wastewater, both before (P1) and after (P2) cesspit/filter system treatment (CFTS), were determined by means of solid phase extraction and reversed‐phase liquid chromatography with fluorescence detection (LC‐FLD) and reversed‐phase liquid chromatography with mass spectrometric detection (LC‐MS/MS). The MECs (n = 7 daily composed samples) were 19 to 155 μg L^–1 (average: 54 ± 21 μg L^–1) and 32 to 99 μg L^–1 (average: 65 ± 45 μg L^–1) in P1 and P2, respectively. No relevant removal was observed from P1 to P2. In a worst case scenario, the final effluent was regarded as MECs of surface water. These MECs were generally 5 to 20,000‐fold higher than what was previously known. If the present data is drawn on to form a model of the situation in developing countries, the picture provides a first rough indication that the environmental risk associated with the use and emission of pharmaceuticals into the environment in developing countries might be higher than in developed countries.