Solubility of KFe(CrO4)2·2H2O at 4–75°C

The solubility of KFe(CrO₄)₂·2H₂O, a precipitate recently identified in a Cr(VI)-contaminated soil, was studied in dissolution and precipitation experiments. Ten dissolution experiments were conducted at 4–75°C and initial pH values between 0.8 and 1.2 using synthetic KFe(CrO₄)₂·2H₂O. Four precipitation experiments were conducted at 25°C with final pH values between 0.16 and 1.39. The log K_SP for the reaction

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The role of gravity in the WEGENER project

Variations in the gravity field are introduced by mass or density redistribution in the vicinity of the measuring point as well as far field or global effects but also any crustal process which involves a height variation has a direct implication on the temporal variation of the gravity field.The measuring techniques involved in the WEGENER project include absolute and high precision relative gravity measurements and stationary measurements with superconducting gravity meters. The state of the art for both techniques is discussed and shown that systematic errors or the measurement of their changes can be detected by inter-comparison with other absolute gravimeters and frequently repeated measurements at a reference station monitored by a superconducting gravimeter. In the combination of the available gravity techniques it is possible to achieve a precision at the micro-Gal level for secular trends and a higher accuracy for period events which enable improvements in the modelling of environmental effects induced by ocean, atmospheric and ground water loading effects from the long term processes.     

The new gravity base net 1976 of the Federal Republic of Germany (DSGN 76)

A new gravity base net (“Schweregrundnetz 1976 der Bundesrepublik Deutschland”, DSGN 76) has been established in the Federal Republic of Germany, to meet the increased requirements of geophysics, geology, metrology and geodesy. The net comprises 21 stations with three excenters each. The gravity values were determined using 4 absolute stations, 11 IGSN71-stations and about 3000 relative gravity meter observations with 4 gravity meters. Instrumental investigations and special treatment of local tidal and atmospheric effects improved the data for the least squares adjustment, which was performed by the method of observation equations following the use of condition equations. The final adjustment showed a point r.m.s. error of about 10μGal[10^?8 ms^?2]. Detailed results will be published in the ”Veröffentlichungen der Deutschen Geodätischen Kommission”.     

Anwendung der Endochronentheorie auf Salzgestein

ZusammenfassungAnwendung der Endochronentheorie auf Salzgestein Es wird ein Stoffgesetz auf Grundlage der Endochronentheorie entwickelt, mit dem das Materialverhalten von Salzgestein beschrieben werden kann. Dafür werden die grundlegenden Vorstellungen dieser allgemeinen Theorie vorgestellt, wie sie von Valanis für Metalle und von Bazant-Bhat für Beton entwickelt wurde.Das Verformungsverhalten von Salzgestein, das durch eine ausgeprägte Kriechneigung geprägt ist, wird erläutert und durch ein rheologisches Modell beschrieben. Das rheologische Modell dient zur Bestimmung der in der Endochronenformulierung vorhandenen Materialfunktionen und Materialkonstanten. Das Stoffgesetz wird in tensorieller Weise formuliert, und es werden Hinweise für seinen Einbau in numerische Rechenmodelle gegeben.

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SummaryUse of the Endochronic Theory on Rock Salt On the basis of the endochronic theory a material model which can describe the behavior of rock salt is developed. This study presents and follows in a modified form the earlier work of Valanis in metals and Bazant-Bhat in concrete.The deformation characteristics of rock salt, subject to extensive creep, are described and explained by an analogous rheological model. This model is used to determine the material functions and constants for the endochronic formulation. The material law is written in tensor form and keys for its use in a computer program are supplied.

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RésuméMise en application de la théorie d'endochrones au niveau de la roche saline A partir de la théorie d'endochrones, l'on développe une loi des matières pouvant décrire le comportement de la roche saline. Dans cette optique, l'on présente les conceptions de base de cette théorie générale, telles qu'elles ont été développées par Valanis pour les métaux et par Bazant-Bhat pour le béton.Le comportement de déformation de la roche saline, caractérisé par une tendance marquée à ramper, est explicité et décrit à l'aide d'un modèle rhéologique. Le modèle rhéologique sert à la détermination des fonctions et constantes de matières, se trouvant dans la formulation d'endochrones. La loi des matières est formulée de facon tensorielle et l'on donne des instructions quant à son application au niveau des ordinateurs.

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Pétrographie des „Permoskyth“ der Jaggl-Plawen-Einheit (Südtirol) und Diskussion der Detritusherkunft mit Hilfe von Kathoden-Lumineszenz-Untersuchungen

The Permo-Scythian deposits E of Lake Reschen (North-Italy) are composed of a sequence of terrestrial sediments in Verrucanofacies and of a series of detrital carbonate and lagoonal-evaporitic rocks (“Wechselschichten”) overlaid by Anisian fossiliferous dolomites. Examinations by cathodo-luminescence give reference to the source area of the detrius and to the diagenesis of the sediments. Further statements can be made by X-ray (triclinity of K-feldspars; inclusions in authigenic minerals) and chemical examinations (composition of dolomites). The detritus of the slightly metamorphic rocks, indicated by the crystallinity of illite, does not originate from the underlying “Plawenkristallin” and from the adjacent “ötztalkristallin”, respectively, but by 70% from a porphyritic source area that is supposed to be located in the region of Lugano.     

Lead-210 and pollen geochronologies on Lake Superior sediments

Rates of sedimentation in two Lake Superior deposits were determined by both ragweed pollen and ²¹⁰Pb geochronologies. The former yields an average rate over the time since the first appearance of enhanced concentrations of the pollen as a consequence of human settlement. Sedimentation rates derived on these two bases can be brought into accord if the first appearance of ragweed pollen in the sediments was around 1830 and if the sedimentation rates have been uniform over the past century.     

Precipitate flotation of copper as the sulfide,using recyclable amphoteric surfactants

An experimental study was made to identify surfactants which are effective for removal of copper from dilute aqueous solution (100–500 ppm) by precipitate flotation as the sulfide, and which at the same time can be recovered from the CuS product for recycle. Batch flotation experiments confirmed that a cationic surfactant was necessary for flotation of CuS from such dilute suspensions; however, no satisfactory way could be found for recovering cationic surfactants from the CuS. This led to consideration of amphoteric surfactants, which are cationic at low pH and anionic at high pH. It was found that a change to negative, rather than simply neutral, charge was required for efficient surfactant recovery. It was further found, through the assistance of experiments in which the CuS suspension was agitated with solvents, that certain functional groups which interact chemically with the CuS surface should also be absent from the surfactant molecule. Following this logic, Amphoterge K-2 (Lonza Chemical Co.) was identified as a suitable surfactant, provided CuS was precipitated with S^2? in excess. Tests established that 95% of adsorbed Amphoterge K-2 could be recovered by raising the pH to 11 and boiling the suspension for one hour, followed by decanting. Surfactant thus recovered was effective in a second flotation test. Foamate solids settled rapidly; such behavior would help reduce the consumption of chemicals for the pH change.Column flotation studies were made using Amphoterge K-2 for removal of Cu²⁺ present at 100 ppm and pH = 2. High removals of CuS could be obtained at concentrations of surfactant above about 25 ppm, for which conditions a substantial fraction of the surfactant remains in solution rather than being adsorbed onto the CuS. The recovery of CuS would be improved by introducing the surfactant in a separate feed, below the feed of CuS suspension. Adding some surfactant in the CuS feed, as well as in a lower feed, gave an even better recovery of CuS (99.8%) at sufficiently high surfactant loadings.     

Diluvialgeologie und Klima

Ohne Zusammenfassung