Optimizing bioventing in shallow vadose zones and cold climates

Abstract

This paper describes a bioventing study design and initial activities applied to a JP-4 jet fuel spill at Eielson Air Force Base, Alaska. The primary objectives of the project were to investigate the feasibility of using bioventing technology to remediate JP-4 jet fuel contamination in a sub-arctic environment and to determine to what degree the biodegradation rate of JP-4 soil contaminants could be enhanced by increasing soil temperature, both actively by circulating heated groundwater and passively by utilizing solar energy. Biodegradation rates at the bioventing site remained relatively high during the winter months in the active-warming test plot and were consistently higher than those observed in the passive-warming and control test plots. These studies suggest that an active-warming system operated in conjunction with bioventing is a useful method for remediating fuel-contaminated areas in cold climates.     

Rate of oxygen removal in some South African groundwaters / Taux d'enlèvement d'oxygène dans de certaines eaux souterraines en Afrique du Sud

Abstract

Data are presented for the dissolved oxygen concentrations and radiometric ages of ‘normal’ (i.e. non-thermal and chemically not unusual) groundwaters in four aquifers in the Cape Province of South Africa. It is demonstrated that a significant amount of the atmospheric oxygen dissolved in the groundwater is consumed within a relatively short period of the order of 20 years. In some environments oxygen concentration measurements may provide a convenient method for locating areas of recharge in groundwater studies.     

Land-cover change and human–environment interactions in a rural cultural landscape in South Africa

This paper presents an historical analysis (1974–97) of associations between land-cover change and socio-economic factors for three villages in a former bantustan region of South Africa. The notion of social–ecological systems is used as the conceptual framework for this analysis, in which the former bantustan region of Bushbuckridge is posited as a cultural landscape. The local landscape showed distinctive modifications over the study period, broad trends including the growth of human settlements and the decrease in woodland cover. However, changes were not uniform across sites, and the direction and magnitude of changes in land cover were often nonlinear and site-specific. Analysis of associations between biophysical and socio-economic changes at different scales revealed a range of important interacting forces such as population growth, drought, shortages of land, grazing and wood resources, weakening institutional governance of natural resources, and the diversification of livelihood strategies, including the sale of fuelwood, concurrent with declining employment security and cattle ownership. Evidence suggests a possible erosion of resilience in these social–ecological systems at various scales, with important implications for socio-economic development and sustainable resource management.     

Spatial scaling properties of annual streamflow in the United States

Abstract

The spatial scaling properties of annual average streamflow is examined using records from 1 433 river basins across the continental United States. The log-linear relationship ln(E[Q^r _i]) = a + b_r ln(A_i) is representative throughout the United States, where E[Q^r _i] represents the expectation of the rth moment of annual streamflow at site i, and A_i represents drainage area. The scaling model parameters a_r and b_r follow nearly perfect linear relationships a_r = rα and b_r = rβ throughout the continental United States. We conclude that the probability distribution of annual streamflow follows simple scaling relationships in all regions of the United States. In temperate regions where climate is relatively homogeneous, scale alone describes most of the variability in the moments of annual streamflow. In the more climatically heterogeneous regions, such as in the Upper Colorado and Missouri river basins, scale alone is a poor predictor of the moments of annual flow.     

Regional calibration of a watershed model

Abstract

As watershed models become increasingly sophisticated and useful, there is a need to extend their applicability to locations where they cannot be calibrated or validated. A new methodology for the regionalization of a watershed model is introduced and evaluated. The approach involves calibration of a watershed model to many sites in a region, concurrently. Previous research that has sought to relate the parameters of monthly water balance models to physical drainage basin characteristics in a region has met with limited success. Previous studies have taken the two-step approach: (a) estimation of watershed model parameters at each site, followed by (b) attempts to relate model parameters to drainage basin characteristics. Instead of treating these two steps as independent, both steps are implemented concurrently. All watershed models in a region are calibrated simultaneously, with the dual objective of reproducing the behaviour of observed monthly streamflows and, additionally, to obtain good relationships between watershed model parameters and basin characteristics. The approach is evaluated using 33 basins in the southeastern region of the United States by comparing simulations using the regional models for three catchments which were not used to develop the regional regression equations. Although the regional calibration approach led to nearly perfect regional relationships between watershed model parameters and basin characteristics, these “improved” regional relationships did not result in improvements in the ability to model streamflow at ungauged sites. This experiment reveals that improvements in regional relationships between watershed model parameters and basin characteristics will not necessarily lead to improvements in the ability to calibrate a watershed model at an ungauged site.     

Noble gases in chondrules and associated metal‐sulfide‐rich samples: Clues on chondrule formation and the behavior of noble gas carrier phases

Abstract— Chondrules are generally believed to have lost most or all of their trapped noble gases during their formation. We tested this assumption by measuring He, Ne, and Ar in chondrules of the carbonaceous chondrites Allende (CV3), Leoville (CV3), Renazzo (CR2), and the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1). Additionally, metalsulfide‐rich chondrule coatings were measured that probably formed from chondrule metal. Low primordial ²⁰Ne concentrations are present in some chondrules, while even most of them contain small amounts of primordial ³⁶Ar. Our preferred interpretation is that‐in contrast to CAIs‐the heating of the chondrule precursor during chondrule formation was not intense enough to expel primordial noble gases quantitatively. Those chondrules containing both primordial ²⁰Ne and ³⁶Ar show low presolar‐diamond‐like ³⁶Ar/²⁰Ne ratios. In contrast, the metal‐sulfide‐rich coatings generally show higher gas concentrations and Q‐like ³⁶Ar/²⁰Ne ratios. We propose that during metalsilicate fractionation in the course of chondrule formation, the Ar‐carrying phase Q became enriched in the metal‐sulfide‐rich chondrule coatings. In the silicate chondrule interior, only the most stable Ne‐carrying presolar diamonds survived the melting event leading to the low observed ³⁶Ar/²⁰Ne ratios. The chondrules studied here do not show evidence for substantial amounts of fractionated solar‐type noble gases from a strong solar wind irradiation of the chondrule precursor material as postulated by others for the chondrules of an enstatite chondrite.