We investigated the acidity and concentrations of water-soluble ions in PM_(2.5) aerosol samples collected from an urban site in Beijing and a rural site in Gucheng, Hebei Province from November 2016 to January 2017 to gain an insight into the formation of secondary inorganic species. The average SO_4~(2–), NO_3~–, and NH_4~+ concentrations were 8.3,12.5, and 14.1 μg m~(–3), respectively, at the urban site and 14.0, 14.2, and 24.2 μg m~(–3), respectively, at the rural site.The nitrogen and sulfur oxidation ratios in urban Beijing were correlated with relative humidity(with correlation coefficient r = 0.79 and 0.67, respectively) and the aerosol loadings. Based on a parameterization model, we found that the rate constant of the heterogeneous reactions for SO_2 on polluted days was about 10 times higher than that on clear days, suggesting that the heterogeneous reactions in the aerosol water played an essential role in haze events.The ISORROPIA II model was used to predict the aerosol pH, which had a mean(range) of 5.0(4.9–5.2) and 5.3(4.6–6.3) at the urban and rural site, respectively. Under the conditions with this predicted pH value, oxidation by dissolved NO_2 and the hydrolysis of N_2O_5 may be the major heterogeneous reactions forming SO_4~(2–) and NO_3~– in haze.We also analyzed the sensitivity of the aerosol p H to changes in the concentrations of SO_4~(2–), NO_3~–, and NH_4~+ under haze conditions. The aerosol p H was more sensitive to the SO_4~(2–) and NH_4~+ concentrations with opposing trends, than to the NO_3~– concentrations. The sensitivity of the p H was relatively weak overall, which was attributed to the buffering effect of NH_3 partitioning. 相似文献
Most porphyry Cu–Mo–Au deposits are found in magmatic arcs worldwide, and are associated with hydrous, high-fO2, calc-alkaline magmas, derived from a mantle wedge that was metasomatized by the fluids from a subducted oceanic slab. Recently, such deposits have been documented as occurring widely in collisional settings, where they are associated with potassic magmas generated during the collisional process, but the genesis of the fertile magmas and the mechanism of metallic enrichment remain controversial. Here we present new geochemical and Sr–Nd–Hf isotopic data from the post-collisional fertile and barren porphyries of the Miocene Gangdese porphyry belt in the Tibetan orogen, an orogen formed by the collision of India and Asia in the early Cenozoic. Both types of porphyry are characterized by high K2O contents, and have geochemical affinities with adakite, but the fertile magmas were most likely derived from the melting of a thickened juvenile mafic lower-crust, formed by the underplating of earlier asthenospheric melts at the base of crust, whereas the derivation of the barren magmas involved variable amounts of old lower-crust in Tibet. The melting of sulfide-bearing phases in the juvenile mantle components of the Tibetan lower-crust probably provided Cu, Au, and S to the fertile magmas. The breakdown of amphibole during melting at the source released the fluids necessary for the formation of the porphyry Cu deposits in Tibet. The thickened crust (up to 70–80 km), due to collision, is thought to be responsible for a decrease in the fO2 of the fertile magmas during their ascent to the upper crust, thus preventing the generation of more porphyry Cu–Au and epithermal Au deposits in this collisional zone. 相似文献
Gravity retaining wall with geogrids has showed excellent seismic performance from Wenchuan great earthquake. However, seismic damage mechanism of this kind of wall is not sufficiently clear. In view of this, a large shaking table test of the gravity retaining wall with geogrids to reinforce the subgrade slope was carried out, and based on the Hilbert-Huang transform and the marginal spectrum theory, the energy identification method of the slope dynamic failure mode was studied. The results show that the geogrids can effectively reduce displacement and rotation of the retaining wall, and it can effectively absorb the energy of the ground movement when combined with the surrounding soil. In addition, it also reveals the failure development of the gravity retaining wall with geogrids to reinforce the subgrade slope. The damage started in the deep zone near the geogrids, and then gradually extended to the surface of the subgrade slope and other zones, finally formed a continuous failure surface along the geogrids. The analysis results of the failure mode identified by the Hilbert marginal spectrum are in good consistency with the experimental results, which prove that the Hilbert marginal spectrum can be applied to obtain the seismic damage mechanism of slope.